US2017158624A1PendingUtilityA1
Pesticidal compositions and processes related thereto
Est. expiryDec 19, 2032(~6.4 yrs left)· nominal 20-yr term from priority
A61P 33/00A61P 43/00C07D 277/32A01N 43/54C07C 335/14C07C 275/14A01N 43/10C07D 331/04A01N 43/16C07D 307/16A01N 47/22A01N 43/653C07D 213/40C07C 233/59C07C 335/08C07D 237/32A01N 53/00C07D 295/192A01N 43/60C07C 243/38C07D 271/10A01N 37/28A01N 37/46A01N 47/00C07D 233/64C07D 309/14A01N 43/78C07C 233/64C07D 295/195C07D 213/61A01N 37/32C07D 401/12C07D 307/52A01N 43/50C07D 241/12A61K 31/175A01N 43/82C07D 207/16C07D 401/10A01N 47/32C07D 239/26C07C 211/29A01N 47/28C07C 233/66A01N 43/36C07C 63/74A01N 43/20A01N 37/10A61K 31/18C07C 337/06C07D 209/50A61K 31/17A01N 43/08A01N 37/18A01N 37/20C07C 233/65C07D 207/27A01N 43/38C07D 277/30A01N 47/34C07C 237/52A01N 37/34A01N 33/04A01N 43/40C07C 281/06C07D 211/58A01N 25/08A01N 43/58C07C 63/70C07D 249/08C07C 327/48C07D 277/64C07C 255/57C07D 307/14A01N 43/84
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Claims
Abstract
This document discloses molecules having the following formula (“Formula One”): and processes associated therewith.
Claims
exact text as granted — not AI-modifiedWe claim:
1 . A composition comprising a molecule according to Formula One:
wherein:
(a) R1 is selected from
(1) H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 )alkyl, has one or more substituents selected from CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 ;
(b) R2 is selected from
(1) H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 )alkyl, has one or more substituents selected from CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 ;
(c) R3 is selected from
(1) H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 )alkyl, has one or more substituents selected from CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 ;
(d) R4 is selected from
(1) H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 )alkyl, has one or more substituents selected from CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 ;
(e) R5 is selected from
(1) H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 )alkyl, has one or more substituents selected from CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from CN and NO 2 ;
(f) R6 is a (C 1 -C 8 )haloalkyl;
(g) R7 is selected from H, F, Cl, Br, I, OH, (C 1 -C 8 )alkoxy, and halo(C 1 -C 8 )alkoxy;
(h) R8 is selected from H, (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, OR14, and N(R14)(R15);
(i) R9 is selected from H, F, Cl, Br, I, (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, OR14, and N(R14)(R15);
(j) R10 is selected from
(1) H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, cyclo(C 3 -C 6 )alkyl, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), NR14R15, C(═O)H, C(═O)N(R14)(R15), CN(R14)(R15)(═NOH), (C═O)O(C 1 -C 8 )alkyl, (C═O)OH, heterocyclyl, (C 2 -C 8 )alkenyl, halo(C 2 -C 8 )alkenyl, (C 2 -C 8 )alkynyl,
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from OH, (C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(O)(C 1 -C 8 )alkyl, S(O) 2 (C 1 -C 8 )alkyl, NR14R15, and
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 )alkyl, has one or more substituents selected from (C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(O)(C 1 -C 8 )alkyl, S(O) 2 (C 1 -C 8 )alkyl, and N(R14)(R15);
(k) R11 is C(═X5)N(H)((C 0 -C 8 )alkyl)N(R11a)(C(═X5)N(H)(R11b))
wherein each X5 is independently selected from O or S, and
wherein each R11a is independently selected from H, (C 1 -C 8 )alkyl, substituted (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, substituted halo(C 1 -C 8 )alkyl, cyclo(C 3 -C 8 )alkyl, substituted cyclo(C 3 -C 8 )alkyl,
