Pesticidal compositions

Abstract

This document discloses molecules having the following formula (“Formula I”):

We claim: 
     
         1 . A molecule having the following formula (“Formula I”): 
       
         
           
           
               
               
           
         
         wherein: 
         (a) X is N or CR8; 
         (b) R1 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, substituted or unsubstituted C 1 -C 20  heterocyclyl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R1, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, C 6 -C 20  aryl, or C 1 -C 20  heterocyclyl, (each of which that can be substituted, may optionally be substituted with R9); 
 
         (c) R2 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, substituted or unsubstituted C 1 -C 20  heterocyclyl, OR9, C(═X1)OR9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R2, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, C 6 -C 20  aryl, or C 1 -C 20  heterocyclyl, (each of which that can be substituted, may optionally be substituted with R9); 
 
         (d) R3 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, substituted or unsubstituted C 1 -C 20  heterocyclyl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R3, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, C 6 -C 20  aryl, or C 1 -C 20  heterocyclyl, (each of which that can be substituted, may optionally be substituted with R9); 
 
         (e) R4 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, substituted or unsubstituted C 1 -C 20  heterocyclyl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R4, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, C 6 -C 20  aryl, or C 1 -C 20  heterocyclyl, (each of which that can be substituted, may optionally be substituted with R9); 
 
         (f) R5 is H, substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, substituted or unsubstituted C 1 -C 20  heterocyclyl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, R9S(O) n R9, C 1 -C 6  alkyl C 6 -C 20  aryl (wherein the alkyl and aryl can independently be substituted or unsubstituted), C(═X2)R9, C(═X1)X2R9, R9×2C(═X1)R9, R9×2R9, C(═O)(C 1 -C 6  alkyl)S(O) n (C 1 -C 6  alkyl), C(═O)(C 1 -C 6  alkyl)C(═O)O(C 1 -C 6  alkyl), (C 1 -C 6  alkyl)OC(═O)(C 6 -C 20  aryl), (C 1 -C 6  alkyl)OC(═O)(C 1 -C 6  alkyl), C 1 -C 6  alkyl-(C 3 -C 10  cyclohaloalkyl), or (C 1 -C 6  alkenyl)C(═O)O(C 1 -C 6  alkyl), or R9×2C(═X1)X2R9;
 wherein each said R5, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, C 6 -C 20  aryl, or C 1 -C 20  heterocyclyl, R9 aryl (each of which that can be substituted, may optionally be substituted with R9) 
 optionally R5 and R7 can be connected in a cyclic arrangement, where optionally such arrangement can have one or more heteroatoms selected from O, S, or, N, in the cyclic structure connecting R5 and R7; 
 
