Materials and configurations for scalable microbial fuel cells

Abstract

Devices for production of electricity and/or hydrogen gas are provided by the present invention. In particular, microbial fuel cells for production of electricity and modified microbial fuel cells for production of hydrogen are detailed. A tube cathode is provided which includes a membrane forming a general tube shape. An anode is provided which has a specific surface area greater than 100 m 2 /m 3 . In addition, the anode is substantially non-toxic to anodophilic bacteria. Combinations of particular anodes and cathodes are included in microbial fuel cells and modified microbial fuel cells.

1 . A microbial fuel cell, comprising:
 a cathode comprising a membrane, the membrane forming a cathode wall generally enclosing and defining an interior space, the cathode wall having an internal surface adjacent the interior space and an opposed external surface, the wall extending between a first end and a second end;   an anode, the anode substantially non-toxic to anodophilic bacteria; and   an electrically conductive connector connecting the anode and the cathode.   
     
     
         2 . The microbial fuel cell of  claim 1  wherein the membrane is selected from the group consisting of: a nanofiltration membrane, an ultrafiltration membrane, and an ion exchange membrane. 
     
     
         3 . The microbial fuel cell of  claim 1  further comprising a conductive material in contact with the internal surface or the external surface of the membrane, the conductive material in electrically conductive connection with the electrically conductive connector. 
     
     
         4 . The microbial fuel cell of  claim 3  wherein the conductive material is a carbon-based material. 
     
     
         5 . The microbial fuel cell of  claim 3  wherein the conductive material is graphite. 
     
     
         6 . The microbial fuel cell of  claim 3  wherein the conductive material is a carbon-based coating, the carbon-based coating present on at least about 50% of the internal surface or the external surface of the membrane. 
     
     
         7 . The microbial fuel cell of  claim 1 , further comprising a catalyst. 
     
     
         8 . The microbial fuel cell of  claim 7 , wherein the catalyst is selected from the group consisting of: a metal-containing catalyst, a non-metal containing catalyst, and a combination thereof. 
     
     
         9 . The microbial fuel cell of  claim 1 , wherein the anode has a specific surface area greater than 100 m 2 / m 3 . 
     
     
         10 . The microbial fuel cell of  claim 1 , wherein the anode is a brush anode. 
     
     
         11 . The microbial fuel cell of  claim 1 , comprising two or more anodes. 
     
     
         12 . The microbial fuel cell of  claim 1 , comprising two or more cathodes. 
     
     
         13 . The microbial fuel cell of  claim 1 , further comprising a power source for enhancing an electrical potential between the anode and the cathode in order to produce hydrogen from the microbial fuel cell, the power source in electrical communication with the anode and the cathode. 
     
     
         14 . The microbial fuel cell of  claim 13  wherein the power source is a second microbial fuel cell, the second microbial fuel cell configured to produce electricity. 
     
     
         15 . A microbial fuel cell, comprising:
 an anode having a specific surface area greater than 100 m 2 /m 3 , the anode substantially non-toxic to anodophilic bacteria;   a cathode; and   an electrically conductive connector connecting the anode and the cathode.   
     
     
         16 . The microbial fuel cell of  claim 15 , wherein the anode comprises one or more conductive fibers. 
     
     
         17 . The microbial fuel cell of  claim 16 , wherein the one or more conductive fibers is attached to a conductive core support. 
     
     
         18 . The microbial fuel cell of  claim 17 , wherein each individual fiber of the one or more conductive fibers is attached to the conductive core support. 
     
     
         19 . The microbial fuel cell of  claim 17 , wherein at least a portion of the one or more fibers comprises one or more carbon fibers. 
     
     
         20 . The microbial fuel cell of  claim 15 , comprising two or more anodes. 
     
     
         21 . The microbial fuel cell of  claim 15 , comprising two or more cathodes. 
     
     
         22 . The microbial fuel cell of  claim 15 , further comprising a power source for enhancing an electrical potential between the anode and the cathode in order to produce hydrogen from the microbial fuel cell, the power source in electrical communication with the anode and the cathode. 
     
     
         23 . The microbial fuel cell of  claim 23  wherein the power source is a second microbial fuel cell, the second microbial fuel cell configured to produce electricity. 
     
     
         24 . A cathode for a microbial fuel cell, comprising:
 a membrane, the membrane forming a cathode wall generally enclosing and defining an interior space, the cathode wall having an internal surface adjacent the interior space and an opposed external surface, the wall extending between a first end and a second end, the wall having a general shape.   
     
     
         25 . The cathode for a microbial fuel cell of  claim 24  wherein the membrane is selected from the group consisting of: a nanofiltration membrane, an ultrafiltration membrane, and an ion exchange membrane. 
     
     
         26 . The cathode for a microbial fuel cell of  claim 24  further comprising a conductive material in contact with the internal surface or the external surface of the membrane, the conductive material in electrically conductive connection with the electrically conductive connector. 
     
     
         27 . The cathode for a microbial fuel cell of  claim 26  wherein the conductive material is a carbon-based material. 
     
     
         28 . The cathode for a microbial fuel cell of  claim 26  wherein the conductive material is graphite. 
     
     
         29 . The cathode for a microbial fuel cell of  claim 26  wherein the conductive material is present on at least about 50% of the internal surface or the external surface of the membrane. 
     
     
         30 . The cathode for a microbial fuel cell of  claim 24 , further comprising a catalyst selected from the group consisting of: a catalyst for enhancement of oxygen reduction and a catalyst for enhancement of proton reduction. 
     
     
         31 . The cathode of  claim 24 , wherein at least one of the first or second ends is closed. 
     
     
         32 . The cathode of  claim 24 , wherein the interior space is at least partially filled with a liquid. 
     
     
         33 . The cathode of  claim 24 , wherein the wall has a shape selected from the group consisting of: generally cylindrical and generally hollow slab-shaped.