wherein each said substituted (C 1 -C 8 )alkyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , OC(═O)H, OH, S(C 1 -C 8 )alkyl, S(O)(C 1 -C 8 )alkyl, S(O) 2 (C 1 -C 8 )alkyl, OS(O) 2 aryl, N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), aryl, substituted aryl, heterocyclyl, substituted heterocyclyl, wherein each said substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo, wherein each said substituted heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), C(═O)(C 1 -C 8 )alkyl, C(═O)(C 3 -C 6 )cycloalkyl, S(═O) 2 (C 1 -C 8 )alkyl, NR14R15, and oxo, wherein each said substituted-aryl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo,
wherein said substituted halo(C 1 -C 8 )alkyl, has one or more substituents selected from CN and NO 2 ,
wherein said substituted cyclo(C 3 -C 8 )alkyl, has one or more substituents selected from CN and NO 2
wherein each R11b is independently selected from (C 1 -C 8 )alkyl, substituted (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, substituted halo(C 1 -C 8 )alkyl, cyclo(C 3 -C 8 )alkyl, substituted cyclo(C 3 -C 8 )alkyl,
wherein each said substituted (C 1 -C 8 )alkyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , OC(═O)H, OH, S(C 1 -C 8 )alkyl, S(O)(C 1 -C 8 )alkyl, S(O) 2 (C 1 -C 8 )alkyl, OS(O) 2 aryl, N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), aryl, substituted aryl, heterocyclyl, substituted heterocyclyl, wherein each said substituted aryl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo, wherein each said substituted heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), C(═O)(C 1 -C 8 )alkyl, C(═O)(C 3 -C 6 )cycloalkyl, S(═O) 2 (C 1 -C 8 )alkyl, NR14R15, and oxo, wherein each said substituted-aryl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo,
wherein said substituted halo(C 1 -C 8 )alkyl, has one or more substituents selected from CN and NO 2 ,
wherein said substituted cyclo(C 3 -C 8 )alkyl, has one or more substituents selected from CN and NO 2 ;
(l) R12 is selected from (v), H, F, Cl, Br, I, CN, (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, and cyclo(C 3 -C 6 )alkyl;
(m) R13 is selected from (v), H, F, Cl, Br, I, CN, (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, and halo(C 1 -C 8 )alkoxy;
(n) each R14 is independently selected from H, (C 1 -C 8 )alkyl, (C 2 -C 8 )alkenyl, substituted (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, substituted halo(C 1 -C 8 )alkyl), (C 1 -C 8 )alkoxy, cyclo(C 3 -C 6 )alkyl, aryl, substituted-aryl, (C 1 -C 8 )alkyl-aryl, (C 1 -C 8 )alkyl-(substituted-aryl), O—(C 1 -C 8 )alkyl-aryl, O—(C 1 -C 8 )alkyl-(substituted-aryl), heterocyclyl, substituted-heterocyclyl, (C 1 -C 8 )alkyl-heterocyclyl, (C 1 -C 8 )alkyl-(substituted-heterocyclyl), O—(C 1 -C 8 )alkyl-heterocyclyl, O—(C 1 -C 8 )alkyl-(substituted-heterocyclyl), N(R16)(R17), (C 1 -C 8 )alkyl-C(═O)N(R16)(R17), C(═O)(C 1 -C 8 )alkyl, C(═O)(halo(C 1 -C 8 )alkyl), C(═O)(C 3 -C 6 )cycloalkyl, (C 1 -C 8 )alkyl-C(═O)O(C 1 -C 8 )alkyl, C(═O)H
wherein each said substituted (C 1 -C 8 )alkyl has one or more substituents selected from CN, and NO 2 ,
wherein each said substituted halo(C 1 -C 8 )alkyl), has one or more substituents selected from CN, and NO 2 ,
wherein each said substituted-aryl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo, and
wherein each said substituted-heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, (C 3 -C 6 )cycloalkyl S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), heterocyclyl, C(═O)(C 1 -C 8 )alkyl, C(═O)O(C 1 -C 8 )alkyl, and oxo, (wherein said alkyl, alkoxy, and heterocyclyl, may be further substituted with one or more of F, Cl, Br, I, CN, and NO 2 );
