Liquid-crystalline mixtures

Abstract

The present invention describes liquid-crystalline mixtures, and also oligomers or polymers which are obtainable by oligomerizing or polymerizing the inventive liquid-crystalline mixtures, a process for printing or coating substrates by applying and then polymerizing the inventive liquid-crystalline mixtures and the use of the inventive liquid-crystalline mixtures or of the inventive oligomers or polymers for production of optical or electrooptical components. The present invention further relates to the use of the inventive liquid-crystalline mixtures which comprise at least one chiral dopant for production of thermal insulation layers, and to such thermal insulation layers.

1 . A liquid-crystalline mixture, comprising:
 (A) a compound of formula I:   
       
         
           
           
               
               
           
         
         (B) a compound of formula II: 
       
       
         
           
           
               
               
           
         
         (C) at least one compound selected from the group consisting of a photoinitiator, a reactive diluent comprising a photopolymerizable group, a diluent, a defoamer, a deaerator, a lubricant, a leveling agent, a thermally curing auxiliary, a radiatively curing auxiliary, a substrate wetting aids, a wetting aid, a dispersing aid, a hydrophobizing agent, an adhesion promoter, a scratch resistance auxiliary, and a chiral dopant, and 
         (D) optionally at least one substance selected from the group consisting of a dye and a pigment, 
         wherein Z 1 , Z 2 , Z 3 , and Z 4  are each independently 
       
       
         
           
           
               
               
           
         
         A 1 , A 2 , A 3 , and A 4  are each independently a spacer having 4 to 8 carbon atoms, 
         Y 1 , Y 2 , Y 3 , and Y 4  are each independently a single chemical bond, oxygen, —CO—, —O—CO—, or —CO—O—, 
         R 1  and R 2  are each independently hydrogen, C 1 -C 6 -alkyl, or CO—O—C 1 -C 6 -alkyl, 
         a proportion of component A is from 22.5 mol % to 32.5 mol % and a proportion of component B is from 67.5 mol % to 77.5 mol %, based on a total molar amount of A and B, and 
         the proportions of components A and B add up to 100 mol % 
       
     
     
         2 . The liquid-crystalline mixture of  claim 1 ,
 wherein Z 1 -Y 1 , Y 2 -Z 2 , Z 3 -Y 3 , and Y 4 -Z 4  are each independently:   
       
         
           
           
               
               
           
         
       
     
     
         3 . An oligomer or polymer, obtained by a process comprising:
 oligomerizing or polymerizing the mixture of  claim 1 .   
     
     
         4 . A process for printing or coating a substrate, the process comprising:
 applying the mixture of  claim 1  to the substrate, and then   polymerizing the mixture.   
     
     
         5 . A process for producing an optical or electrooptical component, comprising:
 producing an optical or electrooptical component with the mixture of  claim 1 .   
     
     
         6 . A process for producing a thermal insulation layer, the process comprising:
 producing the layer with the mixture of  claim 1 ,   wherein the layer comprises a cholesteric layer capable of reflecting at least 40% of infrared incident radiation, and   component (C) comprises a chiral dopant.   
     
     
         7 . A process for producing a thermal insulation layer, the process comprising:
 producing the layer with the mixture of  claim 1 ,   wherein the layer comprises a cholesteric layer with a transmission of at least 80% of incident radiation of wavelength of from 390 nm to 750 nm.   
     
     
         8 . A thermal insulation layer, comprising:
 a cholesteric layer, capable of reflecting at least 40% of infrared incident radiation,   wherein the cholesteric layer is obtained by a process comprising producing the cholesteric layer with the mixture of  claim 1 , and   component (C) comprises a chiral dopant.   
     
     
         9 . A thermal insulation layer, comprising:
 a cholesteric layer with a transmission of at least 80% of incident radiation of wavelength of from 390 nm to 750 nm,   wherein the cholesteric layer is obtained by a process comprising producing the layer with the mixture of  claim 1 , and   wherein component (C) comprises a chiral dopant.   
     
     
         10 . The process of  claim 6 , wherein the cholesteric layer is capable of reflecting at least 45% of infrared incident radiation. 
     
     
         11 . The process of  claim 6 , wherein the cholesteric layer is capable of reflecting at least 40% of incident radiation with wavelength of from 750 to 2000 nm. 
     
     
         12 . The process of  claim 6 , wherein the cholesteric layer is capable of reflecting at least 45% of incident radiation with wavelength of from 750 to 2000 nm. 
     
     
         13 . The process of  claim 7 , wherein the cholesteric layer has a transmission of at least 90% of incident radiation with wavelength of from 390 nm to 750 nm. 
     
     
         14 . The thermal insulation layer of  claim 8 , wherein the cholesteric layer is capable of reflecting at least 45% of infrared incident radiation. 
     
     
         15 . The thermal insulation layer of  claim 8 , wherein the cholesteric layer is capable of reflecting at least 40% of incident radiation with wavelength of from 750 to 2000 nm. 
     
     
         16 . The thermal insulation layer of  claim 8 , wherein the cholesteric layer is capable of reflecting at least 45% of incident radiation with wavelength of from 750 to 2000 nm. 
     
     
         17 . The thermal insulation layer of  claim 9 , wherein the cholesteric layer has a transmission of at least 90% of incident radiation with wavelength of from 390 nm to 750 nm.