Method for shaping the hair using at least one reducing composition, at least one care composition, and heating

Abstract

The present disclosure relates to a method for shaping hair fibers comprising: applying to the hair fibers at least one reducing composition comprising at least one reducing agent and at least one cationic polymer, wherein the weight ratio of the at least one reducing agent to the at least one cationic polymer ranges from 0.1:1 to 10:1; rinsing the hair fibers; applying at least one care composition comprising at least one aminated silicone; optionally rinsing the hair fibers; and heating the hair fibers with a heating device at a temperature ranging from 50 to 280° C., the heating being carried out before or after an optional rinsing of the hair fibers.

1 .- 18 . (canceled) 
     
     
         19 . A method for shaping hair fibers comprising:
 applying to the hair fibers at least one reducing composition comprising at least one reducing agent and at least one cationic polymer, wherein the weight ratio of the at least one reducing agent to the at least one cationic polymer ranges from 0.1:1 to 10:1,   rinsing the hair fibers;   optionally applying to the hair fibers an oxidizing composition, wherein, when an oxidizing composition is applied, the oxidizing composition comprises hydrogen peroxide in a concentration of less than 1 wt % and leaving the oxidizing composition in contact with the hair fibers for a period of less than 5 minutes;   applying to the hair fibers at least one care composition comprising at least one aminated silicone;   optionally rinsing the hair fibers; and   heating the hair fibers with a heating device at a temperature ranging from about 50 to about 280° C., the heating being carried out either before or after the optional rinsing of the hair fibers;   wherein the reducing composition does not comprise ammonium bicarbonate.   
     
     
         20 . The method according to  claim 19 , wherein the weight ratio of the at least one reducing agent to the at least one cationic polymer ranges from 0.5:1 to 8:1. 
     
     
         21 . The method according to  claim 20 , wherein the weight ratio of the at least one reducing agent to the at least one cationic polymer ranges from 1:1 to 5:1. 
     
     
         22 . The method according to  claim 19 , wherein the at least one cationic polymer is chosen from cyclopolymers of alkyldiallylamine and cyclopolymers of dialkyldiallylammonium. 
     
     
         23 . The method according to  claim 22 , wherein the at least one cationic polymer is chosen from homopolymers and copolymers comprising, as main constituent of the chain, units chosen from those of formulae (V) and (VI): 
       
         
           
           
               
               
           
         
       
       wherein:
 k and t are equal to 0or 1, the sum k+t being equal to 1; 
 R 9  denotes a hydrogen atom or a methyl radical; 
 R 7  and R 8 , independently of one another, denote an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group wherein the alkyl group has from 1 to 5 carbon atoms, or a lower (C 1 -C 4 ) amidoalkyl group or else R 7  and R 8  can denote, jointly with the nitrogen atom to which they are attached, heterocyclic groups; and 
 Y −  is an anion. 
 
     
     
         24 . The method according to  claim 23 , wherein R 7  and R 8 , independently of one another, denote an alkyl group having from 1 to 4 carbon atoms. 
     
     
         25 . The method according to  claim 23 , wherein R7 and R8 denote, jointly with the nitrogen atom to which they are attached, piperidinyl or morpholinyl. 
     
     
         26 . The method according to  claim 23 , wherein Y −  is chosen from bromide, chloride, acetate, borate, citrate, tartrate, bisulphate, bisulphite, sulphate, and phosphate. 
     
