Ethylene acid copolymers, their ionomers, and their use in packaging films and injection molded articles

Abstract

Provided are novel ethylene acid copolymers, their ionomers and their use in various articles, including packaging films and injection molded articles. The ethylene acid copolymers comprise copolymerized units of ethylene, about 10 to about 30 wt % of copolymerized units of a first α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms; and about 5 to about 15 wt % of copolymerized units of a derivative of a second α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms. Preferred derivatives include esters, and in particular alkyl esters. These ethylene acid copolymers and ionomers have improved optical properties when compared to conventional ethylene acrylic or methacrylic acid copolymers and their ionomers.

What is claimed is: 
     
         1 . An ethylene acid copolymer comprising copolymerized units of ethylene, about 10 to about 30 wt % of copolymerized units of a first α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms; and about 5 to about 15 wt % of copolymerized units of a derivative of a second α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms; wherein the weight percentages of the copolymerized units are based on the total weight of the ethylene copolymer and the sum of the weight percentages of the copolymerized units is 100 wt %; optionally wherein at least a portion of the carboxylic acid groups of the first α,β-unsaturated carboxylic acid are neutralized to form an ionomer comprising carboxylate groups having counterions. 
     
     
         2 . The ethylene acid copolymer or ionomer of  claim 1 , wherein about 5% to about 90% of the carboxylic acid groups present in the ethylene copolymer have been neutralized. 
     
     
         3 . The ethylene acid copolymer or the ionomer of  claim 1 , wherein the ethylene copolymer comprises about 20 wt % to about 24 wt % of copolymerized units of the first α,β-ethylenically unsaturated carboxylic acid. 
     
     
         4 . The ethylene acid copolymer or the ionomer of  claim 1 , wherein the ethylene copolymer comprises about 8 wt % to about 12 wt % of copolymerized units of the derivative of the second α,β-ethylenically unsaturated carboxylic acid. 
     
     
         5 . The ethylene acid copolymer or the ionomer of  claim 1 , wherein the sum of the weight percentages of the copolymerized acid and of the copolymerized acid derivative is about 20 to about 45 wt %. 
     
     
         6 . The ethylene acid copolymer or the ionomer of  claim 1 , wherein the α,β-ethylenically unsaturated carboxylic acid is acrylic acid, methacrylic acid, or a combination of acrylic acid and methacrylic acid. 
     
     
         7 . A polymer composition comprising the ethylene acid copolymer or the ionomer of  claim 1  and a hydroxyl-containing crosslinking agent. 
     
     
         8 . The polymer composition of  claim 7 , wherein the hydroxyl-containing crosslinking agent is a diol. 
     
     
         9 . The polymer composition of  claim 7 , further comprising an adjuvant selected from the group consisting of N-(2-aminoethyl-3-aminopropyl)trimethoxysilane, 3-glycidoxypropyl trimethoxysilane, and combinations thereof, in amounts of between about 0.025 and 2.0 wt %. 
     
     
         10 . A product of cross-linking the polymer composition of  claim 7 . 
     
     
         11 . A sheet or film comprising the ethylene acid copolymer or the ionomer of  claim 1 . 
     
     
         12 . The film of  claim 11  that is a blown film. 
     
     
         13 . An injection molded article comprising the ethylene acid copolymer or the ionomer of  claim 1 . 
     
     
         14 . A golf ball comprising the ethylene acid copolymer or the ionomer of  claim 1 . 
     
     
         15 . A package comprising the sheet or film of  claim 11 . 
     
     
         16 . A sheet or film comprising the composition of  claim 7  or a product of cross-linking the composition of  claim 7 . 
     
     
         17 . The film of  claim 16  that is a blown film. 
     
     
         18 . An injection molded article comprising the composition of  claim 7  or a product of cross-linking the composition of  claim 7 . 
     
     
         19 . A golf ball comprising the composition of  claim 7  or a product of cross-linking the composition of  claim 7 . 
     
     
         20 . A package comprising the sheet or film of  claim 16 .