Method for reducing carbon dioxide

Abstract

The method for reducing carbon dioxide of the present disclosure includes a step (a) and a step (b) as follows. A step (a) of preparing an electrochemical cell. The electrochemical cell comprises a working electrode, a counter electrode and a vessel. The vessel stores an electrolytic solution. The working electrode contains at least one carbide selected from the group consisting of zirconium carbide, hafnium carbide, niobium carbide, chromium carbide and tungsten carbide. The electrolytic solution contains carbon dioxide. The working electrode and the counter electrode are in contact with the electrolytic solution. A step (b) of applying a negative voltage and a positive voltage to the working electrode and the counter electrode, respectively, to reduce the carbon dioxide.

1 . A method for reducing carbon dioxide, the method comprising:
 a step (a) of preparing an electrochemical cell, wherein   the electrochemical cell comprises a working electrode, a counter electrode and a vessel,   the vessel stores an electrolytic solution,   the working electrode contains, as a catalyst, only at least one carbide, as a catalyst, selected from the group consisting of zirconium carbide, hafnium carbide, niobium carbide, chromium carbide and tungsten carbide,   the electrolytic solution contains carbon dioxide,   the working electrode is in contact with the electrolytic solution, and   the counter electrode is in contact with the electrolytic solution; and   a step (b) of applying a negative voltage and a positive voltage to the working electrode and the counter electrode, respectively, to reduce the carbon dioxide.   
     
     
         2 . The method according to  claim 1 , wherein
 in the step (b), at least one compound selected from the group consisting of methane, ethylene, ethane and formic acid is produced.   
     
     
         3 . The method according to  claim 1 , wherein
 the vessel comprises a solid electrolyte membrane, and   the solid electrolyte membrane is interposed between the working electrode and the counter electrode.   
     
     
         4 . The method according to  claim 1 , wherein
 the electrochemical cell comprises a tube,   one end of the tube is disposed in the electrolytic solution, and   in the step (b), the carbon dioxide is supplied to the electrolytic solution through the tube.