         (g) R6 is O, S, NR9, or NOR9; 
         (h) R7 is substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, substituted or unsubstituted C 1 -C 20  heterocyclyl, OR9, OR9S(O) n R9, C(═X1)R9, C(═X1)OR9, R9C(═X1)OR9, R9×2C(═X1)R9×2R9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)(R9S(O) n R9), N(R9)C(═X1)R9, SR9, S(O) n OR9, R9S(O) n R9, C 1 -C 6 alkylOC(═O)C 1 -C 6 alkyl, OC 1 -C 6  alkyl C 1 -C 20  heterocyclyl, C 1 -C 6 alkylC 1 -C 20  heterocyclyl, C 1 -C 6 , alkylS(═N—CN)(C 1 -C 6 alkyl), C 1 -C 6 alkylS(O)(═N—CN)(C 1 -C 6 alkyl), C 1 -C 6 alkylS(O) n (C 1 -C 6 alkylC 1 -C 20 heterocyclyl), C 1 -C 6 alkylS(O)(═N—CN)(C 1 -C 6  alkyl-C 1 -C 20 heterocyclyl), C 1 -C 6 alkylNH(C(═O)OC 1 -C 6  alkyl), C 1 -C 6  alkylC(═O)OC 1 -C 6  alkyl, C 1 -C 6 alkyl(C 6 -C 20 aryl)NH(C(═O)OC 1 -C 6 alkyl), C 1 -C 6 alkyl(S—C 1 -C 6  alkyl)NH(C(═O)OC 1 -C 6 alkyl), C 1 -C 6 alkyl(S—C 1 -C 6 alkyl-C 6 -C 20 aryl)NH(C(═O)OC 1 -C 6 alkyl), C 1 -C 6  alkyl(NHC(═O)OC 1 -C 6 alkylC 6 -C 20  aryl)NH(C(═O)OC 1 -C 6 alkyl), C 1 -C 6 alkyl(OC 1 -C 6 alkylC 6 -C 20 aryl)NH(C(═O)OC 1 -C 6 alkyl), C 1 -C 6 alkylN(C 1 -C 6 alkyl)(C(═O)OC 1 -C 6 alkyl), C 1 -C 6 alkylNH(C 1 -C 6 alkyl), C 6 -C 20 arylSC 1 -C 6 haloalkyl, C 1 -C 6 alkyl-N(C 1 -C 6  alkyl)(C(═O)C 1 -C 6 alkylC 6 -C 20 aryl), C 1 -C 6 alkylN(C 1 -C 6 alkyl)(C 1 -C 6 alkyl), C 1 -C 6 alkylN(C 1 -C 6  alkyl)(S(O) n C 1 -C 6  alkyl), C 1 -C 6  alkylN(C 1 -C 6  alkyl)(S(O) n C 1 -C 6  alkenylC 6 -C 20  aryl), C 1 -C 6  alkylN(C 1 -C 6  alkyl)(C(═O)C 1 -C 20  heterocyclyl), C 1 -C 6 alkylN(C 1 -C 6 alkyl)(C(═O)OC 1 -C 6  alkylC 6 -C 20 aryl), NH(C 1 -C 6  alkylS(O) n C 1 -C 6 alkyl), NH(C 1 -C 6  alkylS(O) n C 6 -C 20  aryl), C 1 -C 6 alkyl(S(O) n C 1 -C 6  alkyl)(C(═O)C 1 -C 6 alkylS(O) n (C 1 -C 6  alkyl), or R9S(O) n (NZ)R9,
 wherein each said R7, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, C 6 -C 20  aryl, or C 1 -C 20  heterocyclyl, (each of which that can be substituted, may optionally be substituted with R9), C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , ═X2, N(R9) 2 , S(═X2) n R9, R9S(O) n R9, S(O) n N(R9) 2 ; 
 
         (i) R8 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, substituted or unsubstituted C 1 -C 20  heterocyclyl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n R9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R8, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, C 6 -C 20  aryl, or C 1 -C 20  heterocyclyl, (each of which that can be substituted, may optionally be substituted with R9); 
 
         (j) R9 (each independently) is H, CN, substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, substituted or unsubstituted C 1 -C 20  heterocyclyl, S(O) n C 1 -C 6  alkyl, N(C 1 -C 6 alkyl) 2 ,
 wherein each said R9, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OC 1 -C 6  alkyl, OC 1 -C 6  haloalkyl, S(O) n C 1 -C 6 alkyl, S(O) n OC 1 -C 6  alkyl, C 6 -C 20  aryl, or C 1 -C 20  heterocyclyl; 
 
         (k) n is 0, 1, or 2; 
         (l) X1 is (each independently) O or S; 
         (m) X2 is (each independently) O, S, ═NR9, or ═NOR9; and 
         (n) Z is CN, NO 2 , C 1 -C 6  alkyl(R9), C(═X1)N(R9) 2 . 
       
     
     
         2 . A molecule having the following formula (“Formula I”): 
       
         
           
           
               
               
           
         
         wherein: 
         (a) X is N or CR8; 
         (b) R1 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R1, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, or C 6 -C 20  aryl, (each of which that can be substituted, may optionally be substituted with R9); 
 
         (c) R2 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R2, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, or C 6 -C 20  aryl, (each of which that can be substituted, may optionally be substituted with R9); 
 
         (d) R3 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R3, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, or C 6 -C 20  aryl, (each of which that can be substituted, may optionally be substituted with R9); 
 
         (e) R4 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R4, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, or C 6 -C 20  aryl, (each of which that can be substituted, may optionally be substituted with R9); 
 
         (f) R5 is H, substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, R9S(O) n R9, C 1 -C 6  alkyl C 6 -C 20  aryl (wherein the alkyl and aryl can independently be substituted or unsubstituted), C(═X2)R9, C(═X1)X2R9, R9×2C(═X1)R9, R9×2R9, or R9×2C(═X1)X2R9;
 wherein each said R5, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, or C 6 -C 20  aryl, R9 aryl (each of which that can be substituted, may optionally be substituted with R9) 
 optionally R5 and R7 can be connected in a cyclic arrangement, where optionally such arrangement can have one or more heteroatoms selected from O, S, or, N, in the cyclic structure connecting R5 and R7; 
 
