Heat-dissipating film, and its production method and apparatus

Abstract

A heat-dissipating film comprising a heat-conductive layer obtained by burning a mixture layer of flaky carbon and a binder resin to carbonize or burn off the binder resin, and plastic films covering the heat-conductive layer, the heat-conductive layer having a density of 1.9 g/cm 3 or more and thermal conductivity of 450 W/mk or more, is produced by (1) sandwiching a mixture layer of flaky carbon and a binder resin with a pair of first plastic films to form a laminated film; (2) heat-pressing the laminated film to densify the mixture layer; (3) burning the mixture layer to carbonize the binder resin in the mixture layer; (4) pressing the resultant burnt layer to form the heat-conductive layer; and (5) sealing the heat-conductive layer with second plastic films.

1 . A heat-dissipating film comprising a heat-conductive layer obtained by burning a mixture layer of flaky carbon and a binder resin to carbonize or burn off said binder resin, and plastic films covering said heat-conductive layer; said flaky carbon in said heat-conductive layer being aligned substantially in parallel; and said heat-conductive layer having a density of 1.9 g/cm 3  or more and thermal conductivity of 450 W/mk or more. 
     
     
         2 . The heat-dissipating film according to  claim 1 , wherein said flaky carbon is graphite or graphene. 
     
     
         3 . The heat-dissipating film according to  claim 1 , wherein said heat-conductive layer has a density of 2 g/cm 3  or more and thermal conductivity of 600 W/mk or more. 
     
     
         4 . The heat-dissipating film according to  claim 1 , wherein said heat-conductive layer has a thickness of 50-250 g/m 2  (expressed by the weight of flaky carbon per 1 m 2 ). 
     
     
         5 . (canceled) 
     
     
         6 . A method for producing a heat-dissipating film comprising the steps of (1) sandwiching a mixture layer of flaky carbon and a binder resin with a pair of first plastic films to form a laminated film; (2) heat-pressing said laminated film to densify said mixture layer; (3) burning said mixture layer exposed by peeling said first plastic films to carbonize or burn off said binder resin in said mixture layer; (4) pressing the resultant burnt layer to form a densified heat-conductive layer; and (5) sealing said heat-conductive layer with second plastic films. 
     
     
         7 . The method for producing a heat-dissipating film according to  claim 6 , wherein a step of applying a dispersion comprising 5-25% by mass of flaky carbon and 0.05-2.5% by mass of a binder resin in an organic solvent, a mass ratio of said binder resin to said flaky carbon being 0.01-0.1, to a surface of each first plastic film, and then drying said dispersion is repeated plural times, to form said mixture layer. 
     
     
         8 . The method for producing a heat-dissipating film according to  claim 6 , wherein the amount of said dispersion applied by one operation is 5-30 g/m 2  (expressed by the weight of flaky carbon per 1 m 2 ). 
     
     
         9 . The method for producing a heat-dissipating film according to  claim 6 , wherein said binder resin is an acrylic resin, a polystyrene resin or polyvinyl alcohol. 
     
     
         10 . The method for producing a heat-dissipating film according to  claim 6 , wherein said laminated film is heat-pressed by passing through at least a pair of heating rolls. 
     
     
         11 . The method for producing a heat-dissipating film according to  claim 10 , wherein the heat-pressing temperature is 150-250° C., and the heat-pressing pressure is 20 MPa or more. 
     
     
         12 . The method for producing a heat-dissipating film according to  claim 6 , wherein to carbonize said binder resin in said mixture layer, said mixture layer is burned by exposing both surfaces thereof to a flame, or exposing a die containing said mixture layer to a high temperature of 500° C. or higher. 
     
     
         13 . The method for producing a heat-dissipating film according to  claim 6 , wherein said burnt layer is pressed in a die constraining at least a pair of opposing sides of said burnt layer. 
     
     
         14 . The method for producing a heat-dissipating film according to  claim 6 , wherein a lower die part having a cavity and an upper die part having a projection received in said cavity are used wherein after said burnt layer is put in the cavity of said lower die part, said upper die part is combined with said lower die part such that said projection enters said cavity; and wherein the combined upper and lower die parts are caused to pass through a gap between a pair of pressing rolls plural times, to densify said burnt layer. 
     
     
         15 . The method for producing a heat-dissipating film according to  claim 13 , wherein said burnt layer is pressed while vibrating a die containing said burnt layer. 
     
     
         16 . An apparatus for producing a heat-dissipating film comprising (a) a means for conveying a pair of first plastic films; (b) at least one dispersion-applying means disposed for each first plastic film, such that a dispersion comprising flaky carbon and a binder resin is applied to said first plastic film plural times; (c) a means for drying each applied dispersion; (d), a means for laminating a pair of said first plastic films each having the resultant mixture layer comprising said flaky carbon and said binder resin, with the said mixture layer inside; (e) a means for heat-pressing the resultant laminated film; (f) a means for peeling said first plastic films from said laminated film; (g) a means for burning said mixture layer, such that the exposed binder resin in said mixture layer is carbonized; (h) a pressing die means for densifying the resultant burnt layer to form a heat-conductive layer; and (i) a means for sealing said heat-conductive layer with second plastic films. 
     
     
         17 . The apparatus for producing a heat-dissipating film according to  claim 16 , which comprises pluralities of dispersion-applying means arranged with predetermined intervals along the movement direction of each first plastic film. 
     
     
         18 . The apparatus for producing a heat-dissipating film according to  claim 16 , wherein a pair of dispersion-applying means and laminating rolls are disposed in said chamber; and wherein said chamber comprises first openings through which the first plastic films enter, a pair of hot air inlets disposed near said first openings, a gas outlet, and a second opening through which said laminated film exits. 
     
     
         19 . The apparatus for producing a heat-dissipating film according to  claim 16 , wherein said means for burning said mixture layer is a burner ejecting a flame onto each surface of said mixture layer, or a die containing said mixture layer and exposed to a high temperature of 500° C. or higher. 
     
     
         20 . The apparatus for producing a heat-dissipating film according to  claim 16 , wherein said pressing die means for densifying the burnt layer comprises (a) a die comprising a lower die part having a cavity, and an upper die part having a projection engageable with said cavity; (b) a pair of pressing rolls for pressing said die from above and below; (c) guide plates extending upstream and downstream of a gap of said rolls; and (d) a means for reciprocating said die along said guide plates, such that it passes through a gap between a pair of said pressing rolls. 
     
     
         21 . (canceled)