Cpvc pipe with 25% higher hydrostatic design basis than required under astm d2846

Abstract

CPVC pipe in diameters in the range from 15 mm (0.5 inch) to 15.24 cm (6 ins), to carry hot and cold aqueous streams under 690 KPa (100 psi) pressure and 82.2° C. (180° F.) in continuous service, is extruded from a compound in which the CPVC has a high Cl content in the range from 66.5%-70%, when modified with either of two specific impact high rubber modifiers in an amount greater than 5 parts but no more than 6 parts per 100 parts of CPVC. Extruded CPVC pipe provides a HDB measured according to ASTM D2837-01 which is 25% or more greater than that required for commercial pipe as specified in ASTM D2846. As a result, both SDR-11 and SDR-13.5 pipe are produced which provide a HDB of at least 1250 psi (8.62 MPa) at the 100,000 hr intercept.

1 - 18 . (canceled) 
     
     
         19 . A CPVC pipe having a standard dimension ratio of 11 which is made with a CPVC composition meeting a hydrostatic design basis (HDB) of at least 1250 psi at the 100,000 hr intercept, as measured according to ASTM-D2837-01 at 180° F., wherein the pipe is of a cell class of at least 2-4-4-4-7 and said pipe has a pressure rating of at least 125 psig as calculated using a safety factor of 0.5 and wherein the CPVC composition is comprised of (a) 100 parts by weight of a CPVC resin, wherein the CPVC resin has a chlorine content which is within the range of 66.5 percent to 70 percent by weight and made from PVC having an inherent viscosity of at least 0.88; (b) about 5 to about 6 parts by weight of an impact modifier which is a graft copolymer having a polydiene rubber backbone with styrene, acrylonitrile, and/or an acrylate monomer grafted to the polydiene rubber backbone; (c) about 1 to about 7 parts by weight of an inert filler, (d) about 1.3 to about 3.5 parts by weight of a lubricant; (e) about 1.25 to about 3 parts by weight of an organotin stabilizer, and (f) from about 1.5 to about 3 parts by weight of a chlorinated polyethylene. 
     
     
         20 . The CPVC pipe of  claim 19  wherein the pipe is of cell class 2-4-4-4-8. 
     
     
         21 . The CPVC pipe of  claim 19  wherein the pipe is a plumbing pipe for hot and cold water applications. 
     
     
         22 . The CPVC pipe of  claim 19  wherein the pipe is comprised of at least 80 weight percent CPVC resin. 
     
     
         23 . The CPVC pipe of  claim 19  wherein the pipe is comprised of at least 85 weight percent CPVC resin. 
     
     
         24 . The CPVC pipe of  claim 19  wherein the pipe is comprised of at least 86 weight percent CPVC resin. 
     
     
         25 . The CPVC pipe of  claim 19  wherein the CPVC composition has a notched Izod impact strength of at least 5.0 ft·lb/in (266.9 J/m) of notch. 
     
     
         26 . (canceled) 
     
     
         27 . The CPVC pipe of  claim 25  wherein the chlorinated polyethylene has a chlorine content which is within the range of about 32 weight percent to about 40 weight percent and a weight average molecular weight which is within the range of 120,000 to 400,000 Daltons. 
     
     
         28 . The CPVC pipe of  claim 27  wherein the CPVC composition is further comprised of about 0.1 to about 1 part by weight of an antioxidant. 
     
     
         29 . The CPVC pipe of  claim 28  wherein the CPVC composition exhibits a tensile strength of at least 7,000 psi (48.3 MPa), a modulus of elasticity of at least 360,000 psi (2,482 MPa), and a heat deflection temperature (HDT) under a 264 psi (1.82 MPa) load of at least 100° C. without being annealed. 
     
     
         30 . The CPVC pipe of  claim 26  wherein the impact modifier is a graft copolymer having a polybutadiene rubber backbone with styrene and acrylonitrile grafted to said backbone. 
     