     
         27 . The method according to  claim 19 , wherein the at least one cationic polymer is chosen from diquaternary ammonium polymers comprising repeat units corresponding to those of formula (VII): 
       
         
           
           
               
               
           
         
       
       wherein:
 R 10 , R 11 , R 12 , and R 13 , which are identical or different, represent aliphatic, alicyclic or arylaliphatic radicals comprising from 1 to 6 carbon atoms or lower aliphatic hydroxyalkyl radicals or else R 10 , R 11 , R 12 , and R 13 , together or separately, constitute, with the nitrogen atoms to which they are attached, heterocycles optionally comprising a second heteroatom other than nitrogen or else R 10 , R 11 , R 12 , and R 13  represent a linear or branched C 1 -C 6  alkyl radical substituted by a nitrile, ester, acyl, amide or —CO—O—R 14 -D or —CO—NH—R 14 -D group, where R 14  is an alkylene and D is a quaternary ammonium group; 
 A 1  and B 1  represent polymethylene groups comprising from 2 to 20 carbon atoms which can be linear or branched and saturated or unsaturated, and which can comprise, bonded to or inserted into the main chain, at least one aromatic ring or at least one oxygen or sulphur atom or sulphoxide, sulphone, disulphide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester group, and 
 X −  denotes an anion derived from an inorganic or organic acid; 
 A 1 , R 10 , and R 12  can form, with the two nitrogen atoms to which they are attached, a piperazine ring; 
 in addition, if A 1  denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B 1  can also denote a group:
   —(CH 2 ) n —CO-D-OC—(CH 2 ) n —
 
 
 wherein n ranges from 1 to 100 and D denotes: 
 a) a glycol residue of formula —O—Z—O—, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulae:
   —(CH 2 —CH 2 —O) x —CH 2 —CH 2 —
 
   —[CH 2 —CH(CH 3 )—O] y —CH 2 —CH(CH 3 )—
 
 
 
       where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization, or any number from 1 to 4 representing a mean degree of polymerization;
 b) a bissecondary diamine residue; 
 c) a bisprimary diamine residue of formula —NH—Y—NH— where Y denotes a linear or branched hydrocarbon radical or else the divalent radical
   —CH 2 —CH 2 —S—S—CH 2 —CH 2 —;
 
 
 d) a ureylene group of formula —NH—CO—NH—. 
 
     
     
         28 . The method according to  claim 27 , wherein n ranges from 1 to 50. 
     
     
         29 . The method according to  claim 27 , wherein D denotes a piperazine derivative. 
     
     
         30 . The method according to  claim 19 , wherein the at least one reducing agent is present in the at least one reducing composition in an amount ranging from about 0.1% to about 5%, relative to the total weight of the at least one reducing composition. 
     
     
         31 . The method according to  claim 19 , wherein the at least one cationic polymer is present in the at least one reducing composition in an amount ranging from 0.01 to 10% by weight, relative to the total weight of the at least one reducing composition. 
     
     
         32 . The method according to  claim 31 , wherein the at least one cationic polymer is present in the at least one reducing composition in an amount ranging from about 0.1 to about 5% by weight, relative to the total weight of the at least one reducing composition. 
     
     
         33 . The method according to  claim 19 , wherein the hair fibers are heated at a temperature ranging from about 80° C. to about 220° C. 
     
     
         34 . The method according to  claim 19 , wherein the at least one reducing agent is a thiol-comprising reducing agent. 
     
     
         35 . The method according to  claim 19 , wherein the at least one animiated silicone is an aminated silicone chosen from those of formula (X): 
       
         
           
           
               
               
           
         
       
       wherein x′ and y′ are integers dependent on the molecular weight, generally such that the weight-average molecular weight ranges from 5,000 to 500,000;
 R1, R2, and R3, which are identical or different, denote a hydroxyl radical, a C 1  to C 4  alkyl radical, a C 1  to C 4  alkoxy radical, or a phenyl radical; 
 X denotes a branched or unbranched C 1 -C 4  alkylene radical; 
 R4 denotes a C 1 -C 4  alkyl radical or a phenyl radical; and 
 p and p′ denote, independently of one another, an integer ranging from 1 to 10. 
 
     
     
         36 . The method according to  claim 19 , further comprising applying to the hair fibers at least one second care composition different from the at least one care composition comprising at least one aminated silicone, the at least one second care composition comprising at least one silicone or non-silicone fatty substance.