Seamless fuser member process

Abstract

Described herein is a method forming a belt suitable for use with an image forming system. The method includes coating a composition of a polyimide, a phosphate ester and a solvent onto an outer surface of a rotating metal belt, and subsequently curing and releasing the composition from the metal belt.

What is claimed is: 
     
         1 . A method of forming a seamless belt suitable for use with an image forming system, comprising:
 flow coating a composition of a polyimide, a phosphate ester internal release agent and a solvent onto and directly contacting an outer surface of a rotating substrate;   fully curing the coating at a temperature of from about 125° C. to about 190° C. for a time of from about 30 to about 90 minutes, and then at a temperature of from about 250° C. to about 370° C. for a time of from about 30 to about 90 minutes to form a seamless belt;   removing the fully cured belt from the rotating substrate.   
     
     
         2 . The method of  claim 1 , wherein the composition further comprises a polysiloxane polymer selected from the group consisting of a polyester modified polydimethylsiloxane, a polyether modified polydimethylsiloxane, a polyacrylate modified polydimethylsiloxane, and a polyester polyether modified polydimethylsiloxane. 
     
     
         3 . The method of  claim 1 , wherein the phosphate ester is selected from the group consisting of an alkyl alcohol ethoxylate phosphate, an alkyl phenol ethoxylate phosphate, an alkyl polyethoxyethanol phosphate, and an alkylphenoxy polyethoxyethanol phosphate, and said polyimide and said phosphate ester are present in a weight ratio of about 20/80 to about 80/20. 
     
     
         4 . The method of  claim 1 , wherein the solvent is selected from the group consisting of tetrahydrofuran, methyl ethyl ketone, methyl isobutyl ketone, N,N′-dimethylformamide, N,N′-dimethylacetamide, N-methylpyrrolidone and methylene chloride. 
     
     
         5 . The method of  claim 1 , further comprising:
 coating an intermediate layer on an outer layer of the cured belt, wherein said intermediate layer comprises silicone.   
     
     
         6 . The method of  claim 5 , further comprising:
 coating a release layer on the intermediate layer, wherein said release layer comprises fillers and a fluoropolymer.   
     
     
         7 . The method of  claim 6 , wherein the fillers are selected from the group consisting of carbon blacks, carbon nanotubes, metal oxides, doped metal oxides, polyanilines, polythiophenes, polyacetylene, poly(p-phenylene vinylene), poly(p-phenylene sulfide), pyrroles, polyindole, polypyrene, polycarbazole, polyazulene, polyazepine, poly(fluorine), polynaphthalene, salts of organic sulfonic acid, esters of phosphoric acid, esters of fatty acids, ammonium or phosphonium salts, and mixtures thereof, and wherein the fluoropolymer comprises a fluoroelastomer or a fluoroplastic. 
     
     
         8 . The method of  claim 1 , wherein the substrate comprises a metal belt, said belt possessing an Ra of from about 0.01 micron to about 0.5 microns and an R max  of from about 0.02 micron to about 4 microns. 
     
     
         9 . A method of forming a seamless fuser member, comprising:
 flow coating a composition of a polyimide, a phosphate ester internal release agent, a polysiloxane polymer and a solvent onto and directly contacting an outer surface of a rotating substrate;   flow coating a composition of a polyimide, a phosphate ester internal release agent and a solvent onto and directly contacting an outer surface of a rotating substrate;   fully curing the coating at a temperature of from about 125° C. to about 190° C. for a time of from about 30 to about 90 minutes, and then at a temperature of from about 250 ° C. to about 370° C. for a time of from about 30 to about 90 minutes to form a seamless belt;   removing the fully cured belt from the rotating substrate;   coating a intermediate layer on an outer layer of the cured belt; and   coating a release layer on the intermediate layer.   
     
     
         10 . The method of  claim 9 , wherein the solvent is selected from the group consisting of tetrahydrofuran, methyl ethyl ketone, methyl isobutyl ketone, N,N′-dimethylformamide, N,N′-dimethylacetamide, N-methylpyrrolidone and methylene chloride. 
     
     
         11 . The method of  claim 9 , wherein the polysiloxane polymer is selected from the group consisting of a polyester modified polydimethylsiloxane, a polyether modified polydimethylsiloxane, a polyacrylate modified polydimethylsiloxane, and a polyester polyether modified polydimethylsiloxane. 
     
     
         12 . The method of  claim 9 , wherein the phosphate ester is selected from the group consisting of an alkyl alcohol ethoxylate phosphate, an alkyl phenol ethoxylate phosphate, an alkyl polyethoxyethanol phosphate, and an alkylphenoxy polyethoxyethanol phosphate. 
     
     
         13 . The method of  claim 9 , wherein the substrate comprises a metal belt, said belt possessing an Ra of from about 0.01 micron to about 0.5 microns and an R max  of from about 0.02 micron to about 4 microns. 
     
     
         14 . A method of forming a seamless belt suitable for use with an image forming system, comprising:
 flow coating a composition of a polyimide, a phosphate ester internal release agent, a polysiloxane polymer and a solvent onto and directly contacting an outer surface of a rotating substrate wherein the rotating substrate comprises a metal belt, said metal belt possessing an Ra of from about 0.01 micron to about 0.5 microns and an R max  of from about 0.02 micron to about 4 microns;   fully curing the coating at a temperature of from about 125° C. to about 190° C. for a time of from about 30 to about 90 minutes, and then at a temperature of from about 250° C. to about 370° C. for a time of from about 30 to about 90 minutes to form a seamless belt;   removing the fully cured belt from the rotating substrate.   
     
     
         15 . The method of  claim 14 , wherein the composition further comprises a polysiloxane polymer selected from the group consisting of a polyester modified polydimethylsiloxane, a polyether modified polydimethylsiloxane, a polyacrylate modified polydimethylsiloxane, and a polyester polyether modified polydimethylsiloxane. 
     
     
         16 . The method of  claim 14 , wherein the phosphate ester is selected from the group consisting of an alkyl alcohol ethoxylate phosphate, an alkyl phenol ethoxylate phosphate, an alkyl polyethoxyethanol phosphate, and an alkylphenoxy polyethoxyethanol phosphate, and said polyimide and said phosphate ester are present in a weight ratio of about 20/80 to about 80/20. 
     
     
         17 . The method of  claim 14 , wherein the solvent is selected from the group consisting of tetrahydrofuran, methyl ethyl ketone, methyl isobutyl ketone, N,N′-dimethylformamide, N,N′-dimethylacetamide, N-methylpyrrolidone and methylene chloride. 
     
     
         18 . The method of  claim 14 , further comprising:
 coating an intermediate layer on an outer layer of the cured belt, wherein said intermediate layer comprises silicone.   
     
     
         19 . The method of  claim 18 , further comprising:
 coating a release layer on the intermediate layer, wherein said release layer comprises fillers and a fluoropolymer.   
     
     
         20 . The method of  claim 19 , wherein the fillers are selected from the group consisting of carbon blacks, carbon nanotubes, metal oxides, doped metal oxides, polyanilines, polythiophenes, polyacetylene, poly(p-phenylene vinylene), poly(p-phenylene sulfide), pyrroles, polyindole, polypyrene, polycarbazole, polyazulene, polyazepine, poly(fluorine), polynaphthalene, salts of organic sulfonic acid, esters of phosphoric acid, esters of fatty acids, ammonium or phosphonium salts, and mixtures thereof; and wherein the fluoropolymer comprises a fluoroelastomer or a fluoroplastic.