US2013209966A1PendingUtilityA1

Integrated Porcelain System for a Dental Prosthesis

55
Assignee: CHU CHRISTOPHERPriority: May 30, 2008Filed: Mar 18, 2013Published: Aug 15, 2013
Est. expiryMay 30, 2028(~1.9 yrs left)· nominal 20-yr term from priority
A61K 6/858C03C 8/08A61C 13/09C09D 1/00A61C 5/70C03C 8/06C03C 8/02A61C 13/0006C03C 4/0021A61C 13/0835C03C 2204/04A61C 5/77A61C 5/73A61C 5/10A61C 5/08
55
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Claims

Abstract

An integrated dental porcelain system for making dental prostheses and restorations is provided. The system includes three universal major components: a) opaque porcelain composition; b) pressable dentin ingot; and c) veneering porcelain composition that can be used interchangeably for making restorations. Techniques for making the prostheses and restorations include porcelain fused-to-metal (PFM), press-to-metal (PTM), and either pressed and/or machined all-ceramic methods. The system uses both a hand-layering of veneering porcelain (PFM technique) and a hot-pressing process (PTM and all-ceramic technique) to fabricate the prostheses and restorations.

Claims

exact text as granted — not AI-modified
1 . A dental prosthesis comprising:
 a metal substructure;   an opaque layer having a composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Components 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   42-46% 
                 
                     
                   Al 2 O 3   
                    8-12% 
                 
                     
                   Na 2 O 
                   2-5% 
                 
                     
                   K 2 O 
                   6-9% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   0-2% 
                 
                     
                   MgO 
                   0-2% 
                 
                     
                   ZrO 2   
                   20-30% 
                 
                     
                   SnO 2   
                   1-4% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-3% 
                 
                     
                   TiO 2   
                   0-2% 
                 
                     
                   Sb 2 O 3   
                     0-0.1% 
                 
                     
                   Fluorescing agent 
                   0-5% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the opaque layer, after firing to a temperature in the range of 860° to 900° C., forms an opaque coating over the metal substructure, the opaque coating being thermally compatible and thermally stable with the metal substructure. 
       
     
     
         2 . The dental prosthesis of  claim 1  further comprising a porcelain layer over the opaqued metal substructure, the porcelain layer having a composition including the following components: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   63-66% 
                 
                     
                   Al 2 O 3   
                   10-14% 
                 
                     
                   Na 2 O 
                   3-7% 
                 
                     
                   K 2 O 
                    9-12% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   1-4% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the porcelain layer, after pressing at a temperature in the range of 870° C. to 910° C., forms a dentin body layer, the dentin body layer being thermally compatible with the opaqued metal substructure. 
       
     
     
         3 . The dental prosthesis of  claim 2 , further comprising a shade stain layer and/or a glaze layer, the shade stain layer and/or the glaze layer, each having a composition including the following components: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   56-64% 
                 
                     
                   Al 2 O 3   
                    6-13% 
                 
                     
                   Na 2 O 
                    7-15% 
                 
                     
                   K 2 O 
                    7-15% 
                 
                     
                   Li 2 O 
                   0-5% 
                 
                     
                   CaO 
                   0-3% 
                 
                     
                   MgO 
                   2-5% 
                 
                     
                   SnO 2   
                   0-4% 
                 
                     
                   Tb 4 O 7   
                   0-3% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   B 2 O 3   
                   0-5% 
                 
                     
                   Sb 2 O 3   
                     0-0.5% 
                 
                     
                   F 
                     0-2.5% 
                 
                     
                   TiO 2   
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the stain layer and/or the glaze layer, after firing to a temperature in the range of 780° to 840° C., form a shade stain and/or glaze overlayer over the dentin body layer, the shade stain and/or glaze overlayer being thermally compatible and thermally stable with the dentin body layer. 
       
     
     
         4 . The dental prosthesis of  claim 1  further comprising a veneering porcelain layer having a composition including the following components: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   62-65% 
                 
                     
                   Al 2 O 3   
                    8-11% 
                 
                     
                   Na 2 O 
                    8-11% 
                 
                     
                   K 2 O 
                   4-7% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   2-5% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   MgO 
                   1-4% 
                 
                     
                   SnO 2   
                   0-2% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   Sb 2 O 3   
                   0-2% 
                 
                     
                   P 2 O 5   
                     0-0.1% 
                 
                     
                   TiO 2   
                     0-0.1% 
                 
                     
                   F 
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the veneering porcelain layer, after firing at a temperature in the range of 810° C. to 860° C., forms a dentin-enamel layer over the opaqued metal substructure, the dentin-enamel layer being thermally compatible with the opaqued metal substructure. 
       
