Polycrystalline diamond

Abstract

An embodiment of a PCD insert comprises an embodiment of a PCD element joined to a cemented carbide substrate at an interface. The PCD element has internal diamond surfaces defining interstices between them. The PCD element comprises a masked or passivated region and an unmasked or unpassivated region, the unmasked or unpassivated region defining a boundary with the substrate, the boundary being the interface. At least some of the internal diamond surfaces of the masked or passivated region contact a mask or passivation medium, and some or all of the interstices of the masked or passivated region and of the unmasked or unpassivated region are at least partially filled with an infiltrant material.

1 . A method for manufacturing a PCD element; the method including providing a PCD body having internal diamond surfaces, the internal diamond surfaces defining interstices, the PCD body containing a thermally stable region and a porous region, in which at least some of the interstices contain at least partly unfilled pores; introducing a mask or passivation medium proximate or into the thermally stable region; and introducing at least one infiltrant material into the porous region, the mask or passivation medium at least partly isolating diamond of the thermally stable region from chemical interaction with the at least one infiltrant material, wherein a controlled temperature cycle is employed in such a manner as to allow sufficient or a certain amount of the mask or passivation medium or its precursor to be introduced proximate or into the thermally stable region prior to the at least one infiltrant material melting and infiltrating into the porous PCD body. 
     
     
         2 . A method as claimed in  claim 1 , in which the thermally stable region is at least partly porous. 
     
     
         3 . A method as claimed in  claim 1 , the method including coating some or all of the internal diamond surfaces of the thermally stable region, at least partially, with a mask or passivation medium. 
     
     
         4 . A method as claimed in  claim 1 , the method including chemically isolating diamond from chemical interaction with the infiltrant material. 
     
     
         5 . A method as claimed in  claim 1 , in which the PCD body is porous throughout. 
     
     
         6 . A method for manufacturing a PCD element; the method including providing a PCD body having internal diamond surfaces, the internal diamond surfaces defining interstices, the PCD body containing a thermally stable region and a porous region, in which at least some of the interstices contain at least partly unfilled pores; introducing a mask or passivation medium proximate or into the thermally stable region; and thereafter introducing at least one infiltrant material into the porous region, the mask or passivation medium at least partly isolating diamond of the thermally stable region from chemical interaction with the at least one infiltrant material. 
     
     
         7 . A method as claimed in  claim 1 , the method including introducing the mask or passivation medium under HPHT conditions. 
     
     
         8 . A method for manufacturing a PCD element; the method including providing a PCD body having internal diamond surfaces, the internal diamond surfaces defining interstices, the PCD body containing a thermally stable region and a porous region, in which at least some of the interstices contain at least partly unfilled pores; introducing a mask or passivation medium proximate or into the thermally stable region; and introducing at least one infiltrant material into the porous region, the mask or passivation medium at least partly isolating diamond of the thermally stable region from chemical interaction with the at least one infiltrant material, the mask or passivation medium being introduced proximate or into the thermally stable region under conditions other than HPHT conditions. 
     
     
         9 . A method as claimed in  claim 8 , the method including introducing the mask or passivation medium in a gas or vapour phase, as an inert salt or ceramic phase, or using surface chemistry modification of the internal diamond surfaces in the masked or passivated region. 
     
     
         10 . A method as claimed in  claim 9 , the method including introducing the mask or passivation medium by atomic layer deposition, infiltration with a liquid pre-ceramic polymer or polymer solution, using a sol gel or other solution-based chemical route, or a vapour comprising a metal composition. 
     
     
         11 . A method as claimed in  claim 10 , the method including introducing tungsten hexafluoride as a vapour, thereby to deposit tungsten as the mask or passivation medium. 
     
     
         12 . A method as claimed in  claim 1 , the method including introducing the infiltrant material into a volume of the PCD body, the volume being at least about 10 percent of the total volume of the PCD body. 
     
     
         13 . A method as claimed in  claim 1 , the method including introducing the infiltrant material into a volume of the PCD body that is proximate a surface of the PCD body, the surface being remote from or opposing the interface, the volume having a depth from the surface of at least about 0.1 mm. 
     
     
         14 . A method as claimed in  claim 1 , in which the masked or passivated region defines a barrier between the thermally stable region and the infiltrant material.