Foamable resin composition for foam sheet, foam sheet, process for preparing particulate polylactic acid and process for preparing foam sheet

Abstract

Disclosed herein is a foamable resin composition for a foam sheet including polylactic acid resin particles, each of the particles having a particle size of about 1 μm to about 100 μm. A process for preparing a particulate polylactic acid resin includes: introducing a polylactic acid resin and then forming a molten polylactic acid spray solution; and injecting the molten polylactic acid spray solution by a melt spray method and simultaneously cooling the molten polylactic acid spray solution to obtain a particulate polylactic acid. In addition, disclosed herein is a process for preparing a foam sheet using the foamable resin composition for a foam sheet including a polylactic acid resin.

1 . A foamable resin composition for a foam sheet comprising polylactic acid resin particles, each of the particles having a particle size of 1 μm to 100 μm. 
     
     
         2 . The foamable resin composition according to  claim 1 , wherein a foam sheet prepared by molding the composition comprises a polylactic acid resin having a weight average molecular weight of 100,000 to 200,000. 
     
     
         3 . The foamable resin composition according to  claim 1 , wherein the composition is a suspension in which the polylactic acid resin particles are dispersed in a liquid solvent. 
     
     
         4 . A foam sheet comprising polylactic acid resin particles, each of the particles having a particle size of 1 μm to 100 μm. 
     
     
         5 . The foam sheet according to  claim 4 , wherein the foam sheet comprises a polylactic acid resin having a weight average molecular weight of 100,000 to 200,000. 
     
     
         6 . A process for preparing a particulate polylactic acid resin comprising:
 introducing a polylactic acid resin and then forming a molten polylactic acid spray solution; and   spraying the molten polylactic acid spray solution by a melt spray method and simultaneously cooling the molten polylactic acid spray solution to obtain a particulate polylactic acid.   
     
     
         7 . The process according to  claim 6 , wherein the polylactic acid resin is introduced into an extruder, and then transferred to an spray nozzle and heated in the spray nozzle to form the molten polylactic acid spray solution. 
     
     
         8 . The process according to  claim 7 , wherein the polylactic acid resin in the form of pellet or powder is introduced into the extruder. 
     
     
         9 . The process according to  claim 8 , wherein the molten polylactic acid spray solution is introduced into the spray nozzle together with an air and then discharged. 
     
     
         10 . The process according to  claim 9 , wherein a temperature of the air that is injected into the spray nozzle is of 300° C. to 500° C., a pressure of the air that is injected into the spray nozzle is of 100 psi to 1,000 psi, and an injection speed of the air that is injected into the spray nozzle is of 10 m/s to 50 m/s. 
     
     
         11 . The process according to  claim 7 , wherein a temperature of the spray nozzle is of 200° C. to 400° C. 
     
     
         12 . The process according to  claim 7 , wherein a pressure of the spray nozzle is of 10 psi to 1,000 psi. 
     
     
         13 . The process according to  claim 7 , wherein a diameter of the spray nozzle is of 0.5 mm to 3.0 mm. 
     
     
         14 . The process according to  claim 6 , wherein the molten polylactic acid spray solution comprises at least one additive selected from the group consisting of a lubricant, a plasticizer, and a combination thereof. 
     
     
         15 . The process according to  claim 6 , wherein the molten polylactic acid spray solution has a viscosity of 1,500 cps to 2,000 cps at 250° C. 
     
     
         16 . The process according to  claim 7 , wherein a voltage of 2,000 V to 50,000 V is applied to the spray nozzle to carry out a melt electrostatic spray deposition. 
     
     
         17 . The process according to  claim 6 , wherein the particulate polylactic acid resin has an average particle size of 1 μm to 100 μm. 
     
     
         18 . (canceled) 
     
     
         19 . (canceled) 
     
     
         20 . (canceled)