US2016319406A1PendingUtilityA1

High Strength Precipitation Hardenable Stainless Steel

Assignee: CRS HOLDINGS INCPriority: Dec 6, 2012Filed: Jul 14, 2016Published: Nov 3, 2016
Est. expiryDec 6, 2032(~6.4 yrs left)· nominal 20-yr term from priority
C21D 6/02C21D 6/04C21D 9/0068C21D 6/004C22C 38/002C22C 38/02C21D 2211/008C22C 38/04C21D 1/06C22C 38/06C22C 38/001C22C 38/004C22C 38/54C22C 38/50C22C 38/48C22C 38/44C22C 38/52
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Claims

Abstract

A precipitation hardenable, martensitic stainless steel alloy is disclosed. The alloy has the following composition in weight percent, about C 0.03 max Mn 1.0 max Si 0.75 max P 0.040 max S 0.020 max Cr 10-13 Ni 10.5-11.6 Mo 0.25-1.5  Co 0.5-1.5 Cu 0.75 max Ti 1.5-1.8 Al 0.3-0.8 Nb 0.3-0.8 B 0.010 max N 0.030 max The balance is iron and usual impurities. The disclosed alloy provides a unique combination of corrosion resistance, strength, and toughness.

Claims

exact text as granted — not AI-modified
1 . A precipitation hardenable, martensitic stainless steel alloy consisting essentially of, in weight percent, 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Mn 
                   up to about 1.0 
                 
                     
                   Si 
                   up to about 0.75 
                 
                     
                   Cr 
                   about 10 to about 13 
                 
                     
                   Ni 
                   about 10.75 to about 11.6 
                 
                     
                   Mo 
                   about 0.25 to about 1.5 
                 
                     
                   Cu 
                   not more than about 0.25 
                 
                     
                   Co 
                   about 0.9 to about1.5 
                 
                     
                   Ti 
                   about 1.5 to about 1.8 
                 
                     
                   Al 
                   about 0.4 to about 0.8 
                 
                     
                   Cb 
                   about 0.3 to about 0.6 
                 
                     
                   B 
                   up to about 0.010 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
       and the balance is iron and usual impurities, said impurities including about 0.040% max. phosphorus, about 0.005% max. sulfur, about 0.03% max. carbon, and about 0.030% max. nitrogen. 
     
     
         2 . The alloy recited in  claim 1  which contains at least about 0.4% columbium. 
     
     
         3 . The alloy recited in  claim 1  which contains at least about 10.5% chromium. 
     
     
         4 . The alloy recited in  claim 1  which contains not more than about 12.5% chromium. 
     
     
         5 . The alloy recited in  claim 1  which contains not more than about 1.7% titanium. 
     
     
         6 . The alloy recited in  claim 1  which contains not more than about 1.25% molybdenum. 
     
     
         7 . The alloy recited in  claim 1  which contains at least about 0.75 weight percent molybdenum. 
     
     
         8 . The alloy recited in  claim 1  which further contains up to about 0.005% calcium. 
     
     
         9 . The alloy recited in  claim 1  which further contains up to about 0.025% cerium. 
     
     
         10 . A precipitation hardenable, martensitic stainless steel alloy consisting essentially of, in weight percent, 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Mn 
                   up to about 0.25 
                 
                     
                   Si 
                   up to about 0.25 
                 
                     
                   Cr 
                   about 10.5 to about 12.5 
                 
                     
                   Ni 
                   about 10.75 to about 11.25 
                 
                     
                   Mo 
                   about 0.75 to about 1.25 
                 
                     
                   Cu 
                   not more than about 0.25 
                 
                     
                   Co 
                   about 0.9 to about 1.25 
                 
                     
                   Ti 
                   about 1.5 to about 1.7 
                 
                     
                   Al 
                   about 0.45 to about 0.8 
                 
                     
                   Cb 
                   about 0.4 to about 0.6 
                 
                     
                   B 
                   about 0.001 to about 0.005 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
       and the balance is iron and usual impurities, said impurities including about 0.015% max. phosphorus, about 0.005% max. sulfur, about 0.02% max. carbon, and about 0.015% max. nitrogen. 
     
     
         11 . The alloy recited in  claim 10  which contains not more than about 1.1% cobalt. 
     
     
         12 . The alloy recited in  claim 10  which contains at least about 10.85% nickel. 
     
     
         13 . The alloy recited in  claim 10  which contains not more than about 0.6% columbium. 
     
     
         14 . The alloy recited in  claim 10  which contains at least about 0.45% aluminum. 
     
     
         15 . The alloy recited in  claim 10  which contains not more than about 0.65% aluminum. 
     
     
         16 . The alloy recited in  claim 10  which contains at least about 0.9% molybdenum. 
     
     
         17 . The alloy recited in  claim 10  which further contains up to about 0.005% calcium. 
     
     
         18 . The alloy recited in  claim 10  which further contains up to about 0.025% cerium. 
     
     
         19 . A precipitation hardenable, martensitic stainless steel alloy consisting essentially of, in weight percent, 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Mn 
                   up to about 0.10 
                 
                     
                   Si 
                   up to about 0.10 
                 
                     
                   Cr 
                   about 11.0 to about 12.0 
                 
                     
                   Ni 
                   about 10.85 to about 11.25 
                 
                     
                   Mo 
                   about 0.9 to about 1.1 
                 
                     
                   Co 
                   about 0.9 to about 1.1 
                 
                     
                   Cu 
                   not more than about 0.25 
                 
                     
                   Ti 
                   about 1.5 to about 1.7 
                 
                     
                   Al 
                   about 0.45 to about 0.65 
                 
                     
                   Cb 
                   about 0.4 to about 0.6 
                 
                     
                   B 
                   about 0.0015 to about 0.0035 
                 
                     
                   Ca 
                   up to about 0.005 
                 
                     
                   Ce 
                   up to about 0.025 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
       and the balance is iron and usual impurities, said impurities including about 0.010% max. phosphorus, about 0.005% max. sulfur, about 0.015% max. carbon, and about 0.010% max. nitrogen.

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