Adhesion Composition and Textile Materials and Articles Treated Therewith

Abstract

This invention relates to improved adhesion compositions and textile materials and articles treated therewith. The improved adhesion composition comprises a non-crosslinked resorcinol-formaldehyde and/or resorcinol-furfural condensate (or a phenol-formaldehyde condensate that is soluble in water), a rubber latex, and an aldehyde component such as 2-furfuraldehyde. The composition may be applied to textile substrates and used for improving the adhesion between the treated textile substrates and rubber materials. End-use articles that contain the treated textile-rubber composite include, without limitation, automobile tires, belts, and hoses as well as printing blankets.

1 . A composition for adhering textile materials and rubber-containing articles comprising:
 a) a compound selected from the group consisting of a non-crosslinked resorcinol-formaldehyde condensate, a resorcinol-furfural condensate, a phenol-formaldehyde condensate, and mixtures thereof;   b) a latex component; and   c) an aldehyde component represented by Structure (1), (2) or (3):   
       
         
           
           
               
               
           
         
         
           wherein X is selected from the group consisting of oxygen, nitrogen and sulfur; 
         
       
       
         
           
           
               
               
           
         
         wherein R 1 , R 2  and R 3  may be independently selected from the group consisting of alkyl, aryl, halo, hydrogen, and carboxylic functional groups. 
       
     
     
         2 . The composition of  claim 1 , wherein the composition further includes a base component. 
     
     
         3 . The composition of  claim 2 , wherein the base component is selected from the group consisting of sodium hydroxide, potassium hydroxide, ammonium hydroxide, sodium carbonate, and mixtures thereof. 
     
     
         4 . The composition of  claim 1 , wherein the aldehyde component is selected from the group consisting of 2-furfuraldehyde, 3-furfuraldehyde, pyrrole-2-carboxaldehyde, 2-thiophenecarboxaldehyde, 3-thiophenecarboxaldehyde, 2,3-thiophenedicarboxaldehyde, 2,5-thiophenedicarboxaldehyde, 3-(2-furyl)acrolein, 2,5-furfuryldicarboxaldehyde, cinnamic aldehyde, crotonaldehyde, α,β-unsaturated aldehydes, benzyl aldehyde, propylaldehyde, butyraldehyde and iso butyl-aldehyde, propylaldehyde, butylaldehyde, iso butyl-aldehyde, 2-pyridinecarboxaldehyde, 3-pyridinecarboxaldehyde, 4-pyridinecarboxaldehyde, 2,6-pyridinedicarboxaldehyde, phthalic 1,2-dicarboxaldehyde, phthalic 1,3-dicarboxaldehyde, phthalic 1,4-dicarboxaldehyde, o-sulfo-benzoic aldehyde and mixtures thereof. 
     
     
         5 . The composition of  claim 1 , wherein the latex component is selected from the group consisting of epoxy resin, functional rubber latex, an elastomer latex having no unsaturated double bonds, unvulcanized rubber latex, and mixtures thereof. 
     
     
         6 . The composition of  claim 5 , wherein the epoxy resin has an epoxy functionality of three or greater. 
     
     
         7 . The composition of  claim 5 , wherein the epoxy resin is selected from the group consisting of epoxy cresol-novolac resin, epoxy phenol-novolac resin, poly nuclear phenol-glycidyl ether-derived resin, resin containing an aromatic amine backbone, and mixtures thereof. 
     
     
         8 . The composition of  claim 5 , wherein the rubber latex is selected from the group consisting of vinylpyridine rubber latex, styrene-butadiene rubber latex, chloroprene rubber latex, nitrile rubber latex, butyl rubber latex, ethylene propylene diene monomer rubber latex, butadiene rubber latex, polyisoprenes, hydrogenated rubber latex, polyurethane and mixtures thereof. 
     
     
         9 . The composition of  claim 5 , wherein the functionalized rubber latex contains a rubber polymer having at least one pendant carboxyl, amide, or pyridyl group, or a derivative thereof. 
     
     
         10 . The composition of  claim 5 , wherein the unvulcanized rubber latex is selected from the group consisting of polybutadiene, polyisoprene, synthetic trans-rich polyisoprene or cis-rich polyisoprene, natural rubber, poly(styrene-co-butadiene), poly(acrylonitrile-co-butadiene), chloroprene, hydrogenated styrene-butadiene rubber, hydrogenated nitrile-butadiene rubber, butyl rubber, halo-butyl rubber, ethylene propylene diene monomer rubber and mixtures thereof. 
     
     
         11 . The composition of  claim 1 , wherein the composition further includes at least one additive selected from the group consisting of hydrophilic solvents, antioxidants, wetting agents, rheology modifiers, pH buffers, heat stabilizers, ozone stabilizers, ultraviolet light stabilizers, emulsifiers, adhesion promoters, antiozonants, carbon black, silica, and mixtures thereof. 
     
     
         12 . The composition of  claim 1 , wherein the composition further includes a tacky resin. 
     
     
         13 . The composition of  claim 12 , wherein the tacky resin is selected from the group consisting of phenol-containing resins (such as phenol formaldehyde resin, resorcinol formaldehyde condensate, condensate of phenol derivatives with aldehydes and acetylene, terpene phenolic resins), aromatic resins, hydrocarbon resins, terpene resins, indene resins, coumarone resins, rosin-based resins, and mixtures thereof. 
     
