Polyester-polycarbonate composition and article

Abstract

A composition includes specific amounts of an aromatic polycarbonate, a block polycarbonate-polysiloxane, a poly(alkylene terephthalate), a block polyestercarbonate, and an organophosphate ester. Relative to a corresponding composition lacking the block polyestercarbonate, the composition exhibits improved solvent resistance while substantially maintaining impact strength, melt flow, and flame retardancy. The composition is useful for fabricating articles that may come into contact with liquid chemicals or chemical vapors.

1 . A composition comprising, based on the total weight of the composition:
 5 to 50 weight percent of an aromatic polycarbonate;   10 to 40 weight percent of a block polycarbonate-polysiloxane;   5 to 35 weight percent of a poly(alkylene terephthalate);   5 to 50 weight percent of a block polyestercarbonate comprising
 a polyester block comprising resorcinol ester repeat units having the structure 
   
       
         
           
           
               
               
           
         
         
            and 
           a polycarbonate block comprising carbonate repeat units having the structure 
         
       
       
         
           
           
               
               
           
         
         
           wherein at least 60 percent of the total number of R 1  groups are aromatic; and 
         
         4 to 20 weight percent of an organophosphate ester. 
       
     
     
         2 . The composition of  claim 1 , wherein the aromatic polycarbonate comprises repeat units having the structure 
       
         
           
           
               
               
           
         
       
       wherein at least 60 percent of the total number of R 1  groups are aromatic. 
     
     
         3 . The composition of  claim 1 , wherein the aromatic polycarbonate comprises repeat units having the structure 
       
         
           
           
               
               
           
         
       
     
     
         4 . The composition of  claim 1 , wherein the block polycarbonate-polysiloxane comprises a polycarbonate block comprising repeat units having the structure 
       
         
           
           
               
               
           
         
       
       wherein at least 60 percent of the total number of R 1  groups are aromatic, and
 a polysiloxane block comprising siloxane repeat units having the structure 
 
       
         
           
           
               
               
           
         
         wherein each occurrence of R 2  is independently C 1 -C 13  hydrocarbyl. 
       
     
     
         5 . The composition of  claim 1 , wherein the block polycarbonate-polysiloxane comprises, based on the weight of the block polycarbonate-polysiloxane, 70 to 90 weight percent of carbonate units of the formula 
       
         
           
           
               
               
           
         
       
       and
 10 to 30 weight percent of dimethylsiloxane units. 
 
     
     
         6 . The composition of  claim 1 , wherein the poly(alkylene terephthalate) comprises alkylene groups comprising ethylene, 1,3-propylene, 1,4-butylene, 1,5-pentylene, 1,6-hexylene, 1,4-cyclohexylene, 1,4-cyclohexanedimethylene, or a combination thereof. 
     
     
         7 . The composition of  claim 1 , wherein the poly(alkylene terephthalate) comprises poly(butylene terephthalate). 
     
     
         8 . The composition of  claim 1 , wherein the polyester block comprises resorcinol ester repeat units having the structures 
       
         
           
           
               
               
           
         
       
       and 
       wherein the polycarbonate block comprises carbonate repeat units having the structure 
       
         
           
           
               
               
           
         
       
     
     
         9 . The composition of  claim 1 , comprising 0 to 1 weight percent of impact modifiers. 
     
     
         10 . The composition of  claim 1 , comprising 0 to 1 weight percent of reinforcing fillers. 
     
     
         11 . The composition of  claim 1 , comprising 0 to 1 weight percent of any polymer other than the aromatic polycarbonate, the block polycarbonate-polysiloxane, the poly(alkylene terephthalate), the block polyestercarbonate, and, optionally, up to 2 weight percent of a poly(styrene-acrylonitrile)-encapsulated polytetrafluoroethylene. 
     
     
         12 . The composition of  claim 1 , comprising
 15 to 36 weight percent of the aromatic polycarbonate,   20 to 30 weight percent of the block polycarbonate-polysiloxane,   15 to 25 weight percent of the poly(alkylene terephthalate),   20 to 35 weight percent of the block polyestercarbonate, and   5 to 12 weight percent of the organophosphate ester.   
     
     
         13 . The composition of  claim 1 ,
 wherein the aromatic polycarbonate comprises repeat units having the structure   
       
         
           
           
               
               
           
         
         wherein the block polycarbonate-polysiloxane comprises, based on the weight of the block polycarbonate-polysiloxane, 70 to 90 weight percent of carbonate units of the formula 
       
       
         
           
           
               
               
           
         
       
       and 10 to 30 weight percent of dimethylsiloxane units;
 wherein the poly(alkylene terephthalate) comprises poly(butylene terephthalate); 
 wherein the block polyestercarbonate comprises a polyester block comprising resorcinol ester repeat units having the structures 
 
       
         
           
           
               
               
           
         
       
       and 
       a polycarbonate block comprising carbonate repeat units having the structure 
       
         
           
           
               
               
           
         
         wherein the organophosphate ester comprises bisphenol A bis(diphenyl phosphate); and 
         wherein the composition comprises
 15 to 36 weight percent of the aromatic polycarbonate, 
 20 to 30 weight percent of the block polycarbonate-polysiloxane, 
 15 to 25 weight percent of the poly(alkylene terephthalate), 
 20 to 35 weight percent of the block polyestercarbonate, and 
 5 to 12 weight percent of the organophosphate ester. 
 
       
     
     
         14 . An article comprising a composition comprising, based on the total weight of the composition:
 5 to 50 weight percent of an aromatic polycarbonate;   10 to 40 weight percent of a block polycarbonate-polysiloxane;   5 to 35 weight percent of a poly(alkylene terephthalate);   5 to 50 weight percent of a block polyestercarbonate comprising
 a polyester block comprising resorcinol ester repeat units having the structure 
   
       
         
           
           
               
               
           
         
         
            and 
           a polycarbonate block comprising carbonate repeat units having the structure 
         
       
       
         
           
           
               
               
           
         
         
           wherein at least 60 percent of the total number of R 1  groups are aromatic; and 
         
         4 to 20 weight percent of an organophosphate ester. 
       
     
     
         15 . The article of  claim 14 , wherein the article is selected from a component of a household appliance, a component of office equipment, and a component of a consumer electronic device. 
     
     
         16 . The article of  claim 14 ,
 wherein the aromatic polycarbonate comprises repeat units having the structure   
       
         
           
           
               
               
           
         
         wherein the block polycarbonate-polysiloxane comprises, based on the weight of the block polycarbonate-polysiloxane, 70 to 90 weight percent of carbonate units of the formula 
       
       
         
           
           
               
               
           
         
       
       and 10 to 30 weight percent of dimethylsiloxane units;
 wherein the poly(alkylene terephthalate) comprises poly(butylene terephthalate); 
 wherein the block polyestercarbonate comprises a polyester block comprising resorcinol ester repeat units having the structures 
 
       
         
           
           
               
               
           
         
       
       and 
       a polycarbonate block comprising carbonate repeat units having the structure 
       
         
           
           
               
               
           
         
         wherein the organophosphate ester comprises bisphenol A bis(diphenyl phosphate); and 
         wherein the composition comprises
 15 to 36 weight percent of the aromatic polycarbonate, 
 20 to 30 weight percent of the block polycarbonate-polysiloxane, 
 15 to 25 weight percent of the poly(alkylene terephthalate), 
 20 to 35 weight percent of the block polyestercarbonate, and 
 5 to 12 weight percent of the organophosphate ester.