Waterless printing members and related methods

Abstract

In various embodiments, a recording medium comprises an oleophilic substrate and, thereover, a topmost oleophobic layer comprising a cured polymeric silicone matrix that consists essentially of the addition-cure reaction product of a vinyl-functional polydialkylsiloxane and a silane cross-linking agent. The vinyl-functional polydialkylsiloxane has a molecular weight ranging from 30,000 to 75,000 or 110,000 to 130,000. If the molecular weight of the vinyl-functional polydialkylsiloxane is within the range of 30,000 to 75,000, the molar ratio of silane groups to vinyl groups is within the range of about 11:1 to about 25:1; and if the molecular weight of the vinyl-functional polydialkylsiloxane is within the range of 110,000 to 130,000, the molar ratio of silane groups to vinyl groups is from about 5:1 to about 27:1. The recording medium may be used as a lithographic printing plate.

1 - 28 . (canceled) 
     
     
         29 . A recording medium comprising an oleophilic substrate and, thereover, a topmost oleophobic layer comprising a cured polymeric silicone matrix that consists essentially of the addition-cure reaction product of a vinyl-functional polydialkylsiloxane and a silane cross-linking agent, wherein:
 a) the vinyl-functional polydialkylsiloxane has a molecular weight ranging from 110,000 to 130,000; and   b) a molar ratio of silane groups in the cross-linking agent to vinyl groups in the polydialkylsiloxane is from about 5:1 to about 27:1.   
     
     
         30 . The recording medium of  claim 29 , wherein the vinyl-functional polydialkylsiloxane is vinyl-functional polydimethylsiloxane. 
     
     
         31 . The recording medium of  claim 29 , wherein the molar ratio of silane groups in the cross-linking agent to vinyl groups in the polydialkylsiloxane is from about 20:1 to 27:1. 
     
     
         32 . The recording medium of  claim 29 , wherein the silane cross-linking agent is a trimethylsiloxy-terminated polymethylhydrosiloxane. 
     
     
         33 . The recording medium of  claim 29 , wherein the topmost oleophobic layer has a dry coat weight of 2 g/m 2 . 
     
     
         34 . The recording medium of  claim 29 , wherein the substrate comprises a polyester film. 
     
     
         35 . The recording medium of  claim 29 , wherein the substrate comprises a metal sheet having an oleophilic coating thereover. 
     
     
         36 . The recording medium of  claim 29 , further comprising a laser-ablatable imaging layer between the substrate and the topmost layer. 
     
     
         37 . The recording medium of  claim 36 , wherein the imaging layer is ablatable upon exposure to a laser beam having a fluence of at least 250 mJ/cm 2 . 
     
     
         38 . The recording medium of  claim 37 , wherein the imaging layer is a thin metal/metal oxide layer. 
     
     
         39 . The recording medium of  claim 38 , wherein the imaging layer has a thickness no greater than 50 nm.