Chemical and gas-resistant, high-pressure, large-bore bonded flexible rubber pipe and method for producing the same

Abstract

A high-pressure, large-bore bonded flexible rubber pipe resistant to aggressive chemicals and gases, particularly for conveying gas or oil, the flexible pipe having a liner made of poly(vinylidene-fluoride) homopolymer or copolymer wherein a hydrogenated nitrile rubber-based, peroxide-vulcanized rubber compound 2 is bonded to the poly(vinylidene-fluoride) liner, which has a Mooney 05, 150° C. scorch time of at least 10 minutes. Further, a method for manufacturing such hoses, the method including vulcanization performed at a temperature of at least 160° C.

1 . A high-pressure, large-bore bonded flexible rubber pipe resistant to aggressive chemicals and gases, particularly for conveying gas or crude oil, the flexible pipe comprising a liner made of poly(vinylidene-fluoride) homopolymer or copolymer, with at least 80 mole % of the monomeric units being vinylidene-fluoride and a hydrogenated nitrile rubber-based rubber compound vulcanized with peroxide, which has a Mooney 05, 150° C. scorch time of at least 10 minutes, bonded to the poly(vinylidene-fluoride) liner. 
     
     
         2 . The flexible rubber pipe according to  claim 1 , wherein the melting point of the PVDF liner is above 150° C. 
     
     
         3 . The flexible rubber pipe according to  claim 1 , wherein the hydrogenated nitrile rubber-based rubber compound is vulcanized with a peroxide having a half-life at 150° C. of at least 1 hour. 
     
     
         4 . The flexible rubber pipe according to  claim 3 , wherein the hydrogenated nitrile rubber-based rubber compound is vulcanized with either one of 2,5-dimethyl-2,5-di(t-butylperoxy)-3-hexyne,3,3,5,7,7-pentamethyl-1,2,4-trioxepane, di-tert-butyl peroxide, or a combination thereof. 
     
     
         5 . The flexible rubber pipe according to  claim 3 , wherein the hydrogenated nitrile rubber-based rubber compound is vulcanized with either one of cumene hydroperoxide, diisopropylbenzene hydroperoxide, t-butyl hydroperoxide, t-amyl hydroperoxide, or a combination thereof 
     
     
         6 . The flexible rubber pipe according to  claim 1 , wherein the peroxide applied for vulcanizing the hydrogenated nitrile rubber-based rubber compound is a so-called scorch-protected peroxide. 
     
     
         7 . The flexible rubber pipe according to  claim 6 , wherein the hydrogenated nitrile rubber-based rubber compound is vulcanized with peroxide scorch-protected di(tert-butylperoxy isopropyl)benzene. 
     
     
         8 . A method for manufacturing the flexible pipe according to  claim 1 , comprising vulcanizing at a temperature of at least 160° C. 
     
     
         9 . The method according to  claim 8  wherein the vulcanization temperature is selected such that it differs from the melting range of the poly(vinylidene-fluoride) liner by at most +/−10° C. 
     
     
         10 . The method according to  claim 9  wherein the vulcanization temperature is selected such that it differs from the melting range of the poly(vinylidene-fluoride) liner by at most +/−5° C. 
     
     
         11 . The flexible rubber pipe according to  claim 1  further comprising maximum 20 mole % of plasticizer.