         (g) R6 is O, S, NR9, or NOR9; 
         (h) R7 is substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, OR9, OR9S(O) n R9, C(═X1)R9, C(═X1)OR9, R9C(═X1)OR9, R9×2C(═X1)R9×2R9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)(R9S(O) n R9), N(R9)C(═X1)R9, SR9, S(O) n OR9, R9S(O) n R9, or R9S(O) n (NZ)R9,
 wherein each said R7, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, or C 6 -C 20  aryl, (each of which that can be substituted, may optionally be substituted with R9) 
 
         (i) R8 is H, F, Cl, Br, I, CN, NO 2 , substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl, OR9, C(═X1)R9, C(═X1)OR9, C(═X1)N(R9) 2 , N(R9) 2 , N(R9)C(═X1)R9, SR9, S(O) n OR9, or R9S(O) n R9,
 wherein each said R8, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OR9, S(O) n OR9, or C 6 -C 20  aryl (each of which that can be substituted, may optionally be substituted with R9); 
 
         (j) R9 (each independently) is H, CN, substituted or unsubstituted C 1 -C 6  alkyl, substituted or unsubstituted C 2 -C 6  alkenyl, substituted or unsubstituted C 1 -C 6  alkoxy, substituted or unsubstituted C 2 -C 6  alkenyloxy, substituted or unsubstituted C 3 -C 10  cycloalkyl, substituted or unsubstituted C 3 -C 10  cycloalkenyl, substituted or unsubstituted C 6 -C 20  aryl,
 wherein each said R9, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , C 1 -C 6  alkyl, C 2 -C 6  alkenyl, C 1 -C 6  haloalkyl, C 2 -C 6  haloalkenyl, C 1 -C 6  haloalkyloxy, C 2 -C 6  haloalkenyloxy, C 3 -C 10  cycloalkyl, C 3 -C 10  cycloalkenyl, C 3 -C 10  halocycloalkyl, C 3 -C 10  halocycloalkenyl, OC 1 -C 6  alkyl, OC 1 -C 6  haloalkyl, S(O) n OC 1 -C 6  alkyl, C 6 -C 20  aryl; 
 
         (k) n is 0, 1, or 2; 
         (l) X1 is (each independently) O or S; 
         (m) X2 is (each independently) O, S, ═NR9, or ═NOR9; and 
         (n) Z is CN, NO 2 , C 1 -C 6  alkyl(R9), C(═X1)N(R9) 2 . 
       
     
     
         3 . A molecule according to  claim 2  wherein
 (a) X is CR8; 
 (b) R1 is H; 
 (c) R2 is H; 
 (d) R3 is H; 
 (e) R4 is Cl or CH 3 ; 
 (f) R5 is H or unsubstituted C 1 -C 6  alkyl; 
 (g) R6 is O; 
 (h) R7 is (unsubstituted C 1 -C 6  alkyl)S(O) n (unsubstituted C 1 -C 6  alkyl), (unsubstituted C 1 -C 6  alkyl)S(O) n (unsubstituted C 1 -C 6  alkenyl), O(unsubstituted C 1 -C 6  alkyl), (C 1 -C 6  alkyl); 
 (i) R8 is H or F; and 
 (k) n is 0, 1, or 2. 
 
     
     
         4 . A molecule having the following formula (“Formula I”): 
       
         
           
           
               
               
           
         
         wherein:
 (a) X is CR8; 
 (b) R1 is H; 
 (c) R2 is H; 
 (d) R3 is H; 
 (e) R4 is Cl; 
 (f) R5 is an unsubstituted C 1 -C 6  alkyl; 
 (g) R6 is O; 
 (h) R7 is (unsubstituted C 1 -C 6  alkyl)S(O) n (unsubstituted C 1 -C 6  alkyl); 
 (i) R8 is H or F; and 
 (k) n is 0, 1, or 2. 
 
       
     
     
         5 . A molecule according to  claim 4  having the following structure: 
       
         
           
           
               
               
           
         
       
     
     
         6 . A molecule according to  claim 4  having the following structure: 
       
         
           
           
               
               
           
         
       
     
     
         7 . A molecule according to  claim 4  having the following structure: 
       
         
           
           
               
               
           
         
       
     
     
         8 . A molecule according to  claim 4  in the form of a pesticidally acceptable acid addition salt, salt derivative, or solvate. 
     
     
         9 . A molecule according to  claim 4  having at least one  2 H. 
     
     
         10 . A molecule according to  claim 4  having at least one  14 C. 
     
     
         11 . A molecule according to  claim 4  that is a resolved stereoisomer. 
     
     
         12 . A composition comprising a molecule according to  claim 4  and at least one member of the Insecticide Group, Acaricide Group, Nematicide Group, Fungicide Group, or Herbicide Group. 
     