     
         14 . A coated textile material comprising:
 a) a textile substrate; and   b) a composition comprising the reaction product of a mixture comprising:
 i) a compound selected from the group consisting of a non-crosslinked resorcinol-formaldehyde condensate, a resorcinol-furfural condensate, a phenol-formaldehyde condensate, and mixtures thereof; 
 ii) a latex component; and 
 iii) an aldehyde component represented by Structure (1), (2) or (3): 
   
       
         
           
           
               
               
           
         
         
           
             wherein X is selected from the group consisting of oxygen, nitrogen and sulfur; 
           
         
       
       
         
           
           
               
               
           
         
         wherein R 1 , R 2  and R 3  may be independently selected from the group consisting of alkyl, aryl, halo, hydrogen, and carboxylic functional groups. 
       
     
     
         15 . The coated textile material of  claim 14 , wherein the composition further includes a base component. 
     
     
         16 . The coated textile material of  claim 15 , wherein the base component is selected from the group consisting of sodium hydroxide, potassium hydroxide, ammonium hydroxide, sodium carbonate, and mixtures thereof. 
     
     
         17 . The coated textile material of  claim 14 , wherein the aldehyde component is selected from the group consisting of 2-furfuraldehyde, 3-furfuraldehyde, pyrrole-2-carboxaldehyde, 2-thiophenecarboxaldehyde, 3-thiophenecarboxaldehyde, 2,3-thiophenedicarboxaldehyde, 2,5-thiophenedicarboxaldehyde, 3-(2-furyl)acrolein, 2,5-furfuryldicarboxaldehyde, cinnamic aldehyde, crotonaldehyde, α,β-unsaturated aldehydes, benzyl aldehyde, propylaldehyde, butyraldehyde and iso butyl-aldehyde, propylaldehyde, butylaldehyde, iso butyl-aldehyde, 2-pyridinecarboxaldehyde, 3-pyridinecarboxaldehyde, 4-pyridinecarboxaldehyde, 2,6-pyridinedicarboxaldehyde, phthalic 1,2-dicarboxaldehyde, phthalic 1,3-dicarboxaldehyde, phthalic 1,4-dicarboxaldehyde, o-sulfo-benzoic aldehyde and mixtures thereof. 
     
     
         18 . The coated textile material of  claim 14 , wherein the latex component is selected from the group consisting of epoxy resin, functional rubber latex, an elastomer latex having no unsaturated double bonds, unvulcanized rubber latex, and mixtures thereof. 
     
     
         19 . The coated textile material of  claim 18 , wherein the epoxy resin has an epoxy functionality of three or greater. 
     
     
         20 . The coated textile material of  claim 18 , wherein the epoxy resin is selected from the group consisting of epoxy cresol-novolac resin, epoxy phenol-novolac resin, poly nuclear phenol-glycidyl ether-derived resin, resin containing an aromatic amine backbone, and mixtures thereof. 
     
     
         21 . The coated textile material of  claim 18 , wherein the rubber latex is selected from the group consisting of vinylpyridine rubber latex, styrene-butadiene rubber latex, chloroprene rubber latex, nitrile rubber latex, butyl rubber latex, ethylene propylene diene monomer rubber latex, butadiene rubber latex, polyisoprenes, hydrogenated rubber latex, polyurethane and mixtures thereof. 
     
     
         22 . The coated textile material of  claim 18 , wherein the functionalized rubber latex contains a rubber polymer having at least one pendant carboxyl, amide, or pyridyl group, or a derivative thereof. 
     
     
         23 . The coated textile material of  claim 18 , wherein the unvulcanized rubber latex is selected from the group consisting of polybutadiene, polyisoprene, synthetic trans-rich polyisoprene or cis-rich polyisoprene, natural rubber, poly(styrene-co-butadiene), poly(acrylonitrile-co-butadiene), chloroprene, hydrogenated styrene-butadiene rubber, hydrogenated nitrile-butadiene rubber, butyl rubber, halo-butyl rubber, ethylene propylene diene monomer rubber and mixtures thereof. 
     
     
         24 . The coated textile material of  claim 14 , wherein the composition further includes at least one additive selected from the group consisting of hydrophilic solvents, antioxidants, wetting agents, rheology modifiers, pH buffers, heat stabilizers, ozone stabilizers, ultraviolet light stabilizers, emulsifiers, adhesion promoters, antiozonants, carbon black, silica, and mixtures thereof. 
     
     
         25 . The coated textile material of  claim 14 , wherein the composition further includes a tacky resin. 
     
     
         26 . The coated textile material of  claim 25 , wherein the tacky resin is selected from the group consisting of phenol-containing resins (such as phenol formaldehyde resin, resorcinol formaldehyde condensate, condensate of phenol derivatives with aldehydes and acetylene, terpene phenolic resins), aromatic resins, hydrocarbon resins, terpene resins, indene resins, coumarone resins, rosin-based resins, and mixtures thereof. 
     
     
         27 . A product comprising the coated textile material of  claim 14 , wherein said product is one of a printer's blanket, reinforcing yarns or fabrics used in rubber hoses, reinforcing belting fabrics, V-belts, automotive transmission belts, reinforcing tire cord, tire cap ply, tire body ply, tire bead wrap, tire gum strip, and chafer fabrics.