Viscosity index improver concentrates for lubricating oil compositions

Abstract

Concentrates of linear, block copolymers having a polymer block derived from a monoalkenyl arene, covalently linked to one or more blocks of a hydrogenated derivative of a conjugated diene copolymer, dissolved in highly saturated diluent oil, wherein the size of the monoalkenyl arene block is controlled to provide an optimized level of incompatibility of the block copolymer in the selected diluent.

What is claimed is: 
     
         1 . A viscosity modifier concentrate consisting essentially of from about 3 to about 30 mass % of a linear di- or tri-block copolymer, and optionally from about 0.1 to about 5 mass % of lubricating oil flow improver (LOFI) and/or from about 0.1 to about 1 mass % of antioxidant (AO), in a selected diluent oil or diluent oil blend, wherein said di- or tri-block copolymer comprises a first block derived from monoalkenyl arene covalently linked to one or more blocks derived from diene; said selected diluent oil or diluent oil blend has, or has on average, a total saturates content of greater than 90 mass %, a viscosity index (VI) of at least 80, and a sulfur content of no greater than 0.3 mass %, and wherein said first block of said di- or tri-block copolymer has a weight average molecular weight whereby said di- or tri-block copolymer has a Δkv 100  value of no greater than 0.3, wherein Δkv 100  is the difference, as measured at 100° C. (ASTM D445) between the kv 100  of a first blend and a second blend of 1 mass % of said di- or tri-block copolymer in said selected diluent oil or diluent oil blend, said first blend being prepared at a temperature below the glass transition temperature (Tg) of said monoalkenyl arene and said second blend being prepared at a temperature between the glass transition temperature of the monoalkenyl arene material and the decomposition temperature of said monoalkenyl arene. 
     
     
         2 . The concentrate of  claim 1 , wherein said linear di- or tri-block copolymer is a linear di-block copolymer. 
     
     
         3 . The concentrate of  claim 1 , wherein said linear di- or tri-block copolymer has a weight average molecular weight of from about 10,000 daltons to about 700,000 daltons. 
     
     
         4 . The polymer of  claim 3 , wherein said linear di- or tri-block copolymer has a weight average molecular weight of from about 50,000 daltons to about 250,000 daltons. 
     
     
         5 . The concentrate of  claim 2 , wherein said linear di-block copolymer has a weight average molecular weight of from about 10,000 daltons to about 700,000 daltons. 
     
     
         6 . The concentrate of  claim 5 , wherein said linear di-block copolymer has a weight average molecular weight of from about 50,000 daltons to about 120,000 daltons. 
     
     
         7 . The concentrate of  claim 1  wherein said monoalkenyl arene is styrene or an alkylated derivative thereof. 
     
     
         8 . The concentrate of  claim 1  wherein said first block of said linear di- or tri-block copolymer has a weight average molecular weight of at least 4000 daltons 
     
     
         9 . The concentrate of  claim 1 , wherein said one or more blocks derived from diene are derived from isoprene, butadiene or a mixture thereof. 
     
     
         10 . The concentrate of  claim 9 , wherein said one or more blocks derived from diene are derived from a mixture of isoprene and butadiene. 
     
     
         11 . The concentrate of  claim 10 , wherein said one or more blocks derived from diene have a weight ratio of polymer derived from isoprene to a polymer derived from butadiene of from about 90:10 to about 70:30. 
     
     
         12 . The concentrate of  claim 11 , wherein said one or more blocks derived from diene have a weight ratio of polymer derived from isoprene to a polymer derived from butadiene of from about 85:15 to about 80:20 
     
     
         13 . The concentrate of  claim 10 , wherein at least about 90 mass % of the butadiene is incorporated into the polymer as 1,4 units. 
     
     
         14 . The concentrate of  claim 10 , wherein at least about 90 mass % of the isoprene is incorporated into the polymer as 1,4 units. 
     
     
         15 . The concentrate of  claim 1 , wherein said first block comprises from about 5 mass % to about 60 mass % of said di- or tri-block copolymer. 
     
     
         16 . The concentrate of  claim 15 , wherein said first block comprises from about 30 mass % to about 40 mass % of said di- or tri-block copolymer. 
     
     
         17 . The concentrate of  claim 1 , wherein said selected diluent oil or diluent oil blend has, or has on average, a VI of at least 120. 
     
     
         18 . The concentrate of  claim 1 , wherein said selected diluent oil or diluent oil blend has, or has on average, a CCS at −35° C. of less than 3700 cPs. 
     
     
         19 . The concentrate of  claim 18 , wherein said selected diluent oil or diluent oil blend has, or has on average, a CCS at −35° C. of less than 2500 cPs. 
     
     
         20 . The concentrate of  claim 1 , wherein said selected diluent oil or diluent oil blend has, or has on average, a kinematic viscosity at 100° C. (kv 100 ) of at least 3.0 cSt. 
     
     
         21 . The concentrate of  claim 20 , wherein said selected diluent oil or diluent oil blend has, or has on average, a kinematic viscosity at 100° C. (kv 100 ) of from about 3 cSt to 6 cSt. 
     
     
         22 . The concentrate of  claim 1 , comprising from about 5 mass % to about 15 mass % of said linear di- or tri-block copolymer.