Compositions and methods for nail coatings

Abstract

The present disclosure relates generally to compositions for natural and artificial nail coatings, and particularly, but not by way of limitation, to polymerizable compositions and adhesion-promoting basecoats polymerized therefrom. The disclosure further relates to methods of making a polymerized basecoat that are more easily removed than artificial nail enhancements and more durable and long lasting than nail polish coatings.

1 . A polymerizable composition comprising:
 at least one reactive (meth)acrylate;   at least one reactive urethane (meth)acrylate;   at least one reactive polypropylene glycol monomethacrylate;   at least one polymethylmethacrylate (PMMA)—polymethacrylic acid (PMAA) copolymer;   at least one pyromellitic dianhydride glyceryl dimethacrylate (PMGDM);   at least one non-reactive, solvent-dissolvable polymer; and   at least one non-reactive solvent;   wherein upon exposure to actinic radiation, said polymerizable composition cures to   an acrylic thermoset having voids defined therein, said voids containing said at least   one non-reactive, solvent-dissolvable polymer.   
     
     
         2 . The polymerizable composition of  claim 1 , wherein said at least one non-reactive, solvent-dissolvable polymer is a cellulose ester. 
     
     
         3 . The polymerizable composition of  claim 2 , wherein said cellulose ester is a cellulose acetate alkylate. 
     
     
         4 . The polymerizable composition of  claim 3 , wherein said cellulose acetate alkylate is selected from the group consisting of cellulose acetate butyrate, cellulose acetate propionate, and mixtures thereof. 
     
     
         5 . (canceled) 
     
     
         6 . (canceled) 
     
     
         7 . (canceled) 
     
     
         8 . (canceled) 
     
     
         9 . (canceled) 
     
     
         10 . The polymerizable composition of  claim 1 , wherein said at least one at least one urethane (meth)acrylate has a molecular weight (grams/mole) of from about 100 to about 20,000. 
     
     
         11 . The polymerizable composition of  claim 10 , wherein said at least one at least one urethane (meth)acrylate has a molecular weight of from about 200 to about 10,000. 
     
     
         12 . The polymerizable composition of  claim 11 , wherein said at least one at least one urethane (meth)acrylate has a molecular weight of from about 300 to about 5,000. 
     
     
         13 . The polymerizable composition of  claim 12 , wherein said at least one at least one urethane (meth)acrylate has a molecular weight of from about 300 to about 1,000. 
     
     
         14 . The polymerizable composition of  claim 1 , wherein said at least one solvent is selected from the group consisting of ketones, alkyl acetates, alcohols, alkanes, alkenes, and mixtures thereof. 
     
     
         15 . The polymerizable composition of  claim 14 , wherein said at least one non-reactive solvent is selected from the group consisting of acetone, ethyl acetate, butyl acetate, isopropyl alcohol, ethanol, methyl ethyl ketone, toluene, hexane, and mixtures thereof. 
     
     
         16 . The polymerizable composition of  claim 1 , wherein said at least one solvent is included at up to about 70 weight percent. 
     
     
         17 . The polymerizable composition of  claim 1 , further comprising at least one photoinitiator. 
     
     
         18 . The polymerizable composition of  claim 17 , wherein said at least one photoinitiator is selected from the group consisting of benzoylphenylphosphinates, cyclohexylphenyl ketones, benzyl ketals, and mixtures thereof. 
     
     
         19 . The polymerizable composition of  claim 17 , wherein said at least one photoinitiator is selected from the group consisting of 2,4,6-trimethylbenzoyldiphenylphosphinate, hydroxycyclohexyl phenyl ketone, benzyl dimethyl ketal, and mixtures thereof. 
     
     
         20 . The polymerizable composition of  claim 17 , wherein said at least one photoinitiator is present at up to about 10 wt %. 
     
     
         21 . (canceled) 
     
     
         22 . (canceled) 
     
     
         23 . (canceled) 
     
     
         24 . (canceled) 
     
     
         25 . A method of making an acrylic thermoset having a plurality of thermoplastic inclusions defined therein, comprising:
 providing a polymerizable liquid composition; and,   exposing said polymerizable liquid composition to an actinic radiation;   wherein said polymerizable liquid composition comprises:
 at least one (meth)acrylate; 
   at least one urethane (meth)acrylate;   at least one polypropylene glycol monomethacrylate;   at least one polymethylmethacrylate (PMMA)—polymethacrylic acid (PMAA) copolymer;   at least one pyromellitic dianhydride glyceryl dimethacrylate (PMGDM);   at least one non-reactive, solvent-dissolvable polymer; and   at least one non-reactive solvent.