(o) each R15 is independently selected from H, (C 1 -C 8 )alkyl, (C 2 -C 8 )alkenyl, substituted (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, substituted halo(C 1 -C 8 )alkyl), (C 1 -C 8 )alkoxy, cyclo(C 3 -C 6 )alkyl, aryl, substituted-aryl, (C 1 -C 8 )alkyl-aryl, (C 1 -C 8 )alkyl-(substituted-aryl), O—(C 1 -C 8 )alkyl-aryl, O—(C 1 -C 8 )alkyl-(substituted-aryl), heterocyclyl, substituted-heterocyclyl, (C 1 -C 8 )alkyl-heterocyclyl, (C 1 -C 8 )alkyl-(substituted-heterocyclyl), O—(C 1 -C 8 )alkyl-heterocyclyl, O—(C 1 -C 8 )alkyl-(substituted-heterocyclyl), N(R16)(R17), (C 1 -C 8 )alkyl-C(═O)N(R16)(R17), C(═O)(C 1 -C 8 )alkyl, C(═O)(halo(C 1 -C 8 )alkyl), C(═O)(C 3 -C 6 )cycloalkyl, (C 1 -C 8 )alkyl-C(═O)O(C 1 -C 8 )alkyl, C(═O)H
wherein each said substituted (C 1 -C 8 )alkyl has one or more substituents selected from CN, and NO 2 ,
wherein each said substituted halo(C 1 -C 8 )alkyl), has one or more substituents selected from CN, and NO 2 ,
wherein each said substituted-aryl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo, and
wherein each said substituted-heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, (C 3 -C 6 )cycloalkyl S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), heterocyclyl, C(═O)(C 1 -C 8 )alkyl, C(═O)O(C 1 -C 8 )alkyl, and oxo, (wherein said alkyl, alkoxy, and heterocyclyl, may be further substituted with one or more of F, Cl, Br, I, CN, and NO 2 );
(p) each R16 is independently selected from H, (C 1 -C 8 )alkyl, substituted-(C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, substituted-halo(C 1 -C 8 )alkyl, cyclo(C 3 -C 6 )alkyl, aryl, substituted-aryl, (C 1 -C 8 )alkyl-aryl, (C 1 -C 8 )alkyl-(substituted-aryl), O—(C 1 -C 8 )alkyl-aryl, O—(C 1 -C 8 )alkyl-(substituted-aryl), heterocyclyl, substituted-heterocyclyl, (C 1 -C 8 )alkyl-heterocyclyl, (C 1 -C 8 )alkyl-(substituted-heterocyclyl), O—(C 1 -C 8 )alkyl-heterocyclyl, O—(C 1 -C 8 )alkyl-(substituted-heterocyclyl), O—(C 1 -C 8 )alkyl
wherein each said substituted (C 1 -C 8 )alkyl has one or more substituents selected from CN, and NO 2 ,
wherein each said substituted halo(C 1 -C 8 )alkyl), has one or more substituents selected from CN, and NO 2 ,
wherein each said substituted-aryl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo, and
wherein each said substituted-heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo;
(q) each R17 is independently selected from H, (C 1 -C 8 )alkyl, substituted-(C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, substituted-halo(C 1 -C 8 )alkyl, cyclo(C 3 -C 6 )alkyl, aryl, substituted-aryl, (C 1 -C 8 )alkyl-aryl, (C 1 -C 8 )alkyl-(substituted-aryl), O—(C 1 -C 8 )alkyl-aryl, O—(C 1 -C 8 )alkyl-(substituted-aryl), heterocyclyl, substituted-heterocyclyl, (C 1 -C 8 )alkyl-heterocyclyl, (C 1 -C 8 )alkyl-(substituted-heterocyclyl), O—(C 1 -C 8 )alkyl-heterocyclyl, O—(C 1 -C 8 )alkyl-(substituted-heterocyclyl), O—(C 1 -C 8 )alkyl
wherein each said substituted (C 1 -C 8 )alkyl has one or more substituents selected from CN, and NO 2 ,
wherein each said substituted halo(C 1 -C 8 )alkyl), has one or more substituents selected from CN, and NO 2 ,
wherein each said substituted-aryl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo, and
wherein each said substituted-heterocyclyl has one or more substituents selected from F, Cl, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), N((C 1 -C 8 )alkyl) 2 (wherein each (C 1 -C 8 )alkyl is independently selected), and oxo;
(r) X1 is selected from N and CR12;
(s) X2 is selected from N, CR9, and CR13;
(t) X3 is selected from N and CR9; and
(v) R12 and R13 together form a linkage containing 3 to 4 atoms selected from C, N, O, and S, wherein said linkage connects back to the ring to form a 5 to 6 member saturated or unsaturated cyclic ring, wherein said linkage has at least one substituent X4 wherein X4 is selected from R14, N(R14)(R15), N(R14)(C(═O)R14), N(R14)(C(═S)R14), N(R14)(C(═O)N(R14)(R14)), N(R14)(C(═S)N(R14)(R14)), N(R14)(C(═O)N(R14)((C 2 -C 8 )alkenyl)), N(R14)(C(═S)N(R14)((C 2 -C 8 )alkenyl)), wherein each R14 is independently selected.
