Film forming polymer compositions for boosting spf in sunscreens

Abstract

Film-forming compositions comprising a film forming polymer containing acid groups and a neutralizing agent; compositions and methods for increasing the SPF of a composition by neutralizing at least a portion of the acid groups of the film forming agent with the neutralizing agent.

We claim: 
     
         1 . A film forming composition comprising at least one film forming polymer containing a plurality of acid groups, wherein at least a portion of the acid groups have been neutralized with a cosmetically acceptable neutralizing agent, wherein the film forming composition exhibits a boost to SPF in sunscreen compositions by 125% compared to the SPF of sunscreen compositions that do not include the film forming composition, wherein the cosmetically acceptable amine based neutralizing agent is selected from an agent having the structure: 
       
         
           
           
               
               
           
         
       
       wherein R 8  is C 2  to about C 36  straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl group, and R9 is selected from H or CH 3 , or C 2  to C 36  straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl group, and wherein x and y are independently 1 to 100 and wherein said straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl groups can optionally contain one or more heteroatoms; 
       
         
           
           
               
               
           
         
       
       wherein R 10  R 11 , and R 12  are independently selected from H, CH 3  or C 2  to about C 36  straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl group, and wherein n is 1 to 100 and wherein said straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl groups can optionally contain one or more heteroatoms; 
       
         
           
           
               
               
           
         
       
       wherein R 6  is H or CH 3  and x and y are independently from about 1 to about 100; 
       
         
           
           
               
               
           
         
       
       wherein x is from about 1 to about 100; 
       
         
           
           
               
               
           
         
       
       wherein x, y and z are independently from about 1 to about 100; and 
       
         
           
           
               
               
           
         
       
       wherein R 7  is H or C 2 H 5  and n, x, y and z are independently from about 1 to about 100. 
     
     
         2 . The composition of  claim 1 , wherein the amine-based neutralizing agent is selected from an agent having the structure: 
       
         
           
           
               
               
           
         
       
       wherein R 8  is C 2  to about C 36  straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl group, and R 9  is selected from H or CH 3 , or C 2  to C 36  straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl group, and wherein x and y are independently 1 to 100 and wherein said straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl groups can optionally contain one or more heteroatoms; or 
       
         
           
           
               
               
           
         
       
       wherein R 10  R 11 , and R 12  are independently selected from H, CH 3  or C 2  to about C 36  straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl group, and wherein n is 1 to 100 and wherein said straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl groups can optionally contain one or more heteroatoms. 
     
     
         3 . The composition of  claim 1 , wherein the amine-based neutralizing agent is selected from an agent having the structure: 
       
         
           
           
               
               
           
         
       
       wherein R 8  is C 2  to about C 36  straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl group, and R 9  is selected from H or CH 3 , or C 2  to C 36  straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl group, and wherein x and y are independently 1 to 100 and wherein said straight chain, branched or cyclic alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, or aralkynyl group can optionally contain one or more heteroatoms. 
     
     
         4 . The composition of  claim 1 , wherein the film forming polymer comprises two or more distinct monomer units, wherein at least one of said monomers comprises a carboxylic acid moiety. 
     
     
         5 . The composition of  claim 1 , wherein said film forming polymer comprises a plurality of distinct monomers wherein at least one of said monomers comprises from about 5 to about 95 percent of the total monomer content. 
     
     
         6 . The composition of  claim 1 , wherein said film forming polymer comprises a plurality of distinct monomers 
       wherein at least one of said monomers comprises from about 5 to about 50 percent of the total monomer content. 
     
     
         7 . The composition of  claim 1 , wherein from about 5 to about 100 percent of the plurality of acid groups of the film forming polymer are neutralized by said amine-based neutralizing agent. 
     
     
         8 . The composition of  claim 1 , wherein from about 5 to about 50 percent of the plurality of acid groups of the film forming polymer are neutralized by said amine-based neutralizing agent. 
     
     
         9 . The composition of  claim 1 , wherein said acid groups on the film forming polymer are chosen from the group consisting of carboxylic acids, sulfonic acids, phosphoric acids, and combinations thereof. 
     