     
     
         5 . The dental prosthesis of  claim 4 , further comprising a glaze layer having a composition including the following components: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   56-64% 
                 
                     
                   Al 2 O 3   
                    6-13% 
                 
                     
                   Na 2 O 
                    7-15% 
                 
                     
                   K 2 O 
                    7-15% 
                 
                     
                   Li 2 O 
                   0-5% 
                 
                     
                   CaO 
                   0-3% 
                 
                     
                   MgO 
                   2-5% 
                 
                     
                   SnO 2   
                   0-4% 
                 
                     
                   Tb 4 O 7   
                   0-3% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   B 2 O 3   
                   0-4% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the glaze layer, after firing to a temperature in the range of 780° to 840° C., forms a glaze overlayer over the fired dentin-enamel layer, the glaze overlayer being thermally compatible with the dentin-enamel layer. 
       
     
     
         6 . The dental prosthesis of  claim 2 , further comprising a veneering porcelain layer having a composition including the following components: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   62-65% 
                 
                     
                   Al 2 O 3   
                    8-11% 
                 
                     
                   Na 2 O 
                    8-11% 
                 
                     
                   K 2 O 
                   4-7% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   2-5% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   MgO 
                   1-4% 
                 
                     
                   SnO 2   
                   0-2% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   Sb 2 O 3   
                   0-2% 
                 
                     
                   P 2 O 5   
                     0-0.1% 
                 
                     
                   TiO 2   
                     0-0.1% 
                 
                     
                   F 
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the veneering porcelain layer, after firing at a temperature in the range of 810° C. to 860° C., forms an enamel layer over the dentin body layer, the enamel layer being thermally compatible with the opaqued metal substructure and the dentin body layer. 
       
     
     
         7 . The dental prosthesis of  claim 6 , further comprising a glaze layer over the fired enamel layer, the glaze layer having a composition including the following components: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   56-64% 
                 
                     
                   Al 2 O 3   
                    6-13% 
                 
                     
                   Na 2 O 
                    7-15% 
                 
                     
                   K 2 O 
                    7-15% 
                 
                     
                   Li 2 O 
                   0-5% 
                 
                     
                   CaO 
                   0-3% 
                 
                     
                   MgO 
                   2-5% 
                 
                     
                   SnO 2   
                   0-4% 
                 
                     
                   Tb 4 O 7   
                   0-3% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   B 2 O 3   
                   0-4% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the glaze layer, after firing to a temperature in the range of 780° to 840° C., forms a glaze overlayer over the pressed enameled dentin body layer, the glaze overlayer being thermally compatible with the enameled dentin body layer. 
       
     
     
         8 . A dental prosthesis comprising:
 an all-ceramic core, and   a porcelain layer having a composition including the following components;   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   63-66% 
                 
                     
                   Al 2 O 3   
                   10-14% 
                 
                     
                   Na 2 O 
                   3-7% 
                 
                     
                   K 2 O 
                    9-12% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   1-4% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the porcelain layer, after pressing at a temperature in the range of 870° C. to 910° C., forms a dentin body layer, forms a dentin body layer, the dentin body layer being thermally compatible with the ceramic core. 
       
     
     
         9 . The dental prosthesis  claim 8 , further comprising a veneering porcelain layer having a composition including the following components 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   62-65% 
                 
                     
                   Al 2 O 3   
                    8-11% 
                 
                     
                   Na 2 O 
                    8-11% 
                 
                     
                   K 2 O 
                   4-7% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   2-5% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   MgO 
                   1-4% 
                 
                     
                   SnO 2   
                   0-2% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   Sb 2 O 3   
                   0-2% 
                 
                     
                   P 2 O 5   
                     0-0.1% 
                 
                     
                   TiO 2   
                     0-0.1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the veneering porcelain layer, after firing at a temperature in the range of 810° C. to 860° C., forms an enamel layer over the dentin body layer, the enamel layer being thermally compatible with the dentin body layer. 
       
     
     
         10 . The dental prosthesis  claim 9 , further comprising a glaze layer over the fired enamel layer, the glaze layer having a composition including the following components: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   56-64% 
                 
                     
                   Al 2 O 3   
                    6-13% 
                 
                     
                   Na 2 O 
                    7-15% 
                 
                     
                   K 2 O 
                    7-15% 
                 
                     
                   Li 2 O 
                   0-5% 
                 
                     
                   CaO 
                   0-3% 
                 
                     
                   MgO 
                   2-5% 
                 
                     
                   SnO 2   
                   0-4% 
                 
                     
                   Tb 4 O 7   
                   0-3% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   B 2 O 3   
                   0-4% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         wherein the glaze layer, after firing to a temperature in the range of about 780° to 840° C., forms a glaze overlayer over the dentin body layer, the glaze overlayer being thermally compatible with the dentin body layer. 
       