2 . A molecule according to claim 1 wherein R1 is selected from H, F, Cl, Br, I, CN, NO 2 , methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, methoxy, ethoxy, (C 3 )alkoxy, (C 4 )alkoxy, (C 5 )alkoxy, (C 6 )alkoxy, (C 7 )alkoxy, (C 8 )alkoxy, halomethoxy, haloethoxy, halo(C 3 )alkoxy, halo(C 4 )alkoxy, halo(C 5 )alkoxy, halo(C 6 )alkoxy, halo(C 7 )alkoxy, and halo(C 8 )alkoxy.
3 . A molecule according to claim 1 wherein R2 is selected from H, F, Cl, Br, I, CN, NO 2 , methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, methoxy, ethoxy, (C 3 )alkoxy, (C 4 )alkoxy, (C 5 )alkoxy, (C 6 )alkoxy, (C 7 )alkoxy, (C 8 )alkoxy, halomethoxy, haloethoxy, halo(C 3 )alkoxy, halo(C 4 )alkoxy, halo(C 5 )alkoxy, halo(C 6 )alkoxy, halo(C 7 )alkoxy, and halo(C 8 )alkoxy.
4 . A molecule according to claim 1 wherein R3 is selected from H, F, Cl, Br, I, CN, NO 2 , methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, methoxy, ethoxy, (C 3 )alkoxy, (C 4 )alkoxy, (C 5 )alkoxy, (C 6 )alkoxy, (C 7 )alkoxy, (C 8 )alkoxy, halomethoxy, haloethoxy, halo(C 3 )alkoxy, halo(C 4 )alkoxy, halo(C 5 )alkoxy, halo(C 6 )alkoxy, halo(C 7 )alkoxy, and halo(C 8 )alkoxy.
5 . A molecule according to claim 1 wherein R4 is selected from H, F, Cl, Br, I, CN, NO 2 , methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, methoxy, ethoxy, (C 3 )alkoxy, (C 4 )alkoxy, (C 5 )alkoxy, (C 6 )alkoxy, (C 7 )alkoxy, (C 8 )alkoxy, halomethoxy, haloethoxy, halo(C 3 )alkoxy, halo(C 4 )alkoxy, halo(C 5 )alkoxy, halo(C 6 )alkoxy, halo(C 7 )alkoxy, and halo(C 8 )alkoxy.
6 . A molecule according to claim 1 wherein R5 is selected from H, F, Cl, Br, I, CN, NO 2 , methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, methoxy, ethoxy, (C 3 )alkoxy, (C 4 )alkoxy, (C 5 )alkoxy, (C 6 )alkoxy, (C 7 )alkoxy, (C 8 )alkoxy, halomethoxy, haloethoxy, halo(C 3 )alkoxy, halo(C 4 )alkoxy, halo(C 5 )alkoxy, halo(C 6 )alkoxy, halo(C 7 )alkoxy, and halo(C 8 )alkoxy.
7 . A molecule according to claim 1 wherein R2 and R4 are selected from F, Cl, Br, I, CN, and NO 2 and R1, R3, and R5 are H.
8 . A molecule according to claim 1 wherein R2, R3, and R4 are selected from F, Cl, Br, I, CN, and NO 2 and R1, and R5 are H.
9 . A molecule according to claim 1 wherein R2, R3, and R4 are independently selected from F and Cl and R1 and R5 are H.
10 . A molecule according to claim 1 wherein R1 is selected from Cl and H.
11 . A molecule according to claim 1 wherein R2 is selected from CF 3 , CH 3 , Cl, F, and H.
12 . A molecule according to claim 1 wherein R3 is selected from OCH 3 , CH 3 , F, Cl, or H.
13 . A molecule according to claim 1 wherein R4 is selected from CF 3 , CH 3 , Cl, F, and H.
14 . A molecule according to claim 1 wherein R5 is selected from F, Cl, and H.
15 . A molecule according to claim 1 wherein R6 is selected from halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, and halo(C 8 )alkyl.
16 . A molecule according to claim 1 wherein R6 is trifluoromethyl.
17 . A molecule according to claim 1 wherein R7 is selected from H, F, Cl, Br, and I.
18 . A molecule according to claim 1 wherein R7 is selected from H, OCH 3 , and OH.
19 . A molecule according to claim 1 wherein R8 is selected from H, methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, and halo(C 8 )alkyl.
20 . A molecule according to claim 1 wherein R8 is selected from CH 3 and H.
