Fibers and Nonwovens Including a Propylene Random Copolymer, and Processes for Producing the Fibers and Nonwovens

Abstract

Fibers can include a polypropylene composition, which can include a metallocene random copolymer of propylene and a comonomer that is an alpha-olefin different from propylene. The metallocene random copolymer can have a comonomer content of from 1.2 wt % to 1.8 wt %, a molecular weight distribution of at least 1.0 and of at most 4.0 obtained without thermal or chemical degradation, and a melting temperature T melt of at most 140° C. A nonwoven can include the fibers, and a laminate can include the nonwoven. The fibers can be produced by polymerizing the propylene and comonomer in presence of a metallocene-based polymerization catalyst to obtain the metallocene random copolymer. The polypropylene composition can be melt-extruded to obtain a molten polypropylene stream, which can be extruded from capillaries of a spinneret to obtain filaments. A diameter of the filaments can be rapidly reduced to obtain a final diameter.

1 - 15 . (canceled) 
     
     
         16 . Fibers comprising:
 a polypropylene composition comprising a metallocene random copolymer of propylene and at least one comonomer that is an alpha-olefin different from propylene, wherein said metallocene random copolymer has:   a comonomer content of from 1.4 wt % to 1.8 wt %, relative to a total weight of said metallocene random copolymer;   a molecular weight distribution, defined as M w /M n  and determined by size extrusion chromatography, of at least 1.0 and of at most 4.0, obtained without thermal or chemical degradation;   a melt flow index of at least 25 dg/min and at most 50 dg/min, determined according to ISO 1133, condition L, at 230° C. and 2.16 kg;   a melting temperature T melt , determined by Differential Scanning calorimetry according to ISO 3146, of at most 135° C.   
     
     
         17 . The fibers according to  claim 16 , wherein the metallocene random copolymer has a comonomer content ranging from at least 1.4 wt % to at most 1.7 wt %, relative to the total weight of said metallocene random copolymer. 
     
     
         18 . The fibers according to  claim 16 , wherein the alpha-olefin is selected from a group consisting of ethylene, butene-1, pentene-1, hexene-1, octene-1, and 4-methyl-pentene-1. 
     
     
         19 . (canceled) 
     
     
         20 . The fibers according to  claim 16 , wherein the metallocene random copolymer has a content of mmmm pentads of at least 90%. 
     
     
         21 . The fibers according to  claim 16 , wherein the metallocene random copolymer has at least 0.1% and at most 1.0% of 2,1-insertions, relative to the total number of propylene molecules. 
     
     
         22 . The fibers according to  claim 16 , wherein the metallocene random copolymer has at least 90 mole % of the at least one comonomer as isolated units. 
     
     
         23 . The fibers according to  claim 16 , wherein the polypropylene composition further comprises a thermoplastic polymer composition having components selected from propylene homopolymers and random copolymers of propylene and at least one comonomer, with the provision that said random copolymer of propylene and at least one comonomer comprised in said thermoplastic polymer composition is different from the metallocene random copolymer of propylene and at least one comonomer. 
     
     
         24 . A nonwoven comprising the fibers of  claim 16 . 
     
     
         25 . The nonwoven according to  claim 24 , wherein the nonwoven is selected from a group consisting of spunbond nonwoven, needlepunch nonwoven, and spunlaid nonwoven. 
     
     
         26 . A laminate comprising the nonwoven of  claim 24 . 
     
     
         27 . A process for the production of fibers comprising:
 (a) polymerizing propylene and at least one comonomer in presence of a metallocene-based polymerization catalyst, to obtain a metallocene random copolymer of propylene and at least one comonomer;   (b) melt-extruding a polypropylene composition comprising the metallocene random copolymer obtained in step (a) to obtain a molten polypropylene stream;   (c) extruding the molten polypropylene stream of step (c) from capillaries of a spinneret, thus obtaining filaments of molten polypropylene; and   (d) subsequently rapidly reducing a diameter of the filaments to obtain a final diameter;   wherein said metallocene random copolymer has a comonomer content of from 1.4 wt % to 1.8 wt %, relative to a total weight of said metallocene random copolymer;   wherein the at least one comonomer is an alpha-olefin different from propylene; and   wherein said metallocene random copolymer has a molecular weight distribution, defined as M w /M n  and determined by gel permeation chromatography, of from 1.0 to 3.0, obtained without thermal or chemical degradation.   
     
     
         28 . The process according to  claim 27 , further comprising:
 (e) collecting the filaments obtained in step (d) on a support; and   (f) subsequently bonding the collected filaments of step (e) to form a bonded nonwoven.   
     
     
         29 . The process according to  claim 27 , wherein the metallocene random copolymer has a comonomer content ranging from at least 1.4 wt % to at most 1.7 wt %, relative to the total weight of said metallocene random copolymer. 
     
     
         30 . The process according to  claim 27 , wherein the alpha-olefin is selected from a group consisting of ethylene, butene-1, pentene-1, hexene-1, octene-1, and 4-methyl-pentene-1. 
     
     
         31 . The process according to  claim 27 , wherein the metallocene random copolymer has a melt flow index of at least 15 dg/min and at most 100 dg/min, determined according to ISO 1133, condition L, at 230° C. and 2.16 kg. 
     
     
         32 . The process according to  claim 27 , wherein the metallocene random copolymer has a content of mmmm pentads of at least 90%. 
     
     
         33 . The process according to  claim 27 , wherein the metallocene random copolymer has at least 0.1% and at most 1.0% of 2,1-insertions, relative to the total number of propylene molecules. 
     
     
         34 . The process according to  claim 27 , wherein the metallocene random copolymer has at least 90 mole % of the at least one comonomer as isolated units. 
     
     
         35 . The process according to  claim 27 , wherein the polypropylene composition further comprises a thermoplastic polymer composition having components selected from propylene homopolymers and random copolymers of propylene and at least one comonomer, with the provision that said random copolymer of propylene and at least one comonomer comprised in said thermoplastic polymer composition is different from the metallocene random copolymer of propylene and at least one comonomer.