     
     
         11 . A method for making a dental prosthesis comprising the step of:
 providing a metal substructure;   applying an opaque composition over the metal substructure, the opaque composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Component 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   42-46% 
                 
                     
                   Al 2 O 3   
                    8-12% 
                 
                     
                   Na 2 O 
                   2-5% 
                 
                     
                   K 2 O 
                   6-9% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   0-2% 
                 
                     
                   MgO 
                   0-2% 
                 
                     
                   ZrO 2   
                   20-30% 
                 
                     
                   SnO 2   
                   1-4% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-3% 
                 
                     
                   TiO 2   
                   0-2% 
                 
                     
                   Sb 2 O 3   
                     0-0.1% 
                 
                     
                   Fluorescing agent 
                   0-5% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing to a temperature in the range of 860° to 900° C. to form an opaqued metal substructure. 
       
     
     
         12 . The method of  claim 11 , wherein the opaque composition is in powder or paste form prior to being fired. 
     
     
         13 . The method of  claim 11 , wherein the opaque composition is applied to the metal substructure by spraying, slurry dipping, or electro-depositing. 
     
     
         14 . The method of  claim 11 , further comprising the steps of:
 applying a porcelain composition over the opaqued substructure, the porcelain composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   63-66% 
                 
                     
                   Al 2 O 3   
                   10-14% 
                 
                     
                   Na 2 O 
                   3-7% 
                 
                     
                   K 2 O 
                    9-12% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   1-4% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing to a temperature in the range of 870° C. to 910° C. to form a dentin body layer over the opaque substructure, the dentin body layer being thermally compatible with the opaqued substructure. 
       
     
     
         15 . The method of  claim 14 , further comprising the steps of:
 applying a shade stain composition and/or a glaze composition, each including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   56-64% 
                 
                     
                   Al 2 O 3   
                    6-13% 
                 
                     
                   Na 2 O 
                    7-15% 
                 
                     
                   K 2 O 
                    7-15% 
                 
                     
                   Li 2 O 
                   0-5% 
                 
                     
                   CaO 
                   0-3% 
                 
                     
                   MgO 
                   2-5% 
                 
                     
                   SnO 2   
                   0-4% 
                 
                     
                   Tb 4 O 7   
                   0-3% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   B 2 O 3   
                   0-5% 
                 
                     
                   Sb 2 O 3   
                     0-0.5% 
                 
                     
                   F 
                     0-2.5% 
                 
                     
                   TiO 2   
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing at a temperature in the range of 780° to 840° C. to form a shade stain and/or glaze layer over the dentin body layer, the shade stain and/or glaze layer being thermally compatible and thermally stable with the dentin body layer. 
       
     
     
         16 . The method of  claim 11 , further comprising the steps of:
 applying a veneering porcelain composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   62-65% 
                 
                     
                   Al 2 O 3   
                    8-11% 
                 
                     
                   Na 2 O 
                    8-11% 
                 
                     
                   K 2 O 
                   4-7% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   2-5% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   MgO 
                   1-4% 
                 
                     
                   SnO 2   
                   0-2% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   Sb 2 O 3   
                   0-2% 
                 
                     
                   P 2 O 5   
                     0-0.1% 
                 
                     
                   TiO 2   
                     0-0.1% 
                 
                     
                   F 
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing at a temperature in the range of 810° C. to 860° C. to form a dentin-enamel layer over the opaqued substructure, the dentin-enamel layer being thermally compatible with the opaqued substructure. 
       
     
     
         17 . The method of  claim 16 , wherein the later applied dentin-enamel layer is applied by a hot pressing technique or hand build-up technique. 
     
     
         18 . The method of  claim 16 , further comprising the steps of:
 applying a glaze composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   56-64% 
                 
                     
                   Al 2 O 3   
                    6-13% 
                 
                     
                   Na 2 O 
                    7-15% 
                 
                     
                   K 2 O 
                    7-15% 
                 
                     
                   Li 2 O 
                   0-5% 
                 
                     
                   CaO 
                   0-3% 
                 
                     
                   MgO 
                   2-5% 
                 
                     
                   SnO 2   
                   0-4% 
                 
                     
                   Tb 4 O 7   
                   0-3% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   B 2 O 3   
                   0-5% 
                 
                     
                   Sb 2 O 3   
                     0-0.5% 
                 
                     
                   F 
                     0-2.5% 
                 
                     
                   TiO 2   
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing to a temperature in the range of 780° to 840° C. to form a glaze overlayer over the fired dentin-enamel layer, the glaze overlayer being thermally compatible with the dentin-enamel layer. 
       
