Process For Inhibition Of Sulphide Scales

Abstract

The invention provides for the use of a copolymer, comprising a) 0.1 to 10 mol-%, based on the weight of the copolymer, of structural units derived from vinylphosphonic acid or of a salt thereof, b) 40 to 80 mol-%, based on the weight of the copolymer, of structural units derived from compounds of the formula (1) c) 1 to 50 mol-%, based on the weight of the copolymer, of structural units derived from compounds of the formula (5) in which X is OH or NR 3 R 4 , and R 3 and R 4 , independently of one another, are H or C 1 -C 4 -alkyl, for the inhibition and/or dispersion of inorganic sulphide scales, and for a process for the inhibition and/or dispersion of inorganic sulphide scales, the process comprising adding to water being within an oil or gas containing formation said copolymer.

1 . A copolymer for the inhibition and/or dispersion of inorganic sulphide scales, comprising
 a) 0.1 to 10 mol-%, based on the weight of the copolymer, of structural units derived from vinylphosphonic acid or of a salt thereof,   b) 40 to 80 mol-%, based on the weight of the copolymer, of structural units derived from compounds of the formula (1)   
       
         
           
           
               
               
           
         
         c) 1 to 50 mol-%, based on the weight of the copolymer, of structural units derived from compounds of the formula (5) 
       
       
         
           
           
               
               
           
         
         
           in which X is OH or NR 3 R 4 , and R 3  and R 4 , independently of one another, are H or C 1 -C 4 -alkyl. 
         
       
     
     
         2 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein the copolymer comprises additionally 1 to 10 mol-%, based on the weight of the copolymer, of structural units of formula (2) 
       
         
           
           
               
               
           
         
       
       in which n is 3, 4 or 5. 
     
     
         3 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein the copolymer further comprises 1 to 10 mol-% of structural units of formula (3) 
       
         
           
           
               
               
           
         
       
       in which R 1  and R 2 , independently of one another, are hydrogen or C 1 -C 4 -alkyl. 
     
     
         4 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein the copolymer comprises less than 1 mol-% monomers which comprise an olefinically unsaturated hydrocarbon substituted ammonium salt group, wherein the expression hydrocarbon encompasses groups containing oxygen. 
     
     
         5 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein in the copolymer the proportion by weight of vinylphosphonic acid or salts thereof is from 0.8 to 6 mol-%. 
     
     
         6 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein in the copolymer the proportion of structural units which are derived from compounds of the formula (1) is from 45 to 70 mol-%. 
     
     
         7 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein in the copolymer the proportion of structural units which are derived from compounds of the formula (5) is from 5 to 45 mol-%. 
     
     
         8 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein formula (5) is acrylic acid and/or acrylamide. 
     
     
         9 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein formula (5) is acrylamide and the proportion thereof is from 5 to 45 mol-%. 
     
     
         10 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein formula (5) is a mixture of acrylic acid and acrylamide, and the proportion of acrylic acid is from 1 to 10 mol-%, and the proportion of acrylamide is from 1 to 40 mol-%. 
     
     
         11 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 3 , wherein the proportion of structural units which are derived from compound of the formula (3) is from 1 to 10 mol-%. 
     
     
         12 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 2 , wherein the proportion of structural units which are derived from compound of the formula (2) is from 1 to 10 mol-%. 
     
     
         13 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein the molecular weights (number average) of the copolymer is from 100,000 to 10,000,000 g/mol, determined by GPC against polyacrylic acid as standard. 
     
     
         14 . The copolymer for the inhibition and/or dispersion of inorganic sulphide scales according  claim 1 , further comprising a conventional scale inhibitor. 
     
     
         15 . A composition for the inhibition and/or dispersion of inorganic sulphide scales comprising 25-30 wt.-% water or solvent, 0.5-10 wt.-% copolymers according to  claim 1 , 1-25 wt.-% of a conventional scale inhibitor and 5-50 wt.-% of a glycol based solvent. 
     
     
         16 . The composition for the inhibition and/or dispersion of inorganic sulphide scales according to  claim 1 , wherein the conventional scale inhibitor is selected from the group consisting of diethylenetriamine penta(methylene phosphonic acid), nitrilo(methylene phosphonic acid), methacrylic diphosphonate homopolymer, acrylic acid-allyl ethanolamine diphosphonate copolymer, SVS (sodium vinyl sulphate)-acrylic acid-allyl ammonia diphosphonate terpolymer, acrylic acid-maleic acid-DETA (diethylene triamine)allyl phosphonate terpolymer, polyaspartic acid, and polycarboxylates. 
     
     
         17 . A process for the inhibition and/or dispersion of inorganic sulphide scales, wherein the process comprises the step of adding a copolymer comprising
 a) 0.1 to 10 mol-% of structural units derived from vinylphosphonic acid or of a salt thereof,   b) 40 to 80 mol-% of structural units derived from compounds of the formula (1)   
       
         
           
           
               
               
           
         
         c) 1 to 50 mol-% of structural units derived from compounds of the formula (5) 
       
       
         
           
           
               
               
           
         
         
           in which X is OH or NR 3 R 4 , and R 3  and R 4 , independently of one another, are H or C 1 -C 4 -alkyl to water within an oil or gas containing formation.