Composite material; a ballistic resistant article made from same and method of making the article

Abstract

A fiber reinforced resin composite for ballistic protection comprising a plurality of first and second plies wherein the first and second plies further comprise a woven fabric and a polymeric resin. The fabric has a Russell tightness factor of from 0.2 to 0.7 and a cover factor of at least 0.45, The fabric is impregnated with the resin, the resin comprising from 5 to 30 weight percent of the total weight of fabric plus resin. The fabric of each first and second ply comprises regions wherein the fabric is distorted from an orthogonal woven state by a distortion angle of least 30 degrees. The composite may further comprising a third ply having a surface area no greater than 50% of the surface area of a first and second ply. The ratio of the number of first plus second plies to the number of third plies is from 2:1 to 12:1.

What is claimed is: 
     
         1 . A contoured fiber reinforced resin composite for ballistic protection comprising a plurality of first and second plies wherein the first and second plies further comprise (i) a woven fabric made from a plurality of polymeric yarns having a yarn tenacity of from 15 grams per dtex to 50 grams per dtex and a modulus of from 200 grams per dtex to 2200 grams per dtex, and (ii) a polymeric resin, wherein
 (a) the fabric has a Russell tightness factor of from 0.2 to 0.7,   (b) the fabric has an areal weight of from 80 gsm to 510 gsm,   (c) the fabric has a cover factor of at least 0.45,   (d) the fabric is impregnated with the resin, the resin comprising from 5 to 30 weight percent of the total weight of fabric plus resin, and   (e) the fabric of each first and second ply comprises regions wherein the fabric is distorted from an orthogonal woven state by a distortion angle of least 30 degrees.   
     
     
         2 . The composite of  claim 1  wherein the resin content is from 5 to 20 weight percent of the of the total weight of fabric plus resin. 
     
     
         3 . The composite of  claim 1  wherein the resin content is from 5 to 15 weight percent of the of the total weight of fabric plus resin. 
     
     
         4 . The composite of  claim 1  wherein the resin content is from 8 to 12 weight percent of the of the total weight of fabric plus resin. 
     
     
         5 . The composite of  claim 1  wherein the woven fabric of the first and second plies has a Russell tightness factor of from 0.3 to 0.5. 
     
     
         6 . The composite of  claim 1  wherein the polymer of the yarns of the fabric of the first and second plies is para-aramid, polyazole or mixtures thereof. 
     
     
         7 . The composite of  claim 1  wherein the polymer of the yarns of the fabric of the first and second plies is polyethylene. 
     
     
         8 . The composite of  claim 1  wherein the fabric of each first and second ply comprises regions wherein the fabric is distorted from an orthogonal woven state by a distortion angle of least 40 degrees. 
     
     
         9 . The composite of  claim 1  wherein the orientation of a second ply is offset at an angle of from 20 to 70 degrees with respect to the orientation of a first ply, 
     
     
         10 . The composite of  claim 9  further comprising a third ply, the third ply comprising (i) a woven fabric made from a plurality of polymeric yarns having a yarn tenacity of from 15 grams per dtex to 50 grams per dtex and a modulus of from 200 grams per dtex to 2200 grams per dtex, and (ii) a polymeric resin, wherein,
 (a) the surface area of a third ply is no greater than 50% of the surface area of a first and second ply, 
 (b) the fabric has a Russell tightness factor of from 0.2 to 0.7, 
 (c) the fabric has an areal weight of from 80 gsm to 510 gsm, 
 (d) the fabric has a cover factor of at least 0.45, 
 (e) the fabric is impregnated with the resin, the resin comprising from 5 to 30 weight percent of the total weight of fabric plus resin, and 
 (f) the ratio of the number of first plus second plies to the number of third plies in the composite is in the range of from 2:1 to 12:1. 
 
     
     
         11 . The composite of  claim 10  wherein there are no cuts, darts, pleats or folds in the first, second and third plies. 
     
     
         12 . The composite of  claim 10  wherein the geometric shape of the third ply is circular, oval, square, rectangular, diamond, pentagonal, hexagonal or octagonal. 
     
     
         13 . The composite of  claim 10  wherein the polymer of the yarns of the third ply is para-aramid, polyazole or mixtures thereof. 
     
     
         14 . The composite of  claim 10  wherein the polymer of the yarns of the third ply is polyethylene. 
     
     
         15 . A ballistic resistant article comprising the composite of  claim 10   
     
     
         16 . A method of forming a curved fiber reinforced resin composite article comprising the steps of
 (i) providing a roll of resin impregnated fabric composite comprising a woven fabric made from a plurality of polymeric yarns having a yarn tenacity of from 15 grams per dtex to 50 grams per dtex and a modulus of from 200 grams per dtex to 2200 grams per dtex, and a polymeric resin, wherein
 (a) the fabric has a Russell tightness factor of from 0.2 to 0.7, 
 (b) the fabric has an areal weight of from 80 gsm to 510 gsm, 
 (c) the fabric has a cover factor of at least 0.5, and, 
 (d) the fabric is impregnated with the polymeric resin, the resin comprising from 5 to 30 weight percent of the of the total weight of fabric plus resin, 
   (ii) cutting a plurality of plies from the fabric composite roll to provide first and second plies such that the plies have a shape profile similar to the final shape profile of the article being formed,   (iii) cutting a plurality of plies from the fabric composite roll to provide third plies such that the surface area of a third ply is no greater than 50% of the surface area of the first or second plies,   (iv) tensioning the corners or edges of the first and second plies to cause regions of the ply to distort by a distortion angle of at least 30 degrees,   (v) assembling, in the desired order, a plurality of first, second and third plies such that the ratio of the number of first plus second plies to the number of third plies is in the range of from 2:1 to 12:1and the orientation of a second ply is offset at an angle of from 20 to 70 degrees with respect to the orientation of a first ply, and   (vi) consolidating the assembly of step (v) at a temperature of from 115° C. to 230° C. and an applied force of from 34 to 800 tonnes for between 5 to 60 minutes to form a cured composite article.   
     
     
         17 . The method of  claim 16  wherein the polymer of the yarns of the first, second and third plies is para-aramid, polyazole or mixtures thereof. 
     
     
         18 . The method of  claim 16  wherein the polymer of the yarns of the first, second and third plies is polyethylene. 
     
     
         19 . The method of  claim 16  wherein the fabric of each first and second ply comprises regions wherein the fabric is distorted from an orthogonal woven state by a distortion angle of least 40 degrees.