Process and System for Production of Synthesis Gas

Abstract

Methods and apparatus may permit the generation of consistent output synthesis gas from highly variable input feedstock solids carbonaceous materials. A stoichiometric objectivistic chemic environment may be established to stoichiometrically control carbon content in a solid carbonaceous materials gasifier system. Processing of carbonaceous materials may include dominative pyrolytic decomposition and multiple coil carbonaceous reformation. Dynamically adjustable process determinative parameters may be utilized to refine processing, including process utilization of negatively electrostatically enhanced water species, process utilization of flue gas, and adjustment of process flow rate characteristics. Recycling may be employed for internal reuse of process materials, including recycled negatively electrostatically enhanced water species, recycled flue gas, and recycled contaminants. Synthesis gas generation may involve predetermining a desired synthesis gas for output and creating high yields of such a predetermined desired synthesis gas.

1 - 50 . (canceled) 
     
     
         51 . A pyrolysis and gasification system, comprising: a feedstock hopper that receives a carbonaceous feedstock; and a tapered pyrolysis drum that rotates about an axis and drives off carbon based volatiles contained in the carbonaceous feedstock. 
     
     
         52 . The system of  claim 51 , the pyrolysis and gasification system increases heat transfer to the carbonaceous feedstock through use of internal flights within the tapered pyrolysis drum. 
     
     
         53 . The system of  claim 51 , further comprising a first counter-operating pressure valve and a second counter-operating pressure valve. 
     
     
         54 . The system of  claim 53 , the first counter-operating pressure valve and the second counter-operating pressure valve maintain a pressure of at least 50 pounds per square inch (psi) within the pyrolysis and gasification system. 
     
     
         55 . The system of  claim 53 , the first counter-operating pressure valve and the second counter-operating pressure valve maintain a pressure of at least 250 pounds per square inch (psi) within the pyrolysis and gasification system. 
     
     
         56 . The system of  claim 53 , further comprising an airlock vessel disposed between the first counter-operating pressure valve and the second counter-operating pressure valve. 
     
     
         57 . The system of  claim 56 , the airlock vessel holds a charge of feedstock received from the feedstock hopper. 
     
     
         58 . The system of  claim 56 , the airlock vessel draws in a vacuum that evacuates oxygen introduced into the airlock vessel when feedstock is introduced into the airlock vessel. 
     
     
         59 . The system of  claim 58 , the vacuum is drawn through a venturi on steam generated or cooling water loops. 
     
     
         60 . The system of  claim 53 , further comprising an accumulation chamber located after the second counter-operating pressure valve. 
     
     
         61 . The system of  claim 60 , the accumulation chamber includes a plunger/auger that advances a charge of feedstock into the tapered pyrolysis drum. 
     
     
         62 . The system of  claim 63 , further comprises a cooling jacket that surrounds a pipe connecting the second counter-operating pressure valve and an accumulation chamber. 
     
     
         63 . The system of  claim 62 , the cooling jacket utilizes cooling water passed through the cooling jacket to dissipate heat or prevent the second counter-operating pressure valve from overheating. 
     
     
         64 . The system of  claim 51 , the tapered pyrolysis drum is connected to an accumulation chamber via a mechanical seal. 
     
     
         65 . The system of  claim 64 , superheated steam is introduced into the accumulation chamber via a port in the accumulation chamber. 
     
     
         66 . The system of  claim 65 , the superheated steam is heated to at least 1750 .degree. F. 
     
     
         67 . The system of  claim 51 , the tapered pyrolysis drum includes a neck that protrudes beyond a refractory lined enclosure. 
     
     
         68 . The system of  claim 67 , the neck rests on a load bearing roller. 
     
     
         69 . The system of  claim 68 , a cam follower bearing is located outside the refractory lined enclosure and is disposed perpendicular to the load bearing roller. 
     
     
         70 . The system of  claim 69 , the cam follower bearing restricts movement or direct linear growth of the tapered pyrolysis drum in one direction. 
     
     
         71 . The system of  claim 67 , the tapered pyrolysis drum enclosed within the refractory line enclosure. 
     
     
         72 . The system of  claim 67 , the refractory lined enclosure includes at least one burner that provides thermal energy to the pyrolysis and gasification system. 
     
     
         73 . The system of  claim 67 , the refractory lined enclosure constructed to sustain a pressure of at least 50 psi, creating a pressure over pressure environment within the tapered pyrolysis drum. 
     
