US2014140883A1PendingUtilityA1

Quench and temper corrosion resistant steel alloy

Assignee: CRS HOLDINGS INCPriority: Oct 24, 2012Filed: Oct 24, 2013Published: May 22, 2014
Est. expiryOct 24, 2032(~6.3 yrs left)· nominal 20-yr term from priority
Inventors:David E. Wert
C21D 8/00C21D 7/13C21D 6/004C21D 2211/008C21D 6/04C21D 2211/004C22C 38/005C22C 38/06C22C 38/002C22C 38/42C22C 38/48C22C 38/50C22C 38/44C22C 38/04C21D 9/0075C22C 38/02C22C 38/52B64C 9/02C22C 38/001B64C 25/00C21D 1/18C22C 38/46B22F 1/00C22C 38/60
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Claims

Abstract

A quench and temper steel alloy is disclosed having the following composition in weight percent. C 0.2-0.5 Mn 0.1-1.0 Si 0.1-1.2 Cr   9-14.5 Ni 3.0-5.5 Mo 1-2 Cu   0-1.0 Co 1-4 W 0.2 max. V 0.1-1.0 Ti up to 0.5 Nb   0-0.5 Ta   0-0.5 Al   0-0.25 Ce   0-0.01 La   0-0.01 The balance of the alloy is iron and the usual impurities including not more than about 0.01% phosphorus, not more than about 0.010% sulfur, and not more than about 0.10% nitrogen. A quenched and tempered steel article made from this alloy is also disclosed. The steel article is characterized by a tensile strength of at least about 290 ksi, a fracture toughness (K Ic ) of at least about 65 ksi, good resistance to general corrosion, and good resistance to pitting corrosion.

Claims

exact text as granted — not AI-modified
1 . A steel alloy comprising, in weight percent, about: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C  
                   0.2-0.5 
                 
                     
                   Mn 
                   0.1-1.0 
                 
                     
                   Si 
                   0.1-1.2 
                 
                     
                   Cr 
                     9-14.5 
                 
                     
                   Ni 
                   3.0-5.5 
                 
                     
                   Mo 
                   1-2 
                 
                     
                   Cu 
                   up to 1.0 
                 
                     
                   Co  
                   1-4 
                 
                     
                   V 
                   0.1-1.0 
                 
                     
                   Ti 
                   up to 0.5 
                 
                     
                   Al 
                     0-0.25 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         the balance of the alloy is iron and usual impurities including not more than about 0.01% phosphorus, not more than about 0.001% sulfur, and not more than about 0.10% nitrogen. 
       
     
     
         2 . The alloy set forth in  claim 1  which contains up to about 0.5% niobium and/or tantalum. 
     
     
         3 . The alloy as set forth in  claim 2  which contains up to about 0.01% cerium and up to about 0.01% lanthanum. 
     
     
         4 . The alloy as set forth in  claim 1  which contains not more than about 0.05% nitrogen. 
     
     
         5 . The alloy set forth in  claim 1  which contains about 9.5-12.5% chromium. 
     
     
         6 . The alloy set forth in  claim 1  which contains about 1.25-1.75% molybdenum. 
     
     
         7 . The alloy set forth in  claim 1  which contains about 2-3% cobalt. 
     
     
         8 . The alloy set forth in  claim 1  which contains about 3.2-4.3% nickel. 
     
     
         9 . The alloy as set forth in  claim 1  which contains at least about 0.3% vanadium. 
     
     
         10 . The alloy as set forth in  claim 1  which contains at least about 0.01% titanium. 
     
     
         11 . The alloy as set forth in  claim 1  which contains at least about 0.1% copper. 
     
     
         12 . The alloy as set forth in  claim 11  which contains not more than about 0.7% copper. 
     
     
         13 . The alloy as set forth in  claim 1  which contains not more than about 0.01% copper and at least about 3.75% nickel. 
     
     
         14 . The alloy as set forth in  claim 13  which contains not more than about 4.0% nickel. 
     
     
         15 . A steel alloy consisting essentially of, in weight percent, about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                   0.35-0.45 
                 
                     
                   Mn 
                   0.1-0.7 
                 
                     
                   Si  
                   0.1-1.0 
                 
                     
                   Cr 
                    9.5-12.5 
                 
                     
                   Ni 
                   3.2-4.3 
                 
                     
                   Mo 
                   1.25-1.75 
                 
                     
                   Cu  
                   0.1-1.0 
                 
                     
                   Co 
                   2-3 
                 
                     
                   W 
                   up to 0.05 
                 
                     
                   V 
                   0.3-0.6 
                 
                     
                   Ti  
                   0.01-0.2  
                 
                     
                   Nb 
                   up to 0.01 
                 
                     
                   Ta 
                   up to 0.01 
                 
                     
                   Al 
                   0.01 max. 
                 
                     
                   Ce 
                     0-0.006 
                 
                     
                   La 
                     0-0.005 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance is iron and the usual impurities including not more than about 0.005% phosphorus, not more than about 0.001% sulfur, and not more than about 0.03% nitrogen. 
       
     
     
         16 . The alloy as set forth in  claim 15  which contains not more than about 0.7% copper. 
     
     
         17 . The alloy as set forth in  claim 15  which contains at least about 0.3% copper. 
     
     
         18 . A quenched and tempered steel article made from the alloy set forth in  claim 1  which has a tensile strength of at least 290 ksi. 
     
     
         19 . The steel article set forth in  claim 18  which has a fracture toughness (K Ic ) of at least about 65 ksi√in when tested in accordance with ASTM Standard Test Procedure E1290. 
     
     
         20 . The steel article set forth in  claim 19  which has sufficient general corrosion resistance such that the article does not rust after 200 hours when tested in accordance with ASTM Standard Test procedure B 117. 
     
     
         21 . The steel article as set forth in  claim 19  which has sufficient pitting corrosion resistance such that the article has a pitting potential of at least 90 mV when tested in accordance with ASTM Standard Test procedure G61 modified by using round bar samples. 
     
     
         22 . A structural component for an aerospace vehicle wherein the component is made from an alloy consisting essentially of, in weight percent, about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                   0.35-0.45 
                 
                     
                   Mn 
                   0.1-0.7 
                 
                     
                   Si 
                   0.1-1.0 
                 
                     
                   Cr 
                    9.5-12.5 
                 
                     
                   Ni 
                   3.2-4.3 
                 
                     
                   Mo 
                   1.25-1.75 
                 
                     
                   Cu 
                   0.1-0.7 
                 
                     
                   Co 
                   2-3 
                 
                     
                   W 
                    0.1 max. 
                 
                     
                   V  
                   0.3-0.6  
                 
                     
                   Ti 
                   0.01-0.2  
                 
                     
                   Nb 
                   0.01 max. 
                 
                     
                   Ta 
                   0.01 max. 
                 
                     
                   Al 
                   0.01 max. 
                 
                     
                   Ce 
                     0-0.006 
                 
                     
                   La 
                     0-0.005 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance is iron and the usual impurities including not more than about 0.005% phosphorus, not more than about 0.0005% sulfur, and not more than about 0.03% nitrogen. 
       
     
     
         23 . The aerospace structural component as set forth in  claim 22  wherein the component is selected from the group consisting of one or more of landing gear, a rotatable shaft, an actuator, flap tracks, and slat tracks.

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