Photocatalytically active polysiloxane coating compositions

Abstract

The invention is a coating composition comprising photocatalytic titanium dioxide particles, an opacifying agent, a silicone compound, de-HNO 3 particles, styrene resin hollow microspheres, and a solvent. The combination of a silicone compound and styrene resin hollow microspheres in a depolluting coating composition results in improved opacity and durability compared to conventional coatings.

1 . In a photocatalytically active polysiloxane composition for coating a substrate comprising:
 (a) from 0.5% to 20% by weight, based on the total weight of the composition, of photocatalytic titanium dioxide particles having a mean particle size between 2 nm and 100 nm;   (b) from 0.05% to 40% by weight of calcium carbonate particles, wherein the ratio of calcium carbonate particles to photocatalytic titanium dioxide particles is from 0.01 to 50; and   (c) a solvent selected from water, an organic solvent or a mixed solvent consisting of water and an organic solvent, the improvement comprising incorporating into said polysiloxane composition from 0.1% to 20% by weight (expressed in dry matter), based on the total weight of the composition, of hollow styrene resin microspheres having an outside diameter of from 0.1 μm to 10 μm whereby
 (i) the opacity of a dry film coating formed from said polysiloxane composition is greater than the opacity of a dry film coating formed from the same polysiloxane composition that does not include said hollow styrene resin microspheres, and 
 (ii) percent weight loss of said dry film coating over a defined time period is less than percent weight loss of the same polysiloxane dry film coating over the same defined time period, but without having said hollow styrene resin microspheres present in the polysiloxane composition. 
   
     
     
         2 . The coating composition of  claim 1  wherein the styrene resin hollow microspheres are selected from the group consisting of polystyrene, poly-α-methylstyrene, and styrene-acrylic copolymer resins. 
     
     
         3 . The coating composition of  claim 2  wherein the styrene resin hollow microspheres are selected from styrene-acrylic copolymer resins.