Epoxy compositions

Abstract

Epoxy resin compositions that include oligomeric phosphonates, carbodiimides, carbodiimides and phenolic antioxidants or phosphite antioxidants, oligomeric phosphonates and carbodiimides, or oligomeric phosphonates, carbodiimides, and phenolic antioxidants or phosphite antioxidants and exhibit improved glass transition temperature, improved heat resistance, and improved flame retardancy are described herein.

1 . A composition comprising:
 an epoxy resin;   one or more oligomeric phosphonates; and   one or more carbodiimides.   
     
     
         2 . The composition of  claim 1 , wherein the epoxy resin is selected from the group consisting of novolac-type epoxy resin, cresol-novolac epoxy resin, triphenolalkane-type epoxy resin, aralkyl-type epoxy resin, aralkyl-type epoxy resin having a biphenyl skeleton, biphenyl-type epoxy resin, dicyclopentadiene-type epoxy resin, heterocyclic-type epoxy resin, epoxy resin containing a naphthalene ring, a bisphenol-A type epoxy compound, a bisphenol-F type epoxy compound, stilbene-type epoxy resin, trimethylol-propane type epoxy resin, terpene-modified epoxy resin, linear aliphatic epoxy resin obtained by oxidizing olefin bonds with peracetic acid or a similar peracid, alicyclic epoxy resin, sulfur-containing epoxy resin, phenolic novolac type epoxy containing benzoxazines such as bisphenol-A based benzoxazines, bisphenol-F based benzoxazines, dicyclopentadiene based benzoxazines, phenolpthalein based benzoxazines, polyphenol-A type benzoxazines and combinations thereof. 
     
     
         3 . The composition of  claim 1 , wherein the one or more oligomeric phosphonates are selected from the group consisting of linear oligomeric phosphonates, branched oligomeric phosphonates, and hyperbranched oligomeric phosphonates. 
     
     
         4 . The composition of  claim 1 , wherein the one or more oligomeric phosphonates comprise about 60% to about 100% reactive end groups based on a total number of termini. 
     
     
         5 . The composition of  claim 1 , wherein the one or more oligomeric phosphonates are a random or block co-oligo(phosphonate ester) or a random or block co-oligo(phosphonate carbonate). 
     
     
         6 . The composition of  claim 1 , wherein the one or more oligomeric phosphonates comprise reactive end groups selected from the group consisting of hydroxyl, carboxylic acid, epoxy, glycidyl ether, vinyl, vinyl ester, isopropenyl, isocyanate, and combinations thereof. 
     
     
         7 . The composition of  claim 1 , wherein the one or more oligomeric phosphonates have reactive end groups that are hydroxyl. 
     
     
         8 . The composition of  claim 1 , wherein the one or more oligomeric phosphonates comprise a compound of formula (I): 
       
         
           
           
               
               
           
         
         wherein R is a C 1  to C 20  alkyl or, optionally substituted, aryl group, X is an aromatic, cycloalkyl, or aliphatic group, and n is an integer of from 1 to about 10 
       
     
     
         9 . The composition of  claim 1 , wherein the one or more oligomeric phosphonates have a weight average molecular weight as determined by gel permeation chromatography based on polystyrene standards of about 500 g/mole to about 18,000 g/mole. 
     
     
         10 . The composition of  claim 1 , wherein the one or more oligomeric phosphonates have a phosphorous content of about 2% to about 12% by weight. 
     
     
         11 . The composition of  claim 1 , comprising about 5 wt. % to about 60 wt. % of the one or more oligomeric phosphonates. 
     
     
         12 . The composition of  claim 1 , wherein the one or more carbodiimides are selected from the group consisting N,N′-dicyclohexylcarbodiimide, N-cyclohexyl-N′-(2-morpholinoethyl)carbodiimide metho-p-toluenesulfonate, bis(trimethylsilyl)carbodiimide, N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide, N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride, 1,3-di-p-tolylcarbodiimide, N,N′-bis(2-methylphenyl)carbodiimide, N-(tert-butyl)-N′-[1-(2-chlorophenyl)-1-methylethyl]carbodiimide, N-(tert-butyl)-N′-(2,6-dichlorophenyl)carbodiimide, N-butyl-N′-[1-(2-chlorophenyl)-1-methylethyl]carbodiimide, N,N′-diisopropylcarbodiimide, dicyclohexylcarbodiimide, N-benzyl-N′-cyclohexylcarbodiimide, and combinations thereof. 
     
     
         13 . The composition of  claim 1 , comprising about 0.01 wt. % to about 4.0 wt. % of the one or more carbodiimides. 
     
     
         14 . The composition of  claim 1 , further comprising one or more antioxidants. 
     
     
         15 . The composition of  claim 13 , wherein the antioxidant is a hindered phenolic antioxidant or a phosphite antioxidant. 
     
