Protective coating of silver

Abstract

In the method, silver is protected against tarnishing using an Atomic Layer Deposition method. In the Atomic Layer Deposition method, a thin film coating is formed on the surface of silver by depositing successive molecule layers of the coating material. For example aluminium oxide (Al 2 O 3 ) or zirconium oxide may be used as the coating material.

1 . A method for protecting silver products, articles or parts against tarnish in an atmosphere, the method consisting of applying a thin coating layer of protective material having a thickness between 2 nm to 20 nm on at least a part of an outer surface of a silver product, article or part using an ald (atomic layer deposition) method to prevent tarnishing of the outer surface of the silver product, article or part in the atmosphere. 
     
     
         2 . The method according to  claim 1 , wherein applying the thin coating layer comprises providing at least one layer of metal oxide using the ALD (Atomic Layer Deposition) method. 
     
     
         3 . The method according to  claim 2 , wherein the metal oxides comprise aluminum oxide Al 2 O 3 , titanium oxide TiO 2 , chromium oxide Cr 2 O 3 , zirconium oxide ZrO 2 , indium oxide In 2 O 3 , and niobium oxide Nb 2 O 5 . 
     
     
         4 . The method according to  claim 1 , wherein the thin coating layer is substantially transparent non-oxide material. 
     
     
         5 . The method according to  claim 1 , further comprising applying a substantially colorless coating layer on at least a part of the outer surface of the silver product, article or part. 
     
     
         6 . The method according to  claim 1 , further comprising applying said thin coating layer at a temperature, which is in a range of 80 to 400° C. 
     
     
         7 . The method according to  claim 1 , wherein the thin coating layer is produced on a multiple-part silver product after the product is assembled. 
     
     
         8 . The method according to  claim 1 , wherein the method is applied to silver jewelry, coins, medals, tableware, ornaments, silver products, or at least a part of an electronic or electrical component or other industrial component made of silver or silver alloys. 
     
     
         9 . The method according to  claim 1 , wherein the method is applied to products comprising several different materials in addition to silver. 
     
     
         10 . The method according to  claim 6 , comprising applying said thin coating layer at a temperature, which is in a range of 120 to 300° C. 
     
     
         11 . The method according to  claim 6 , comprising applying said thin coating layer at a temperature, which is 200° C. 
     
     
         12 . A method for protecting products comprising silver against tarnish in an atmosphere, the method comprising applying a thin coating of protective material having a thickness between 2 nm to 20 nm on at least a part of a product using an ALD (Atomic Layer Deposition) method to prevent tarnishing of the silver of the product in the atmosphere. 
     
     
         13 . A method for protecting silver products, articles or parts against tarnish in an atmosphere, the method comprising applying a thin coating of protective material having a thickness between 2 nm to 20 nm on at least a part of an outer surface of a silver product, article or part using an ALD (Atomic Layer Deposition) method to prevent tarnishing of an outer surface of the silver product, article or part in the atmosphere. 
     
     
         14 . The method according to  claim 13 , wherein the thin coating of protective material forms an outer surface of the silver product, article or part to prevent tarnishing of the outer surface of the silver product, article or part in the atmosphere.