US2017044316A1PendingUtilityA1

Bifunctional Poly(alkyleneoxides) with Aminoalkyl and Unsaturated Termini and Derivatives Thereof

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Assignee: GELEST TECH INCPriority: Aug 10, 2015Filed: Jul 22, 2016Published: Feb 16, 2017
Est. expiryAug 10, 2035(~9.1 yrs left)· nominal 20-yr term from priority
Inventors:Barry C. ArklesJonathan D. GoffFerdinand Gonzaga
C08G 65/2621C08F 12/26C08G 77/14C08G 65/2639C08G 65/329C08F 12/22C08F 30/08C08G 77/46C08G 65/336C08G 65/2624C08G 65/337C08F 212/08C08F 212/14
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Claims

Abstract

A heterofunctional poly(alkyleneoxide) according to the invention contains a first polymer terminus containing a protected, unprotected, or derivatized amine or aminoalkyl functionality and a second polymer terminus containing an unsaturated functionality. Reaction products, derivatives, and methods of making these materials are also described.

Claims

exact text as granted — not AI-modified
We claim: 
     
         1 . A heterofunctional poly(alkyleneoxide) having first and second polymer termini, wherein the first polymer terminus comprises a protected, unprotected, or derivatized aminoalkyl functionality and the second polymer terminus comprises an unsaturated functionality. 
     
     
         2 . The poly(alkyleneoxide) according to  claim 1 , wherein the aminoalkyl functionality is a silylated amine functional group. 
     
     
         3 . The poly(alkyleneoxide) according to  claim 1 , wherein the alkyleneoxide is selected from an ethylene oxide, a propylene oxide, a butylene oxide, a hexafluoropropylene oxide, and a glycidyl ether of a silicone. 
     
     
         4 . The poly(alkyleneoxide) according to  claim 1 , comprising an α-amine or α-aminoalkyl terminus and an ω-allyl terminus. 
     
     
         5 . The poly(alkyleneoxide) according to  claim 4 , wherein the aminoalkyl terminus is a silylated amine functional group. 
     
     
         6 . The poly(alkyleneoxide) according to  claim 1 , comprising an α-amine or α-aminoalkyl terminus and an ω-vinylbenzyl terminus. 
     
     
         7 . The poly(alkyleneoxide) according to  claim 7 , wherein the aminoalkyl terminus is a silylated amine functional group. 
     
     
         8 . The poly(alkyleneoxide) according to  claim 1 , comprising an a N,N-bis(trimethylsilyl)amine terminus and an ω-allyl terminus. 
     
     
         9 . The poly(alkyleneoxide) according to  claim 1 , comprising an a N,N-bis(trimethylsilyl)amine terminus and an ω-vinylbenzyl terminus. 
     
     
         10 . A copolymer of the poly(alkyleneoxide) according to  claim 1  with an unsaturated monomer. 
     
     
         11 . A composition formed by the hydrosilylation of the poly(alkyleneoxide) according to  claim 1  with a siloxane. 
     
     
         12 . An amide reaction product of a composition according to  claim 11  with an acid chloride. 
     
     
         13 . A substituted urea product of a composition according to  claim 1  with an isocyanate. 
     
     
         14 . The reaction product according to  claim 12 , wherein the amide is an acrylamide, methacrylamide, or alkylamide functional macromer. 
     
     
         15 . A method of producing a heterofunctional poly(alkyleneoxide) according to  claim 1 , wherein the first polymer terminus comprises a protected aminoalkyl functionality, the method comprising polymerizing an alkylene oxide with a metal hexaalkyldisilazane to form a polymer and reacting the polymer with an unsaturated halide. 
     
     
         16 . A method of producing a heterofunctional poly(alkyleneoxide) according to  claim 1 , wherein the first polymer terminus comprises an unprotected aminoalkyl functionality, the method comprising polymerizing an alkylene oxide with a metal hexaalkyldisilazane to form a polymer, reacting the polymer with an unsaturated halide to yield a poly(alkyleneoxide) having a protected aminoalkyl terminus, and adding water or an alcohol to deblock the protecting group. 
     
     
         17 . A composition formed by the hydrosilylation of a poly(alkyleneoxide) according to  claim 1  with a silane. 
     
     
         18 . The poly(alkyleneoxide) according to  claim 1 , wherein the derivatized aminoalkyl functionality is an amide or N-substituted urea. 
     
     
         19 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is α-bis(trimethylsilylaminoethyl)-ω-allyl terminated polyethylene oxide. 
     
     
         20 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is α-bis(trimethylsilylaminoethyl)-ω-vinylbenzyl terminated polyethylene oxide. 
     
     
         21 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is α-aminoalkyl-ω-allyl terminated polyethylene oxide. 
     
     
         22 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is α-bis(trimethylsilylamino)-ω-vinylbenzyl terminated polyethylene oxide. 
     
     
         23 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is α-bis(trimethylsilylaminoalkyl)-ω-allyl terminated polyethylene oxide. 
     
     
         24 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is α-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentane) terminated polyethylene oxide. 
     
     
         25 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is bis(methylphenylvinylsilyl)-protected-α-amino-ω-allyl terminated polyethylene oxide. 
     
     
         26 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is α-amino-ω-allyl terminated polyethylene oxide. 
     
     
         27 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is bis(ethyldimethylsilyl)-protected-α-amino-ω-allyl terminated polyethylene oxide. 
     
     
         28 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is bis(trimethylsilyl)-protected-α-amino-ω-allyl terminated polyethylene oxide. 
     
     
         29 . The poly(alkyleneoxide) according to  claim 1 , wherein the poly(alkyleneoxide) is α-dodecanoylamide-ω-allyl terminated polyethylene oxide. 
     
     
         30 . The composition according to  claim 17 , wherein the composition is α-dodecanoylamide-ω-(triethoxysilyl)propyl terminated polyethylene oxide. 
     
     
         31 . The composition according to  claim 17 , wherein the composition is α-amino-ω-(triethoxysilyl)propyl-terminated polyethylene oxide. 
     
     
         32 . The composition according to  claim 11 , wherein the composition is 1-butyl-9-aminoethoxy(polyethyleneoxy)propyl decamethylpentasiloxane. 
     
     
         33 . The composition according to  claim 11 , wherein the composition is 1-butyl-n-methacrylamidoethoxy(polyethyleneoxy)propyl decamethylpentasiloxane.

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