     
         31 . The CPVC pipe of  claim 26  wherein the impact modifier is a graft copolymer having a polybutadiene rubber backbone with methylmethacrylate and styrene grafted to said backbone. 
     
     
         32 . The CPVC pipe of  claim 26  wherein the impact modifier is a graft copolymer having a styrene-butadiene rubber backbone with methylmethacrylate and styrene grafted to said backbone. 
     
     
         33 . The CPVC pipe of  claim 26  wherein the filler is selected from the group consisting of carbon black and titanium dioxide, wherein the filler has a primary particle size which is within the range of about 0.01 μm to 3 μm with about 90 percent of the particles being in the particle size range of about 0.01 μm to 2 μm. 
     
     
         34 . A piping system which is comprised of multiple lengths of the CPVC pipe of  claim 19  and multiple CPVC pipe fittings. 
     
     
         35 . The piping system of  claim 34  wherein said CPVC pipe and said CPVC pipe fittings are joined together by an adhesive. 
     
     
         36 . The piping system of  claim 35  wherein said adhesive is a solvent cement adhesive comprising CPVC resin. 
     
     
         37 . A chlorinated polyvinyl chloride composition comprising: (a) 100 parts by weight of a CPVC resin, wherein the CPVC resin has a chlorine content which is within the range of 66.5 percent to 70 percent by weight and made from PVC having an inherent viscosity of at least 0.88; (b) about 5 to about 6 parts by weight of an impact modifier which is a graft copolymer having a polydiene rubber backbone with styrene, acrylonitrile, and/or an acrylate monomer grafted to the polydiene rubber backbone; (c) about 1 to about 7 parts by weight of an inert filler, (d) about 1.3 to about 3.5 parts by weight of a lubricant; and (e) about 1.25 to about 3 parts by weight of an organotin stabilizer; wherein the composition when compression molded into a plaque, exhibits a notched Izod impact strength of at least 266.9 J/m (5 ft·lb/in) of notch, a tensile strength of at least 48.3 MPa (7,000 psi), a modulus of elasticity of at least 2482 MPa (360,000 psi), and a heat deflection temperature (HDT) under a 1.82 MPa (264 psi) load of at least 110° C. with annealing, to meet requirements of cell class 2-4-4-4-8. 
     
     
         38 . The chlorinated polyvinyl chloride composition of  claim 37  which is further comprised of from about 1.5 to about 3 parts by weight of a chlorinated polyethylene having a chlorine content which is within the range of about 32 weight percent to about 40 weight percent and a weight average molecular weight which is within the range of 120,000 to 400,000 Daltons. 
     
     
         39 . The chlorinated polyvinyl chloride composition of  claim 38  which is further comprised of about 0.1 to about 1 part by weight of an antioxidant. 
     
     
         40 . The chlorinated polyvinyl chloride composition of  claim 37  which is extruded into the form of a pipe having dimensions as specified in ASTM F441. 
     
     
         41 . The chlorinated polyvinyl chloride composition of  claim 40  wherein the extruded pipe has dimensions of schedule 40 or schedule 80 as specified in ASTM F441. 
     
     
         42 . The chlorinated polyvinyl chloride composition of  claim 37  which is in the form of an extruded pipe having dimensions as specified in ASTM F442 selected from the group consisting of SDR-7, SDR-9, SDR-11, SDR-13.5, SDR-17, SDR-21, SDR-26, and SDR-32.5. 
     
     
         43 . The chlorinated polyvinyl chloride composition of  claim 37  wherein when said composition is extruded into a pipe, said pipe is of cell class 2-4-4-4-7. 
     
     
         44 . The chlorinated polyvinyl chloride composition of  claim 37  wherein when said composition is extruded into a pipe, said pipe is of cell class 2-4-4-4-8. 
     
     
         45 . The chlorinated polyvinyl chloride composition of  claim 37  further comprising a co-stabilizer in the amount of from about 0.1 to about 1.0 part by weight. 
     
     
         46 . The chlorinated polyvinyl chloride composition of  claim 45  wherein said co-stabilizer is a zeolite.