21 . A molecule according to claim 1 wherein R9 is selected from H, F, Cl, Br, I, methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, methoxy, ethoxy, (C 3 )alkoxy, (C 4 )alkoxy, (C 5 )alkoxy, (C 6 )alkoxy, (C 7 )alkoxy, (C 8 )alkoxy, halomethoxy, haloethoxy, halo(C 3 )alkoxy, halo(C 4 )alkoxy, halo(C 5 )alkoxy, halo(C 6 )alkoxy, halo(C 7 )alkoxy, and halo(C 8 )alkoxy.
22 . A molecule according to claim 1 wherein R10 is selected from H, F, Cl, Br, I, CN, methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, methoxy, ethoxy, (C 3 )alkoxy, (C 4 )alkoxy, (C 5 )alkoxy, (C 6 )alkoxy, (C 7 )alkoxy, (C 8 )alkoxy, halomethoxy, haloethoxy, halo(C 3 )alkoxy, halo(C 4 )alkoxy, halo(C 5 )alkoxy, halo(C 6 )alkoxy, halo(C 7 )alkoxy, halo(C 8 )alkoxy, cyclopropyl, cyclobutyl, cyclopentyl, and cyclohexyl.
23 . A molecule according to claim 1 wherein R10 is selected from H, Cl, Br, CH 3 , and CF 3 .
24 . A molecule according to claim 1 wherein R10 is selected from Br, C(═NOH)NH 2 , C(═O)H, C(═O)NH 2 , C(═O)OCH 2 CH 3 , C(═O)OH, CF 3 , CH 2 CH 3 , CH 2 OH, CH3, Cl, CN, F, H, NH 2 , NHC(═O)H, NHCH 3 , NO 2 , OCH 3 , OCHF 2 , and pyridyl.
25 . A molecule according to claim 1 wherein R11 is selected from C(═O)N(H)N(CH 3 )(C(═O)N(H)(CH 2 CH 3 )), or C(═O)N(H)N(CH 3 )(C(═O)N(H)(CH 2 CF 3 )).
26 . A molecule according to claim 1 wherein R11 is selected from C(═O)N(H)N(CH 3 )(C(═S)N(H)(CH 2 CH 3 )), or C(═O)N(H)N(CH 3 )(C(═S)N(H)(CH 2 CF 3 )).
27 . A molecule according to claim 1 wherein R11 is selected from C(═O)N(H)CH 2 CH 2 N(CH 3 )(C(═O)N(H)(CH 2 CH 3 )), or C(═O)N(H) CH 2 CH 2 N(CH 3 )(C(═S)N(H)(CH 2 CF 3 )).
28 . A molecule according to claim 1 wherein R11 is selected from C(═O)N(H)N(CH 3 )(C(═O)N(H)(CH 2 CH 3 )), C(═O)N(H)N(CH 3 )(C(═O)N(H)(CH 2 CF 3 )), C(═O)N(H)N(CH 3 )(C(═S)N(H)(CH 2 CH 3 )), C(═O)N(H)N(CH 3 )(C(═S)N(H)(CH 2 CF 3 )), C(═O)N(H)CH 2 CH 2 N(CH 3 )(C(═O)N(H)(CH 2 CH 3 )), or C(═O)N(H) CH 2 CH 2 N(CH 3 )(C(═S)N(H)(CH 2 CF 3 )).
29 . A molecule according to claim 1 wherein R12 is selected from H, F, Cl, Br, I, methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, halomethoxy, haloethoxy, halo(C 3 )alkoxy, halo(C 4 )alkoxy, halo(C 5 )alkoxy, halo(C 6 )alkoxy, halo(C 7 )alkoxy, and halo(C 8 )alkoxy.
30 . A molecule according to claim 1 wherein R12 is selected from CH 3 and H.
31 . A molecule according to claim 1 wherein R13 is selected from H, F, Cl, Br, I, methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, halomethoxy, haloethoxy, halo(C 3 )alkoxy, halo(C 4 )alkoxy, halo(C 5 )alkoxy, halo(C 6 )alkoxy, halo(C 7 )alkoxy, and halo(C 8 )alkoxy.
32 . A molecule according to claim 1 wherein R13 is selected from CH 3 , Cl, and H.
33 . A molecule according to claim 1 wherein R12-R13 is the hydrocarbyl linkage CH═CHCH═CH.
