US2014161658A1PendingUtilityA1

High Strength Precipitation Hardenable Stainless Steel

Assignee: CRS HOLDINGS INCPriority: Dec 6, 2012Filed: Dec 6, 2012Published: Jun 12, 2014
Est. expiryDec 6, 2032(~6.4 yrs left)· nominal 20-yr term from priority
C21D 6/04C21D 6/004C21D 6/02C21D 9/0068C22C 38/06C22C 38/04C22C 38/002C21D 2211/008C21D 1/06C22C 38/02C22C 38/001C22C 38/50C22C 38/54C22C 38/52C22C 38/44C22C 38/004C22C 38/48
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Claims

Abstract

A precipitation hardenable, martensitic stainless steel alloy is disclosed. The alloy has the following composition in weight percent, about C  0.03 max Mn  1.0 max Si  0.75 max P 0.040 max S 0.020 max Cr 10-13 Ni 10.5-11.6 Mo 0.25-1.5  Co 0.5-1.5 Cu  0.75 max Ti 1.5-1.8 Al 0.3-0.8 Nb 0.3-0.8 B 0.010 max N 0.030 max The balance is iron and usual impurities. The disclosed alloy provides a unique combination of corrosion resistance, strength, and toughness.

Claims

exact text as granted — not AI-modified
1 . A precipitation hardenable, martensitic stainless steel alloy having a unique combination of strength, toughness, and corrosion resistance comprising in weight percent, about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                    0.03 max 
                 
                     
                   Mn 
                    1.0 max 
                 
                     
                   Si 
                    0.75 max 
                 
                     
                   P 
                   0.040 max 
                 
                     
                   S 
                   0.020 max 
                 
                     
                   Cr 
                   10-13 
                 
                     
                   Ni 
                   10.5-11.6 
                 
                     
                   Mo 
                   0.25-1.5  
                 
                     
                   Cu 
                    0.75 max 
                 
                     
                   Co 
                   0.5-1.5 
                 
                     
                   Ti 
                   1.5-1.8 
                 
                     
                   Al 
                   0.3-0.8 
                 
                     
                   Cb 
                   0.3-0.8 
                 
                     
                   B 
                   0.010 max 
                 
                     
                   N 
                   0.030 max 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
       and the balance is iron and usual impurities. 
     
     
         2 . The alloy recited in  claim 1  which contains no more than about 0.50% copper. 
     
     
         3 . The alloy recited in  claim 1  which contains at least about 0.75% cobalt. 
     
     
         4 . The alloy recited in  claim 1  which contains at least about 0.4% columbium. 
     
     
         5 . The alloy recited in  claim 1  which contains at least about 10.75% nickel. 
     
     
         6 . The alloy recited in  claim 1  which contains at least about 0.4% aluminum. 
     
     
         7 . The alloy recited in  claim 1  which contains at least about 10.5% chromium. 
     
     
         8 . The alloy recited in  claim 1  which contains not more than about 12.5% chromium. 
     
     
         9 . The alloy recited in  claim 1  which contains not more than about 1.7% titanium. 
     
     
         10 . The alloy recited in  claim 1  which contains not more than about 1.25% molybdenum. 
     
     
         11 . The alloy recited in  claim 1  which contains at least about 0.75 weight percent molybdenum. 
     
     
         12 . The alloy recited in  claim 1  which contains up to about 0.003% calcium. 
     
     
         13 . The alloy recited in  claim 1  which contains up to about 0.025% cerium. 
     
     
         14 . A precipitation hardenable, martensitic stainless steel alloy having a good combination of corrosion resistance, strength, and toughness comprising in weight percent, about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                   0.02 max 
                 
                     
                   Mn 
                   0.25 max 
                 
                     
                   Si 
                   0.25 max 
                 
                     
                   P 
                   0.015 max  
                 
                     
                   S 
                   0.010 max  
                 
                     
                   Cr 
                   10.5-12.5 
                 
                     
                   Ni 
                   10.75-11.25 
                 
                     
                   Mo 
                   0.75-1.25 
                 
                     
                   Cu 
                   0.50 max 
                 
                     
                   Co 
                   0.75-1.25 
                 
                     
                   Ti 
                   1.5-1.7 
                 
                     
                   Al 
                   0.4-0.7 
                 
                     
                   Cb 
                   0.4-0.7 
                 
                     
                   B 
                   0.001-0.005 
                 
                     
                   N 
                   0.015 max  
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
       and the balance is iron and usual impurities. 
     
     
         15 . The alloy recited in  claim 14  which contains not more than about 1.1% cobalt. 
     
     
         16 . The alloy recited in  claim 14  which contains at least about 0.9% cobalt. 
     
     
         17 . The alloy recited in  claim 14  which contains at least about 10.85% nickel. 
     
     
         18 . The alloy recited in  claim 14  which contains not more than about 0.6% columbium. 
     
     
         19 . The alloy recited in  claim 14  which contains at least about 0.45% aluminum. 
     
     
         20 . The alloy recited in  claim 14  which contains not more than about 0.65% aluminum. 
     
     
         21 . The alloy recited in  claim 14  which contains at least about 0.9% molybdenum. 
     
     
         22 . The alloy recited in  claim 14  which contains up to about 0.003% calcium. 
     
     
         23 . The alloy recited in  claim 14  which contains up to about 0.025% cerium. 
     
     
         24 . A precipitation hardenable, martensitic stainless steel alloy having a good combination of corrosion resistance, strength, and toughness consisting essentially of, in weight percent, about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                   0.015 max 
                 
                     
                   Mn 
                    0.10 max 
                 
                     
                   Si 
                    0.10 max 
                 
                     
                   P 
                   0.010 max 
                 
                     
                   S 
                   0.005 max 
                 
                     
                   Cr 
                   11.0-12.0 
                 
                     
                   Ni 
                   10.85-11.25 
                 
                     
                   Mo 
                   0.9-1.1 
                 
                     
                   Co 
                   0.9-1.1 
                 
                     
                   Cu 
                    0.25 max 
                 
                     
                   Ti 
                   1.5-1.7 
                 
                     
                   Al 
                   0.45-0.65 
                 
                     
                   Cb 
                   0.4-0.6 
                 
                     
                   B 
                   0.0015-0.0035 
                 
                     
                   N 
                   0.010 max 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
       and the balance is iron and usual impurities. 
     
     
         25 . The alloy recited in  claim 24  which contains up to about 0.003% calcium. 
     
     
         26 . The alloy recited in  claim 24  which contains up to about 0.025% cerium.

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