     
     
         19 . The method of  claim 14 , further comprising the steps of:
 applying a veneering porcelain composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   62-65% 
                 
                     
                   Al 2 O 3   
                    8-11% 
                 
                     
                   Na 2 O 
                    8-11% 
                 
                     
                   K 2 O 
                   4-7% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   2-5% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   MgO 
                   1-4% 
                 
                     
                   SnO 2   
                   0-2% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   Sb 2 O 3   
                   0-2% 
                 
                     
                   P 2 O 5   
                     0-0.1% 
                 
                     
                   TiO 2   
                     0-0.1% 
                 
                     
                   F 
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing at a temperature in the range of 810° C. to 860° C. to form an enamel layer over the dentin body layer, the enamel layer being thermally compatible with the opaqued metal substructure and the dentin body layer. 
       
     
     
         20 . The porcelain composition of  claim 19 , wherein the later applied dentin-enamel layer is applied by a hand build-up technique. 
     
     
         21 . The method of  claim 19 , further comprising the steps of:
 applying a glaze composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   56-64% 
                 
                     
                   Al 2 O 3   
                    6-13% 
                 
                     
                   Na 2 O 
                    7-15% 
                 
                     
                   K 2 O 
                    7-15% 
                 
                     
                   Li 2 O 
                   0-5% 
                 
                     
                   CaO 
                   0-3% 
                 
                     
                   MgO 
                   2-5% 
                 
                     
                   SnO 2   
                   0-4% 
                 
                     
                   Tb 4 O 7   
                   0-3% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   B 2 O 3   
                   0-5% 
                 
                     
                   Sb 2 O 3   
                     0-0.5% 
                 
                     
                   F 
                     0-2.5% 
                 
                     
                   TiO 2   
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing to a temperature in the range of 780° to 840° C. to form a glaze layer over the fired enamel layer, the glaze overlayer being thermally compatible with the fired enamel layer. 
       
     
     
         22 . A method for making a dental prosthesis comprising the step of:
 providing an all ceramic core;   applying a porcelain composition over the ceramic core, the porcelain composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   63-66% 
                 
                     
                   Al 2 O 3   
                   10-14% 
                 
                     
                   Na 2 O 
                   3-7% 
                 
                     
                   K 2 O 
                    9-12% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   1-4% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing at a temperature in the range of 870° C. to 910° C. to form a dentin body layer over the ceramic core, the dentin body layer being thermally compatible with the ceramic core. 
       
     
     
         23 . The method of  claim 22 , further comprising the steps of:
 applying a porcelain composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   62-65% 
                 
                     
                   Al 2 O 3   
                    8-11% 
                 
                     
                   Na 2 O 
                    8-11% 
                 
                     
                   K 2 O 
                   4-7% 
                 
                     
                   Li 2 O 
                   0-2% 
                 
                     
                   CaO 
                   2-5% 
                 
                     
                   BaO 
                   0-3% 
                 
                     
                   MgO 
                   1-4% 
                 
                     
                   SnO 2   
                   0-2% 
                 
                     
                   Tb 4 O 7   
                   0-2% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   Sb 2 O 3   
                   0-2% 
                 
                     
                   P 2 O 5   
                     0-0.1% 
                 
                     
                   TiO 2   
                     0-0.1% 
                 
                     
                   F 
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing at a temperature in the range of 810° C. to 860° C. to form an enamel layer over the dentin body layer, the enamel layer being thermally compatible with the dentin body layer. 
       
     
     
         24 . The method of  claim 23 , further comprising the steps of:
 applying a glaze composition including the following components:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Oxide 
                   Concentration Range (Wt. %) 
                 
                     
                     
                 
                     
                   SiO 2   
                   56-64% 
                 
                     
                   Al 2 O 3   
                    6-13% 
                 
                     
                   Na 2 O 
                    7-15% 
                 
                     
                   K 2 O 
                    7-15% 
                 
                     
                   Li 2 O 
                   0-5% 
                 
                     
                   CaO 
                   0-3% 
                 
                     
                   MgO 
                   2-5% 
                 
                     
                   SnO 2   
                   0-4% 
                 
                     
                   Tb 4 O 7   
                   0-3% 
                 
                     
                   CeO 2   
                   0-2% 
                 
                     
                   B 2 O 3   
                   0-5% 
                 
                     
                   Sb 2 O 3   
                     0-0.5% 
                 
                     
                   F 
                     0-2.5% 
                 
                     
                   TiO 2   
                   0-1% 
                 
                     
                     
                 
             
                
                
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and firing to a temperature in the range of 780° to 840° C. to form a glaze layer over the fired enamel layer, the glaze layer being thermally compatible with the fired enamel layer.

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