34 . A molecule according to claim 1 wherein R14 and R15 are independently selected from H, methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, methyl-aryl, ethyl-aryl, (C 3 )alkyl-aryl, (C 4 )alkyl-aryl, (C 5 )alkyl-aryl, (C 6 )alkyl-aryl, (C 7 )alkyl-aryl, (C 8 )alkyl-aryl, methyl-(substituted-aryl), ethyl-(substituted-aryl), (C 3 )alkyl-(substituted-aryl), (C 4 )alkyl-(substituted-aryl), (C 5 )alkyl-(substituted-aryl), (C 6 )alkyl-(substituted-aryl), (C 7 )alkyl-(substituted-aryl), (C 8 )alkyl-(substituted-aryl), O-methyl-aryl, O-ethyl-aryl, O—(C 3 )alkyl-aryl, O—(C 4 )alkyl-aryl, O—(C 5 )alkyl-aryl, O—(C 6 )alkyl-aryl, O—(C 7 )alkyl-aryl, O—(C 8 )alkyl-aryl, O-methyl-(substituted-aryl), O-ethyl-(substituted-aryl), O—(C 3 )alkyl-(substituted-aryl), O—(C 4 )alkyl-(substituted-aryl), O—(C 5 )alkyl-(substituted-aryl), O—(C 6 )alkyl-(substituted-aryl), O—(C 7 )alkyl-(substituted-aryl), O—(C 8 )alkyl-(substituted-aryl), methyl-heterocyclyl, ethyl-heterocyclyl, (C 3 )alkyl-heterocyclyl, (C 4 )alkyl-heterocyclyl, (C 5 )alkyl-heterocyclyl, (C 6 )alkyl-heterocyclyl, (C 7 )alkyl-heterocyclyl, (C 8 )alkyl-heterocyclyl, methyl-(substituted-heterocyclyl), ethyl-(substituted-heterocyclyl), (C 3 )alkyl-(substituted-heterocyclyl), (C 4 )alkyl-(substituted-heterocyclyl), (C 5 )alkyl-(substituted-heterocyclyl), (C 6 )alkyl-(substituted-heterocyclyl), (C 7 )alkyl-(substituted-heterocyclyl), (C 8 )alkyl-(substituted-heterocyclyl), O-methyl-heterocyclyl, O-ethyl-heterocyclyl, O—(C 3 )alkyl-heterocyclyl, O—(C 4 )alkyl-heterocyclyl, O—(C 5 )alkyl-heterocyclyl, O—(C 6 )alkyl-heterocyclyl, O—(C 7 )alkyl-heterocyclyl, O—(C 8 )alkyl-heterocyclyl, O-methyl-(substituted-heterocyclyl), O-ethyl-(substituted-heterocyclyl), O—(C 3 )alkyl-(substituted-heterocyclyl), O—(C 4 )alkyl-(substituted-heterocyclyl), O—(C 5 )alkyl-(substituted-heterocyclyl), O—(C 6 )alkyl-(substituted-heterocyclyl), O—(C 7 )alkyl-(substituted-heterocyclyl), O—(C 8 )alkyl-(substituted-heterocyclyl), methyl-C(═O)N(R16)(R17), ethyl-C(═O)N(R16)(R17), (C 3 )alkyl-C(═O)N(R16)(R17), (C 4 )alkyl-C(═O)N(R16)(R17), (C 5 )alkyl-C(═O)N(R16)(R17), (C 6 )alkyl-C(═O)N(R16)(R17), (C 7 )alkyl-C(═O)N(R16)(R17), and (C 8 )alkyl-C(═O)N(R16)(R17).
35 . A molecule according to claim 1 wherein R14 and R15 are independently selected from H, CH 3 , CH 2 CF 3 , CH 2 -halopyridyl, oxo-pyrrolidinyl, halophenyl, thietanyl, CH 2 -phenyl, CH 2 -pyridyl, thietanyl-dioxide, CH 2 -halothiazolyl, C((CH 3 ) 2 )-pyridyl, N(H)(halophenyl), CH 2 -pyrimidinyl, CH 2 -tetrahydrofuranyl, CH 2 -furanyl, O—CH 2 -halopyridyl, and CH 2 C(═O)N(H)(CH 2 CF 3 ).
