Use Of Compounds Revealing The Efficiency Of Filterability Additives In Hydrocarbon Distillates, And Synergic Composition Containing Same

Abstract

The invention relates to the use, in a hydrocarbon distillate with a boiling temperature of between 150 and 450° C. and a crystallization onset temperature as measured by Differential Calorimetric Analysis of greater than or equal to −50° C., preferably of −5° C. to +10° C., of a homopolymer obtained from an olefinic ester of carboxylic acid of 3 to 12 carbon atoms and from a fatty alcohol containing a chain of more than 16 carbon atoms and optionally an olefinic double bond, as a compound for revealing the efficiency of filterability additives based on copolymer and/or terpolymers of ethylene and of vinyl ester of a carboxylic acid of 3 to 12 carbon atoms, and of a monoalcohol containing 1 to 10 carbon atoms. The invention is also directed to an additive composition comprising a conventional hydrocarbon filterability additive in combination with an efficiency reveal additive, and also to the combustion fuels, motor fuel and oil fuel that comprise these additive combinations.

What is claimed is: 
     
         1 . A method of improving the activity of filterability additives, added to a hydrocarbon distillate, the method comprising:
 adding a polyacrylate to a hydrocarbon distillate containing filterability additives, the filterability additives comprising a copolymer and/or terpolymer of ethylene and of a vinyl ester of a carboxylic acid with 2 to 5 carbon atoms and of a monoalcohol comprising 1 to 10 carbon atoms, the hydrocarbon distillate being resistant to the filterability additives,   wherein the polyacrylate comprises side hydrocarbon chains with 18-40 carbon atoms, and the hydrocarbon distillate has a boiling temperature comprised between 150 and 450° C., an onset crystallization temperature as measured by differential scanning calorimetry analysis, greater than or equal to −5° C., and a weight content of n-paraffins containing more than 18 carbon atoms greater than 4%,   wherein the polyacrylate cooperates synergistically with the filterability additives to increase the filterability of the hydrocarbon distillate, and   wherein the polyacrylate is not a polymethacrylate.   
     
     
         2 . The method according to  claim 1 , wherein the hydrocarbon distillate comprises a weight content greater than or equal to 0.7% of n-paraffins, the carbon number of which is greater than 24. 
     
     
         3 . The method according to  claim 1 , wherein the distillate comprises a mixture of 0.7 to 2% by weight of n-paraffins having a carbon number ranging from C 24  to C 40 . 
     
     
         4 . The method according to  claim 1 , wherein the filterability additives are copolymers of ethylene containing more than 20% of ester units. 
     
     
         5 . The method according to  claim 1 , wherein the filterability additives are selected from copolymers of ethylene and of vinyl acetate, of ethylene and vinyl propionate, of ethylene and vinyl versatate, of ethylene and (alkyl)acrylates, of ethylene and (alkyl)methacrylates, taken alone or as a mixture, comprising from 20 to 40% by weight of ester units. 
     
     
         6 . The method according to  claim 1 , wherein said esters are of the vinyl acetate, vinyl propionate, vinyl versatate, (alkyl)acrylate and (alkyl)methacrylate type, the alkyl group containing 1 to 7 carbon atoms. 
     
     
         7 . The method according to  claim 1 , wherein the homopolymer is obtained by polymerization of an olefinic ester of acrylic acid, and of an alcohol comprising from 18 to 50 carbon atoms. 
     
     
         8 . The method according to  claim 1 , wherein the distillate is selected from the distillates with a boiling temperature comprised between 150 and 450° C. comprising the distillates from direct distillation, in vacuo distillates, hydrotreated distillates, distillates stemming from catalytic cracking and/or hydrocracking of distillates in vacuo, distillates resulting from ARDS type conversion and/or viscosity breaking methods, distillates stemming from valuation of Fisher Tropsch cuts, and distillates resulting from BTL conversion of vegetable and/or animal biomass, and distillates containing alkyl esters of vegetable or animal oils, taken alone or as a mixture. 
     
     
         9 . The method according to  claim 1 , wherein the polyacrylate has an average molecular weight Mw comprised between 10,000 and 19,000. 
     
     
         10 . The method according to  claim 1 , wherein the hydrocarbon distillate has an onset crystalization temperature as measured by differential scanning calorimetry analysis, greater than or equal to −1.2° C. 
     
     
         11 . A method of improving the activity of filterability additives, added to a hydrocarbon distillate, the method comprising:
 adding a polyacrylate to a hydrocarbon distillate containing filterability additives, the filterability additives being ethylene copolymers comprising from 20 to 40% by weight of ester units and selected from the group consisting of copolymers of ethylene and of vinyl acetate, copolymers of ethylene and vinyl propionate, copolymers of ethylene and vinyl versatate, copolymers of ethylene and (alkyl)acrylates, copolymers of ethylene and (alkyl)methacrylates, and mixtures thereof, the hydrocarbon distillate being resistant to the filterability additives,   wherein the polyacrylate comprises side hydrocarbon chains with 18-40 carbon atoms, and the hydrocarbon distillate has a boiling temperature comprised between 150 and 450° C., an onset crystallization temperature as measured by differential scanning calorimetry analysis, greater than or equal to −5° C., and a weight content of n-paraffins containing more than 18 carbon atoms greater than 4%,   wherein the polyacrylate cooperates synergistically with the filterability additives to increase the filterability of the hydrocarbon distillate, and   wherein the polyacrylate is not a polymethacrylate.   
     
     
         12 . A method of improving the activity of filterability additives, added to a hydrocarbon distillate, the method comprising:
 adding a polyacrylate to a hydrocarbon distillate containing filterability additives, the filterability additives comprising a copolymer and/or terpolymer of ethylene and of a vinyl ester of a carboxylic acid with 2 to 5 carbon atoms and of a monoalcohol comprising 1 to 10 carbon atoms, the hydrocarbon distillate being resistant to the filterability additives,   wherein the polyacrylate cooperates synergistically with the filterability additives to increase the filterability of the hydrocarbon distillate,   wherein the polyacrylate is not a polymethacrylate.   
     
     
         13 . The method according to  claim 12 , wherein the polyacrylate comprises side hydrocarbon chains with 18-40 carbon atoms, and the hydrocarbon distillate has a boiling temperature comprised between 150 and 450° C., an onset crystallization temperature as measured by differential scanning calorimetry analysis, greater than or equal to 5° C., and a weight content of n-paraffins containing more than 18 carbon atoms greater than 4%. 
     
     
         14 . The method according to  claim 12 , wherein the filterability additives are selected from copolymers of ethylene and of vinyl acetate, of ethylene and vinyl propionate, of ethylene and vinyl versatate, of ethylene and (alkyl)acrylates, of ethylene and (alkyl)methacrylates, taken alone or as a mixture, comprising from 20 to 40% by weight of ester units.