Fabric adhesion improvement for epdm based low cost timing belt

Abstract

The present invention is directed to timing belts having improved fabric adhesion to the tooth facing which can be achieved by the use of a combination of a RFL treated fabric and an EPDM body provided the RFL treatment or the body include ZDA or the RF latex is an X-HNBR latex.

What is claimed is: 
     
         1 . A method of making a toothed belt comprising: (1) forming a body having a length, laterally spaced sides, and inside and an outside surface, and defining a plurality of teeth spaced in a lengthwise direction on one of the inside or the outside of the body, said body defining at least in part by a rubber composition comprising at least an ethylene propylene diene monomer terpolymer, (2) applying a cloth layer on the teeth on one of the inside or outside of the body and bonding said cloth layer to said body whereby the cloth layer is disposed on the surface of and adhered to the teeth, wherein the cloth layer is comprised of a cloth fabric selected from cotton fabrics, polyester fabrics, and polyamide fabrics, said cloth layer being treated with a solution of resorcin-formalin-latex, wherein the solution of resorcin-formalin-latex consists of a reaction product of resorcin and formalin, a carboxylated hydrogenated nitrile rubber latex, ammonia, optionally a wax, optionally urea, and optionally an antioxidant, wherein the mole ratio of the resorcin to the formalin is within the range of 1:1 to 1:3, and wherein the rubber composition and the solution for treating said cloth layer are void of metal salts of α,β-unsaturated organic acids. 
     
     
         2 . The method of  claim 1  wherein the rubber composition includes at least one reinforcing filler. 
     
     
         3 . The method of  claim 2  wherein the cloth layer is comprised of a cotton fabric. 
     
     
         4 . The method of  claim 1  wherein the cloth layer is comprised of a polyester fabric. 
     
     
         5 . The method of  claim 1  wherein the cloth layer is comprised of a polyamide fabric. 
     
     
         6 . The method of  claim 1  wherein the cloth layer is comprised of a nylon-66 fabric. 
     
     
         7 . The method of  claim 1  wherein the cloth fabric is made by plain weaving. 
     
     
         8 . The method of  claim 1  wherein the cloth fabric is made by twill weaving. 
     
     
         9 . The method of  claim 1  wherein the cloth fabric is made by satin weaving. 
     
     
         10 . The method of  claim 1  wherein the solution of resorcin-formalin-latex has a pH of at least 9.0. 
     
     
         11 . The method of  claim 2  wherein the reinforcing filler is present at a level which is within the range of 25 phr to 250 phr. 
     
     
         12 . The method of  claim 2  wherein the reinforcing filler is present at a level which is within the range of 25 phr to 100 phr. 
     
     
         13 . The method of  claim 12  wherein the reinforcing filler is carbon black. 
     
     
         14 . The method of  claim 12  wherein the reinforcing filler is calcium carbonate. 
     
     
         15 . The method of  claim 12  wherein the reinforcing filler is talc. 
     
     
         16 . The method of  claim 12  wherein the reinforcing filler is clay. 
     
     
         17 . The method of  claim 12  wherein the reinforcing filler is hydrated silica. 
     
     
         18 . The method of  claim 1  wherein the rubber composition defining the body of the belt consists of the ethylene propylene diene terpolymer. 
     
     
         19 . The method of  claim 18  wherein the cloth layer is comprised of is a single ply polyamide fabric. 
     
     
         20 . The method of  claim 18  wherein the cloth layer is comprised of is a single ply nylon-66 fabric.