36 . A molecule according to claim 1 wherein R16 and R17 are independently selected from H, methyl, ethyl, (C 3 )alkyl, (C 4 )alkyl, (C 5 )alkyl, (C 6 )alkyl, (C 7 )alkyl, (C 8 )alkyl, halomethyl, haloethyl, halo(C 3 )alkyl, halo(C 4 )alkyl, halo(C 5 )alkyl, halo(C 6 )alkyl, halo(C 7 )alkyl, halo(C 8 )alkyl, methyl-aryl, ethyl-aryl, (C 3 )alkyl-aryl, (C 4 )alkyl-aryl, (C 5 )alkyl-aryl, (C 6 )alkyl-aryl, (C 7 )alkyl-aryl, (C 8 )alkyl-aryl, methyl-(substituted-aryl), ethyl-(substituted-aryl), (C 3 )alkyl-(substituted-aryl), (C 4 )alkyl-(substituted-aryl), (C 5 )alkyl-(substituted-aryl), (C 6 )alkyl-(substituted-aryl), (C 7 )alkyl-(substituted-aryl), (C 8 )alkyl-(substituted-aryl), O-methyl-aryl, O-ethyl-aryl, O—(C 3 )alkyl-aryl, O—(C 4 )alkyl-aryl, O—(C 5 )alkyl-aryl, O—(C 6 )alkyl-aryl, O—(C 7 )alkyl-aryl, O—(C 8 )alkyl-aryl, O-methyl-(substituted-aryl), O-ethyl-(substituted-aryl), O—(C 3 )alkyl-(substituted-aryl), O—(C 4 )alkyl-(substituted-aryl), O—(C 5 )alkyl-(substituted-aryl), O—(C 6 )alkyl-(substituted-aryl), O—(C 7 )alkyl-(substituted-aryl), O—(C 8 )alkyl-(substituted-aryl), methyl-heterocyclyl, ethyl-heterocyclyl, (C 3 )alkyl-heterocyclyl, (C 4 )alkyl-heterocyclyl, (C 5 )alkyl-heterocyclyl, (C 6 )alkyl-heterocyclyl, (C 7 )alkyl-heterocyclyl, (C 8 )alkyl-heterocyclyl, methyl-(substituted-heterocyclyl), ethyl-(substituted-heterocyclyl), (C 3 )alkyl-(substituted-heterocyclyl), (C 4 )alkyl-(substituted-heterocyclyl), (C 5 )alkyl-(substituted-heterocyclyl), (C 6 )alkyl-(substituted-heterocyclyl), (C 7 )alkyl-(substituted-heterocyclyl), (C 8 )alkyl-(substituted-heterocyclyl), O-methyl-heterocyclyl, O-ethyl-heterocyclyl, O—(C 3 )alkyl-heterocyclyl, O—(C 4 )alkyl-heterocyclyl, O—(C 5 )alkyl-heterocyclyl, O—(C 6 )alkyl-heterocyclyl, O—(C 7 )alkyl-heterocyclyl, O—(C 8 )alkyl-heterocyclyl, O-methyl-(substituted-heterocyclyl), O-ethyl-(substituted-heterocyclyl), O—(C 3 )alkyl-(substituted-heterocyclyl), O—(C 4 )alkyl-(substituted-heterocyclyl), O—(C 5 )alkyl-(substituted-heterocyclyl), O—(C 6 )alkyl-(substituted-heterocyclyl), O—(C 7 )alkyl-(substituted-heterocyclyl), and O—(C 8 )alkyl-(substituted-heterocyclyl).
37 . A molecule according to claim 1 wherein R16 and R17 are independently selected from H, CH 2 CF 3 , cyclopropyl, thietanyl, thietanyl dioxide, and halophenyl.
38 . A molecule according to claim 1 wherein X1 is CR12, X2 is CR13, and X3 is CR9.
39 . A molecule according to claim 1 wherein said molecule is one of the following
Compound
Number
Structure
F1
F2
F3
F4
F5
F6
F7
F8
F9
F10
F11
F12
F13
F14
F15
F16
F17
F18
F19
F20
F21
F22
F23
F24
F25
F26
F27
F28
F29
F30
F31
F32
F33
F34
F35
F36
F37
F38
F39
F40
40 . A molecule according to claim 1 wherein said molecule is one of the following
41 . A composition according to claim 1 further comprising:
(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or
(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or
(c) both (a) and (b).