     
         74 . The system of  claim 67 , the refractory lined enclosure fabricated to maintain pressured of at least 15 psi or less than 49.9 psi, creating a partial pressure over pressure environment within the tapered pyrolysis drum. 
     
     
         75 . The system of  claim 74 , the partial pressure over pressure environment within the tapered pyrolysis drum established by a compressor or a fan employed to build up pressure. 
     
     
         76 . The system of  claim 74 , the partial pressure over pressure environment within the tapered pyrolysis drum established by siphoning off exhaust gas from the refractory lined enclosure and directing the exhaust gas to a gas turbine to create shaft horsepower. 
     
     
         77 . The system of  claim 76 , the shaft horsepower utilized to spin a device that compresses ambient air or combustion air, wherein the compressed ambient air or combustion air is fed back to the refractory lined enclosure to build up or sustain the partial pressure over pressure environment established in the tapered pyrolysis drum. 
     
     
         78 . The system of  claim 67 , the refractory lined enclosure constructed to maintain a pressure of at least 14.5 psi, wherein the refractory lined enclosure is constructed of mild steel. 
     
     
         79 . The system of  claim 67 , the refractory lined enclosure is manufactured to operate at atmospheric pressure. 
     
     
         80 . The system of  claim 67 , heat vented from the refractory line enclosure is employed for steam generation or power production. 
     
     
         81 . The system of  claim 51 , a mechanical seal is utilized between the tapered pyrolysis drum and stationary portions of the pyrolysis and gasification system. 
     
     
         82 . The system of  claim 81 , the mechanical seal operates to maintain a working pressure within the tapered pyrolysis drum. 
     
     
         83 . The system of  claim 51 , the tapered pyrolysis drum rotated about an axis by an electric motor connected to a chain and sprocket. 
     
     
         84 . The system of  claim 51 , the tapered pyrolysis drum conveys carbonaceous feedstock from an input end to a discharge end of the tapered pyrolysis drum via internal flights. 
     
     
         85 . The system of  claim 51 , the tapered pyrolysis drum is constructed to ensure that no shelf is created when a diameter of the tapered pyrolysis drum constricts back to an exit gas pipe size. 
     
     
         86 . The system of  claim 51 , fully pyrolyzed or partially pyrolyzed carbonaceous feedstock exits from a discharge end of the tapered pyrolysis drum at a temperature of more than 1450 .degree. F. and less than 1700 .degree. F. 
     
     
         87 . The system of  claim 86 , the discharge end includes a neck that rests on a load bearing roller, the neck is connected to a stationary piece of the gasification and pyrolysis system through a mechanical seal located external to a refractory lined vessel, the neck rotatable around an axis on the load bearing roller. 
     
     
         88 . The system of  claim 87 , product gas exits from the tapered pyrolysis drum into a steam reformer. 
     
     
         89 . The system of  claim 87 , partially pyrolyzed carbonaceous feedstock transitions via an auger to a secondary solids reactor, the secondary solids reactor employed to complete conversion of the partially pyrolyzed carbonaceous feedstock into syngas. 
     
     
         90 . The system of  claim 89 , further comprising a selective particulate entrapment component that employs a venturi placed between the tapered pyrolysis drum and a secondary solids reactor, wherein the venturi captures particles below a specified micro size in an entrained flow of gas and steam entering a reforming reactor. 
     
     
         91 . An apparatus operable in a carbonaceous gasification environment, comprising: a hopper that supplies a carbonaceous feedstock through an airlock vessel that removes entrapped air from the carbonaceous feedstock; and a tapered pyrolysis drum that receives the carbonaceous feedstock from the airlock vessel, the tapered pyrolysis drum includes an internal flight that increases heat transfer to the carbonaceous feedstock. 
     
     
         92 . A method, comprising: introducing feedstock material to a charge end of a tapered pyrolysis drum; rotating the tapered pyrolysis drum to advance the feedstock material from the charge end of the tapered pyrolysis drum to a discharge end of the tapered pyrolysis drum; heating the feedstock within the tapered pyrolysis drum, wherein a degree of heat applied at the charge end of the tapered pyrolysis drum is less than the degree of heat applied at the discharge end of the tapered pyrolysis drum; and evacuating from the discharge end of the tapered pyrolysis drum product gas, and fully pyrolyzed, or partially pyrolyzed, feedstock material.