Complex oxide, method for producing same, and exhaust gas purifying catalyst

Abstract

Disclosed are a composite oxide which is capable of maintaining a large volume of pores even used in a high temperature environment, and which has excellent heat resistance and catalytic activity, as well as a method for producing the composite oxide and a catalyst for exhaust gas purification employing the composite oxide. The composite oxide contains cerium and at least one element selected from aluminum, silicon, or rare earth metals other than cerium and including yttrium, at a mass ratio of 85:15 to 99:1 in terms oxides, and has a property of exhibiting a not less than 0.30 cm 3 /g, preferably not less than 0.40 cm 3 /g volume of pores with a diameter of not larger than 200 nm, after calcination at 900° C. for 5 hours, and is suitable for a co-catalyst in a catalyst for vehicle exhaust gas purification.

1 . A composite oxide comprising cerium and at least one element selected from aluminum, silicon, or rare earth metals other than cerium and including yttrium, at a mass ratio of 85:15 to 99:1 in terms oxides, and having a property of exhibiting a not less than 0.30 cm 3 /g volume of pores with a diameter of not larger than 200 nm, after calcination at 900° C. for 5 hours. 
     
     
         2 . The composite oxide according to  claim 1  having a property of exhibiting a not less than 0.40 cm 3 /g volume of pores with a diameter of not larger than 200 nm, after calcination at 900° C. for 5 hours. 
     
     
         3 . The composite oxide according to  claim 1  having a property of exhibiting a not less than 0.50 cm 3 /g volume of pores with a diameter of not larger than 200 nm, after calcination at 900° C. for 5 hours. 
     
     
         4 . The composite oxide according to  claim 1 , having a property of exhibiting a not less than 0.32 cm 3 /g volume of pores with a diameter of not larger than 200 nm, after calcination at 800° C. for 5 hours. 
     
     
         5 . The composite oxide according to  claim 1 , comprising at least silicon as said at least one element selected from aluminum, silicon, or rare earth metals other than cerium and including yttrium, and having a property of exhibiting a not less than 0.60 cm 3 /g volume of pores with a diameter of not larger than 200 nm, after calcination at 900° C. for 5 hours. 
     
     
         6 . The composite oxide according to  claim 1 , wherein said rare earth metals other than cerium and including yttrium comprise at least one element selected from the group consisting of yttrium, lanthanum, praseodymium, and neodymium. 
     
     
         7 . A method for producing a composite oxide comprising the steps of:
 (a) providing a cerium solution not less than 90 mol % of which cerium ions are tetravalent,   (b) heating and maintaining said cerium solution obtained from step (a) up to and at not lower than 60° C.,   (c) adding an oxide precursor of at least one element selected from aluminum, silicon, or rare earth metals other than cerium and including yttrium, to a cerium suspension obtained through said heating and maintaining,   (d) heating and maintaining said cerium suspension containing said oxide precursor of at least one element selected from aluminum, silicon, or rare earth metals other than cerium and including yttrium, up to and at not lower than 100° C.,   (e) neutralizing said suspension obtained from step (d),   (f) adding a surfactant to said suspension neutralized in step (e) to obtain a precipitate, and   (g) calcining said precipitate.   
     
     
         8 . The method according to  claim 7 , wherein a cerium content of said cerium solution in step (a) is 5 to 100 g/L in terms of CeO 2 . 
     
     
         9 . A catalyst for exhaust gas purification comprising the composite oxide according to  claim 1 .