     
         13 . A composition comprising a molecule according to  claim 4  and at least one biopesticide. 
     
     
         14 . A composition comprising a molecule according to  claim 4  and at least one of the following compounds:
 (a) 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-oxa-1-azaspiro[4,5]dec-3-en-2-one; 
 (b) 3-(4′-chloro-2,4-dimethyl[1,1′-biphenyl]-3-yl)-4-hydroxy-8-oxa-1-azaspiro[4,5]dec-3-en-2-one; 
 (c) 4-[[(6-chloro-3-pyridinyl)methyl]methylamino]-2(5H)-furanone; 
 (d) 4-[[(6-chloro-3-pyridinyl)methyl]cyclopropylamino]-2(5H)-furanone; 
 (e) 3-chloro-N2-[(1S)-1-methyl-2-(methylsulfonyl)ethyl]-N1-[2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]-1,2-benzenedicarboxamide; 
 (f) 2-cyano-N-ethyl-4-fluoro-3-methoxy-benenesulfonamide; 
 (g) 2-cyano-N-ethyl-3-methoxy-benzenesulfonamide; 
 (h) 2-cyano-3-difluoromethoxy-N-ethyl-4-fluoro-benzenesulfonamide; 
 (i) 2-cyano-3-fluoromethoxy-N-ethyl-benzenesulfonamide; 
 (j) 2-cyano-6-fluoro-3-methoxy-N,N-dimethyl-benzenesulfonamide; 
 (k) 2-cyano-N-ethyl-6-fluoro-3-methoxy-N-methyl-benzenesulfonamide; 
 (l) 2-cyano-3-difluoromethoxy-N,N-dimethylbenzenesulfon-amide; 
 (m) 3-(difluoromethyl)-N-[2-(3,3-dimethylbutyl)phenyl]-1-methyl-1H-pyrazole-4-carboxamide; 
 (n) N-ethyl-2,2-dimethylpropionamide-2-(2,6-dichloro-α,α,α-trifluoro-p-tolyl) hydrazone; 
 (o) N-ethyl-2,2-dichloro-1-methylcyclopropane-carboxamide-2-(2,6-dichloro-α,α,α-trifluoro-p-tolyl) hydrazone nicotine; 
 (p) O-{(E-)-[2-(4-chloro-phenyl)-2-cyano-1-(2-trifluoromethylphenyl)-vinyl]}S-methyl thiocarbonate; 
 (q) (E)-N1-[(2-chloro-1,3-thiazol-5-ylmethyl)]-N2-cyano-N1-methylacetamidine; 
 (r) 1-(6-chloropyridin-3-ylmethyl)-7-methyl-8-nitro-1,2,3,5,6,7-hexahydro-imidazo[1,2-a]pyridin-5-ol; 
 (s) 4-[4-chlorophenyl-(2-butylidine-hydrazono)methyl)]phenyl mesylate; or 
 (t) N-Ethyl-2,2-dichloro-1-methylcyclopropanecarboxamide-2-(2,6-dichloro-alpha,alpha,alpha-trifluoro-p-tolyl)hydrazone. 
 
     
     
         15 . A process comprising applying to an area a molecule according to  claim 4  in an amount sufficient to control pests. 
     
     
         16 . A process comprising reacting molecule VIIIb with molecule IXb to form molecule Xb 
       
         
           
           
               
               
           
         
         wherein R1, R2, R3, and R4 are defined as in  claim 1 . 
       
     
     
         17 . A process comprising reacting molecule VXb with t-butanol to form molecule XVIIc. 
       
         
           
           
               
               
           
         
         wherein R4 is as defined in  claim 1 . 
       
     
     
         18 . A process comprising reacting molecule XIIIg to form molecule VIIIk 
       
         
           
           
               
               
           
         
         wherein R1, R2, R3, R4, and R5 are as defined in  claim 1 . 
       
     
     
         19 . A process comprising reacting a molecule selected from molecules VIIa-k with molecule XXd to form molecule Iv 
       
         
           
           
               
               
           
         
         wherein R1, R2, R3, R4, R5, R6, and R7 are as defined in  claim 1 . 
       
     
     
         20 . A process comprising reacting molecule XVIIb (where R4 is H) to form molecule XXV, then reacting molecule XXV with XIXc to form molecule XXVI, then reacting molecule XXVI to form molecule XXVII. 
       
         
           
           
               
               
           
         
         wherein R1, R2, and R3, are as defined in  claim 1 , and R 4 in XXVII is limited to F, Cl, Br, or I.