     
         16 . The composition of  claim 1 , further comprising one or more additional components selected from the group consisting of chopped or continuous glass fiber, metal fibers, aramid fibers, carbon fibers, or ceramic fibers, surfactants, organic binders, polymeric binders, crosslinking agents, diluents, coupling agents, flame retardant agents, anti-dripping agents, fluorinated polyolefins, silicones, lubricants, mould release agents, pentaerythritol tetrastearate, nucleating agents, anti-static agents, conductive blacks, carbon nanotubes, graphite, graphene, oxidized graphene, organic antistatics, polyalkylene ethers, alkylsulfonates, perfluor sulfonic acid, perfluorbutane, sulfonic acid potassium salt, polyamide-containing polymers, catalysts, colorants, inks, dyes, antioxidants, stabilizers, and combinations thereof. 
     
     
         17 . The composition of  claim 16 , comprising about 0.001 wt. % to about 1 wt. % of each individual additional component. 
     
     
         18 . A method for making an epoxy formulation comprising:
 combining an epoxy resin, reactive phosphonate oligomer, carbodiimide, and   a catalyst in a solvent to form a mixture; and   heating the mixture.   
     
     
         19 . The method of  claim 18 , wherein heating is carried out to a temperature of about 20° C. to about 250° C. 
     
     
         20 . The method of  claim 18 , wherein heating is carried out for 60 minutes to 300 minutes. 
     
     
         21 . The method of  claim 18 , wherein heating is carried out at a pressure of about 3×103 Pa to about 1×10 −1  Pa. 
     
     
         22 . The method of  claim 18 , wherein the catalyst is selected from the group consisting of transition metal catalysts, tertiary amines, imidazole containing compounds, and combinations thereof. 
     
     
         23 . The method of  claim 18 , wherein the solvent is selected from the group consisting of perfluorohexane, a,a,a-trifluorotoluene, pentane, hexane, cyclohexane, methylcyclohexane, decalin [c+t], dioxane, carbon tetrachloride, freon-11, benzene, toluene, triethyl amine, carbon disulfide, diisopropyl ether, diethyl ether (ether), t-butyl methyl ether (MTBE), chloroform, ethyl acetate, 1,2-dimethoxyethane (glyme), 2-methoxyethyl ether (diglyme), tetrahydrofuran (THF), methylene chloride, pyridine (Py), methyl ethyl ketone (MEK), acetone, hexamethylphosphoramide, N-methylpyrrolidinone, nitromethane, dimethylformamide, acetonitrile, sulfolane, dimethyl sulfoxide, and propylene carbonate. 
     
     
         24 . An article of manufacture comprising an epoxy resin, one or more reactive oligomeric phosphonates, and one or more carbodiimides. 
     
     
         25 . The article of manufacture of  claim 24 , wherein the article is a prepreg or laminate. 
     
     
         26 . The article of manufacture of  claim 24 , wherein the article is selected from the group consisting of televisions, computers, laptop computers, tablet computers, printers, cell phones, video games, DVD players, stereos, big data servers, and consumer electronics. 
     
     
         27 . A composition comprising:
 an epoxy resin;   one or more oligomeric phosphonates; and   one or more hindered phenolic antioxidant, a phosphite antioxidant, or   combinations thereof.   
     
     
         28 . The composition of  claim 27 , wherein the one or more oligomeric phosphonates have a relative viscosity (ηrel) as be determined by dissolving the sample in dichloromethane at 25° C. at a concentration of 0.5 g polymer/liter and measuring the solution with a viscometer of about 1.01 to about 1.10. 
     
     
         29 . The composition of  claim 27 , wherein the one or more oligomeric phosphonates comprise reactive end groups selected from the group consisting of hydroxyl, carboxylic acid, epoxy, glycidyl ether, vinyl, vinyl ester, isopropenyl, isocyanate, and combinations thereof. 
     
     
         30 . The composition of  claim 27 , wherein the one or more oligomeric phosphonates comprise a compound of formula (I): 
       
         
           
           
               
               
           
         
         wherein R is a C 1  to C 20  alkyl or, optionally substituted, aryl group, X is an aromatic, cycloalkyl, or aliphatic group, and n is an integer of from 1 to about 10 
       
     
     
         31 . The composition of  claim 27 , comprising about 5 wt. % to about 60 wt. % of the one or more oligomeric phosphonates. 
     
     
         32 . The composition of  claim 27 , wherein the one or more hindered phenolic antioxidant, a phosphite antioxidant, or combinations thereof is selected from the group consisting of sterically hindered phenolic antioxidants, hydrolytically stable organophosphites, organophosphite antioxidants, sterically hindered lactone antioxidants, octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, N,N′-hexane-1,6-diylbis(3-(3,5-di-tert-butyl-4-hydroxyphenylpropionamide)), 3,3′,3′,5,5′,5′-hexa-tert-butyl-a,a′,a′-(mesitylene-2,4,6-triyl)tri-p-cresol, 4,6-bis (octylthiomethyl)-o-cresol, bis(2,4-ditert-butylphenyl)pentaerytritol diphosphite, tris(2,4-ditert-butylphenyl)phosphite, and combinations thereof. 
     
     
         33 . The composition of  claim 27 , wherein the one or more hindered phenolic antioxidant, a phosphite antioxidant, or combinations thereof comprises about 0.01 wt. % to about 1.0 wt. % of the composition.