US2014024807A1PendingUtilityA1

Lenalidomide and Thalidomide Immunoassays

Assignee: SALADAX BIOMEDICAL INCPriority: Mar 12, 2010Filed: Mar 28, 2013Published: Jan 23, 2014
Est. expiryMar 12, 2030(~3.7 yrs left)· nominal 20-yr term from priority
C07D 401/14C07D 401/04C07K 16/44G01N 33/5308Y10S436/815G01N 33/9453
64
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Claims

Abstract

Novel conjugates and immunogens derived from lenalidomide and antibodies generated by these immunogens are useful in immunoassays for the quantification and monitoring of thalidomide and lenalidomide in biological fluids.

Claims

exact text as granted — not AI-modified
1 - 35 . (canceled) 
     
     
         36 . A compound of the formula: 
       
         
           
           
               
               
           
         
         wherein B is —C(═O)—CH 2 —, —C(═O)—NH—CH 2 —, —C(═O)—O—CH 2 — or —CH 2 — Y is an organic spacing group; 
         p is an integer from 0 to 1; 
         X is a terminal functional group capable of binding to said polyamine polymer; 
       
     
     
         37 . The compound of  claim 36  wherein p is 0. 
     
     
         38 . The compound of  claim 37 , wherein X is 
       
         
           
           
               
               
           
         
       
       wherein R 3  is hydrogen or taken together with its attached oxygen atom forms a reactive ester and R 4  is oxygen or sulfur. 
     
     
         39 . The compound of  claim 38  wherein X is 
       
         
           
           
               
               
           
         
       
     
     
         40 . The compound of  claim 38 , wherein X is 
       
         
           
           
               
               
           
         
       
       and R 3  is hydrogen. 
     
     
         41 . The compound of  claim 38 , wherein X is 
       
         
           
           
               
               
           
         
       
       and R 3  forms a reactive ester. 
     
     
         42 . The compound of  claim 41 , wherein the ester formed is a lower alkyl ester, imidoester or amidoester. 
     
     
         43 . The compound of  claim 36 , wherein p is 1. 
     
     
         44 . The compound of  claim 43  wherein B is —C(═O)—CH 2 —. 
     
     
         45 . The compound of  claim 43 , wherein X is 
       
         
           
           
               
               
           
         
       
       wherein R 3  is hydrogen or taken together with its attached oxygen atom forms a reactive ester and R 4  is oxygen or sulfur. 
     
     
         46 . The compound of  claim 45 , wherein Y is alkylene containing from 1 to 10 carbon atoms, 
       
         
           
           
               
               
           
         
       
       wherein n and o are integers from 0 to 6, and m is an integer from 1 to 6. 
     
     
         47 . The compound of  claim 46 , wherein Y is lower alkylene containing from 1 to 6 carbon atoms. 
     
     
         48 . The compound of  claim 44 , wherein X is 
       
         
           
           
               
               
           
         
       
       and R 3  is as above. 
     
     
         49 . The compound of  claim 48  wherein OR 3  forms a hydroxy succinimide ester. 
     
     
         50 . The compound of  claim 46 , wherein Y is 
       
         
           
           
               
               
           
         
       
       wherein m and o are as above. 
     
     
         51 . The compound of  claim 50 , wherein X is 
       
         
           
           
               
               
           
         
       
       and R 3  is as above. 
     
     
         52 . The compound of  claim 51  wherein OR 3  forms a sulfo-N-hydroxy succinimide ester. 
     
     
         53 . A conjugate comprising a carrier conjugated with a ligand of the formula: 
       
         
           
           
               
               
           
         
         Wherein B is —C(═O)—CH 2 —, —C(═O)—NH—CH 2 —, —C(═O)—O—CH 2 — or —CH 2 — Y is an organic spacing group; 
         p is an integer from 0 to 1; 
         X is a terminal functional group capable of binding to a carrier; 
       
     
     
         54 . The conjugate of  claim 53 , wherein the carrier is an immunogenic carrier which contains a polyamine polymer and X is a terminal functional group capable of binding to said polyamine polymer. 
     
     
         55 . The conjugate of  claim 53 , wherein p is 0. 
     
     
         56 . The conjugate of  claim 55 , wherein X is 
       
         
           
           
               
               
           
         
       
       wherein R 3  is hydrogen or taken together with its attached oxygen atom forms a reactive ester and R 4  is oxygen or sulfur. 
     
     
         57 . The conjugate of  claim 53 , wherein p is 1. 
     
     
         58 . The conjugate of  claim 57 , wherein Y is alkylene containing from 1 to 10 carbon atoms, 
       
         
           
           
               
               
           
         
       
       wherein n and o are integers from 0 to 6, and m is an integer from 1 to 6. 
     
     
         59 . The conjugate of  claim 58 , wherein X is 
       
         
           
           
               
               
           
         
       
       wherein R 3  is hydrogen or taken together with its attached oxygen atom forms a reactive ester and R 4  is oxygen or sulfur. 
     
     
         60 . The conjugate of  claim 57 , wherein the carrier is an immunogenic carrier which contains a polyamine polymer and X is a terminal functional group capable of binding to said polyamine polymer 
     
     
         61 . The conjugate of  claim 60  wherein Y is an alkylene containing from 1 to 6 carbon atoms. 
     
     
         62 . The conjugate of  claim 61 , wherein X is 
       
         
           
           
               
               
           
         
       
       and R 3  is as above. 
     
     
         63 . The conjugate of  claim 60 , wherein Y is 
       
         
           
           
               
               
           
         
       
       wherein m and o are as above. 
     
     
         64 . The conjugate of  claim 63 , wherein X is 
       
         
           
           
               
               
           
         
       
       and R 3  is as above. 
     
     
         65 - 80 . (canceled)

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