Non-aqueous secondary battery

Abstract

A non-aqueous secondary battery contains a positive electrode, a negative electrode, a separator and a non-aqueous electrolytic solution. The positive electrode contains a layered structure lithium-containing compound oxide, or a spinel lithium-containing compound oxide containing manganese as an active material. The non-aqueous electrolytic solution contains at least one additive selected from a sulfonic acid anhydride, a sulfonate ester derivative, a cyclic sulfate derivative and a cyclic sulfonate ester derivative, and a vinylene carbonate or a derivative of the vinylene carbonate.

What is claimed is: 
     
         1 . A non-aqueous secondary battery comprising:
 a positive electrode;   a negative electrode;   a separator; and   a non-aqueous electrolytic solution,   wherein the positive electrode comprises, as an active material, a layered lithium-containing compound oxide containing manganese as a constituent element or a spinel lithium-containing compound oxide containing manganese as a constituent element, and   the non-aqueous electrolytic solution contains a cyclic sulfate derivative expressed by the general formula (3) and a vinylene carbonate or a derivative of the vinylene carbonate:   
       
         
           
           
               
               
           
         
         wherein R 5  in the general formula (3) represents independently hydrogen or an alkyl group having 1-4 of carbon atoms, which can have a fluorinated substituent, n is 0 or 1. 
       
     
     
         2 . The non-aqueous secondary battery according to  claim 1 , wherein the non-aqueous electrolytic solution contains 0.2 mass % or more of the cyclic sulfate derivative. 
     
     
         3 . The non-aqueous secondary battery according to  claim 1 , wherein the non-aqueous electrolytic solution contains 5 mass % or less of the cyclic sulfate derivative. 
     
     
         4 . The non-aqueous secondary battery according to  claim 1 , wherein the non-aqueous electrolytic solution contains 0.2 mass % or more of the vinylene carbonate or its derivative. 
     
     
         5 . The non-aqueous secondary battery according to  claim 1 , wherein the non-aqueous electrolytic solution contains 5 mass % or less of the vinylene carbonate or its derivative. 
     
     
         6 . The non-aqueous secondary battery according to  claim 1 , wherein the non-aqueous electrolytic solution contains, as the cyclic sulfate derivative, at least one selected from ethylene glycol sulfuric ester, 1,2-propanediol sulfuric ester, 1,3-propanediol sulfuric ester, 1,2-butanediol sulfuric ester, 1,3-butanediol sulfuric ester, 1,2-pentane diol sulfuric ester, 1,3-pentane diol sulfuric ester, 1,3-hexane diol sulfuric ester, and 1,3-heptane diol sulfuric ester.