Polycarbonate resins and processes for producing the same

Abstract

The invention is to provide polycarbonate resins having excellent light resistance, transparency, hue, heat resistance, thermal stability, and mechanical strength and to provide processes for efficiently and stably producing a polycarbonate resin which stably shows those performances. The invention includes: polycarbonate resins which at least contain structural units derived from a dihydroxy compound having the portion represented by formula (1) as part of the structure thereof and which have specific properties; and processes for producing the polycarbonate resins, where the case where the portion represented by formula (1) is part of —CH 2 —O—H is excluded.

1 : A polycarbonate resin which at least contains structural units derived from a dihydroxy compound having the portion represented by formula (1) as part of the structure thereof, the polycarbonate resin giving a molded object (thickness, 3 mm) which has a yellowness index (YI) value, as measured with respect to transmitted light in accordance with ASTM D1925-70, of 12 or less after having been irradiated with light for 100 hours using a metal halide lamp in an environment of 63° C. and a relative humidity of 50% at an irradiance for the wavelength range of 300-400 nm of 1.5 kW/m 2 , 
       
         
           
           
               
               
           
         
         wherein the case where the portion represented by formula (1) is part of —CH 2 —O—H is excluded. 
       
     
     
         2 : The polycarbonate resin of  claim 1 , wherein the molded object (thickness, 3 mm) formed from the polycarbonate resin has an initial yellowness index value of 10 or less. 
     
     
         3 : The polycarbonate resin of  claim 1 , wherein the difference between the initial yellowness index value of the molded object (thickness, 3 mm) formed from the polycarbonate resin and the yellowness index (YI) value thereof measured with respect to transmitted light in accordance with ASTM D1925-70 after the molded object has been irradiated with light for 100 hours using a metal halide lamp in an environment of 63° C. and a relative humidity of 50% at an irradiance for the wavelength range of 300-400 nm of 1.5 kW/m 2  is 6 or less in terms of absolute value. 
     
     
         4 : The polycarbonate resin as claimed in  claim 1 , wherein the molded object (thickness, 3 mm) formed from the polycarbonate resin has a light transmittance, as measured at a wavelength of 350 nm, of 60% or higher. 
     
     
         5 : A polycarbonate resin obtained by condensation-polymerizing at least one dihydroxy compound including a dihydroxy compound which has the portion represented by formula (1) as part of the structure thereof with a carbonic diester represented by formula (2) in the presence of a catalyst, the catalyst comprising one or more compounds containing at least one metal selected from the group consisting of lithium and the Group-2 metals of the long-form periodic table, the polycarbonate resin having a content of the metal-containing compounds of 20 μmol or less in terms of metal amount per mole of the dihydroxy compound and containing an aromatic monohydroxy compound in an amount of 700 weight ppm or less, 
       
         
           
           
               
               
           
         
         wherein the case where the portion represented by formula (1) is part of —CH 2 —O—H is excluded, 
       
       
         
           
           
               
               
           
         
         wherein, in formula (2), A 1  and A 2  each independently are a substituted or unsubstituted aliphatic group having 1-18 carbon atoms or a substituted or unsubstituted aromatic group, and 
         wherein the polycarbonate resin has contains the carbonic diester represented by formula (2) in an amount of 60 weight ppm or less. 
       
     
     
         6 : The polycarbonate resin of  claim 5 , wherein the catalyst comprises at least one metal compound selected from the group consisting of magnesium compounds and calcium compounds. 
     
     
         7 : The polycarbonate resin as claimed in  claim 5 , wherein the dihydroxy compound having the portion represented by formula (1) as part of the structure thereof is a compound represented by formula (4) 
       
         
           
           
               
               
           
         
       
     
     
         8 : The polycarbonate resin of  claim 5 , which contains structural units derived from the dihydroxy compound that has the portion represented by formula (1) as part of the structure thereof and further contains structural units derived from at least one compound selected from the group consisting of aliphatic dihydroxy compounds and alicyclic dihydroxy compounds. 
     
     
         9 : The polycarbonate resin as claimed in  claim 5 , wherein the concentration of the end group represented by formula (3) in the polycarbonate resin is 20-160 μeq/g 
       
         
           
           
               
               
           
         
       
     
     
         10 : The polycarbonate resin of  claim 5 , which satisfies A/(A+B)≦0.1, wherein A is the number of moles of the H bonded to the aromatic rings contained in the polycarbonate resin and B is the number of moles of the H bonded to the part other than the aromatic rings. 
     
     
         11 : The polycarbonate resin of  claim 5 , wherein a molded object (thickness, 3 mm) formed from the polycarbonate resin has a light transmittance, as measured at a wavelength of 350 nm, of 60% or higher. 
     
     
         12 : The polycarbonate resin of  claim 5 , wherein a molded object (thickness, 3 mm) formed from the polycarbonate resin has a light transmittance, as measured at a wavelength of 320 nm, of 30% or higher. 
     
     
         13 : The polycarbonate resin of  claim 5 , wherein a molded object (thickness, 3 mm) formed from the polycarbonate resin has a yellowness index (YI) value, as measured with respect to transmitted light in accordance with ASTM D1925-70, of 12 or less after having been irradiated with light for 100 hours using a metal halide lamp in an environment of 63° C. and a relative humidity of 50% at an irradiance for the wavelength range of 300-400 nm of 1.5 kW/m 2 . 
     
     
         14 : The polycarbonate resin of  claim 5 , wherein a molded object (thickness, 3 mm) formed from the polycarbonate resin has an initial yellowness index value of 10 or less. 
     
     
         15 : The polycarbonate resin of  claim 5 , wherein the difference between the initial yellowness index value of a molded object (thickness, 3 mm) formed from the polycarbonate resin and the yellowness index (YI) value thereof measured with respect to transmitted light in accordance with ASTM D1925-70 after the molded object has been irradiated with light for 100 hours using a metal halide lamp in an environment of 63° C. and a relative humidity of 50% at an irradiance for the wavelength range of 300-400 nm of 1.5 kW/m 2  is 6 or less in terms of absolute value.