     
         10 . The composition of  claim 1 , wherein said at least one film forming polymer is chosen from polyacrylic acid, polycrotonic acid, polymethacrylic acid, polymaleic acid, polyitaconic acid, octylacrylamide/acrylates/butylaminoethyl methacrylate copolymer, acrylates/octylacrylamide copolymer, acrylates copolymer, octylacrylamide/butylaminoethyl methacrylate copolymer, VA/crotonates/vinyl neodecanoate copolymer, VA/Crotonates copolymer, sodium polystyrene sulfonate, polyurethane-14 (and) AMP-Acrylates copolymer, acrylates/octylacrylamide copolymer, acrylates/steareth-20 itaconate, copolymer, acrylates/ceteth-20 itaconate copolymer, PVM/MA half ethyl ester copolymer, butylated PVP, PVP/hexadecene copolymer, PVP/eicosene copolymer, tricontanyl PVP, butyl ester of PVM/MA copolymer, PVM/MA copolymer, ethyl ester of PVM/MA copolymer, butyl ester of PVM/MA copolymer, vinyl caprolactam/PVP/dimethylaminoethyl methacrylate copolymer, polyquaternium-11, polyquaternium-28, Polyimide-1, PVP/Vinylcaprolactam/DMAPA Acrylates Copolymer, Isobutylene/Ethylmaleimide/Hydroxyethylmaleimide Copolymer, Acrylates/C1-2 Succinates/Hydroxyacrylates Copolymer, PVP/DMAPA Acrylates Copolymer, VP/Acrylates/Lauryl Methacrylate Copolymer, Polyquaternium-55, PVP/Dimethylaminoethylmethacrylate Copolymer, VinylcaprolactamNP/Dimethylaminoethyl Methacrylate Copolymer, VA/Butyl Maleate/Isobornyl Acrylate Copolymer, acrylic acid/ethyl acrylate/t-butyl acrylamide, t-butyl acrylate/ethyl acrylate/methacrylic acid, ethyl acrylate/t-butyl acrylate/methacrylic acid, polyquaternium-16, polyquaternium-16, PVP, PVPNA copolymer, PVPNA copolymer, Polyurethane-1, VP/MethacrylamideNinyl Imidazole Copolymer, Acrylates Copolymer, Acrylates/Acrylamide Copolymer, Polyvinylcaprolactam, Dimethicone/Acrylates Copolymer; Amerchol, acrylic acid/methacrylic acid/acrylates/methacrylates, acrylic acid/methacrylic acid/acrylates/methacrylates/hydroxy ester acrylates; methacryloyl ethyl betaine/acrylates copolymer, Acrylates/Hydroxyesters Acrylates Copolymer, Ethylenecarboxyamide/AMPSA/Methacrylates Copolymer, methacrylic acid/sodium acrylamidomethyl propane sulfonate copolymer, AMP-Acrylates/Allyl Methacrylate Copolymer, Polyacrylates-X, Acrylates/C10-30 Alkyl Acrylates Copolymer, Acrylates Copolymer, Polyurethane-2, Polyurethane-4, PPG-17/IPDI/DMPA Copolymer; polyethylene glycol; water-soluble acrylics; water-soluble polyesters; polyacrylamides; polyamines; polyquaternary amines; styrene maleic anhydride (SMA) resin; or mixtures or combinations thereof. 
     
     
         11 . The composition of  claim 1  further comprising a volatile solvent. 
     
     
         12 . The composition of  claim 11  wherein the solvent is selected from the group consisting of ethanol, isopropanol, methanol and acetone. 
     
     
         13 . A method for producing a film-forming composition comprising neutralizing at least a portion of the acid groups of an acid group-containing film forming polymer with a cosmetically acceptable amine-based neutralizing agent, and wherein the film forming composition of the neutralized film-forming polymer provides a boost to SPF in sunscreen compositions by 125% compared to the SPF of sunscreen compositions that do not include the film forming composition. 
     
     
         14 . The method of  claim 13 , wherein at least 5% of the acid groups of the film forming polymer are neutralized by the amine-based neutralization agent. 
     
     
         15 . The method of  claim 13 , wherein at least 10% of the acid groups of the film forming polymer are neutralized by the amine-based neutralization agent. 
     
     
         16 . The method of  claim 13 , wherein at least 25% of the acid groups of the film forming polymer are neutralized by the amine-based neutralization agent. 
     
     
         17 . The method of  claim 13 , wherein at least 50% of the acid groups of the film forming polymer are neutralized by the amine-based neutralization agent. 
     
     
         18 . The method of  claim 13 , wherein the film forming composition boosts SPF in sunscreen compositions by 150% compared to the SPF of sunscreen compositions that do not include the film forming composition. 
     
     
         19 . The method of  claim 13 , wherein the film forming composition boosts SPF in sunscreen compositions by 200% compared to the SPF of sunscreen compositions that do not include the film forming composition. 
     
     
         20 . The method of  claim 13 , wherein said amine neutralizing agent is alkylamine, alkenylamine, dialkylamine, dialkenylamine, dimethyl alkylamine, methyl dialkylamine, triakylamine, dimethyl alkenylamine, methyl dialkenylamine, trialkenylamine, or a combination or mixture thereof. 
     
     
         21 . The method of  claim 13 , wherein said acid groups on the film forming polymer comprise carboxylic acid groups, sulfonic acid groups, phosphoric acid groups, or a combination thereof.