42 . A composition according to claim 1 wherein further comprising one or more compounds selected from: (3-ethoxypropyl)mercury bromide, 1,2-dichloropropane, 1,3-dichloropropene, 1-methylcyclopropene, 1-naphthol, 2-(octylthio)ethanol, 2,3,5-tri-iodobenzoic acid, 2,3,6-TBA, 2,3,6-TBA-dimethylammonium, 2,3,6-TBA-lithium, 2,3,6-TBA-potassium, 2,3,6-TBA-sodium, 2,4,5-T, 2,4,5-T-2-butoxypropyl, 2,4,5-T-2-ethylhexyl, 2,4,5-T-3-butoxypropyl, 2,4,5-TB, 2,4,5-T-butometyl, 2,4,5-T-butotyl, 2,4,5-T-butyl, 2,4,5-T-isobutyl, 2,4,5-T-isoctyl, 2,4,5-T-isopropyl, 2,4,5-T-methyl, 2,4,5-T-pentyl, 2,4,5-T-sodium, 2,4,5-T-triethylammonium, 2,4,5-T-trolamine, 2,4-D, 2,4-D-2-butoxypropyl, 2,4-D-2-ethylhexyl, 2,4-D-3-butoxypropyl, 2,4-D-ammonium, 2,4-DB, 2,4-DB-butyl, 2,4-DB-dimethylammonium, 2,4-DB-isoctyl, 2,4-DB-potassium, 2,4-DB-sodium, 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-diethylammonium, 2,4-D-dimethylammonium, 2,4-D-diolamine, 2,4-D-dodecylammonium, 2,4-DEB, 2,4-DEP, 2,4-D-ethyl, 2,4-D-heptylammonium, 2,4-D-isobutyl, 2,4-D-isoctyl, 2,4-D-isopropyl, 2,4-D-isopropylammonium, 2,4-D-lithium, 2,4-D-meptyl, 2,4-D-methyl, 2,4-D-octyl, 2,4-D-pentyl, 2,4-D-potassium, 2,4-D-propyl, 2,4-D-sodium, 2,4-D-tefuryl, 2,4-D-tetradecylammonium, 2,4-D-triethylammonium, 2,4-D-tris(2-hydroxypropyl)ammonium, 2,4-D-trolamine, 2iP, 2-methoxyethylmercury chloride, 2-phenylphenol, 3,4-DA, 3,4-DB, 3,4-DP, 4-aminopyridine, 4-CPA, 4-CPA-potassium, 4-CPA-sodium, 4-CPB, 4-CPP, 4-hydroxyphenethyl alcohol, 8-hydroxyquinoline sulfate, 8-phenylmercurioxyquinoline, abamectin, abscisic acid, ACC, acephate, acequinocyl, acetamiprid, acethion, acetochlor, acetophos, acetoprole, acibenzolar, acibenzolar-S-methyl, acifluorfen, acifluorfen-methyl, acifluorfen-sodium, aclonifen, acrep, acrinathrin, acrolein, acrylonitrile, acypetacs, acypetacs-copper, acypetacs-zinc, alachlor, alanycarb, albendazole, aldicarb, aldimorph, aldoxycarb, aldrin, allethrin, allicin, allidochlor, allosamidin, alloxydim, alloxydim-sodium, allyl alcohol, allyxycarb, alorac, alpha-cypermethrin, alpha-endosulfan, ametoctradin, ametridione, ametryn, amibuzin, amicarbazone, amicarthiazol, amidithion, amidoflumet, amidosulfuron, aminocarb, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachlor-potassium, aminopyralid, aminopyralid-potassium, aminopyralid-tris(2-hydroxypropyl)ammonium, amiprofos-methyl, amiprophos, amisulbrom, amiton, amiton oxalate, amitraz, amitrole, ammonium sulfamate, ammonium α-naphthaleneacetate, amobam, ampropylfos, anabasine, ancymidol, anilazine, anilofos, anisuron, anthraquinone, antu, apholate, aramite, arsenous oxide, asomate, aspirin, asulam, asulam-potassium, asulam-sodium, athidathion, atraton, atrazine, aureofungin, aviglycine, aviglycine hydrochloride, azaconazole, azadirachtin, azafenidin, azamethiphos, azimsulfuron, azinphos-ethyl, azinphos-methyl, aziprotryne, azithiram, azobenzene, azocyclotin, azothoate, azoxystrobin, bachmedesh, barban, barium hexafluorosilicate, barium polysulfide, barthrin, BCPC, beflubutamid, benalaxyl, benalaxyl-M, benazolin, benazolin-dimethylammonium, benazolin-ethyl, benazolin-potassium, bencarbazone, benclothiaz, bendiocarb, benfluralin, benfuracarb, benfuresate, benodanil, benomyl, benoxacor, benoxafos, benquinox, bensulfuron, bensulfuron-methyl, bensulide, bensultap, bentaluron, bentazone, bentazone-sodium, benthiavalicarb, benthiavalicarb-isopropyl, benthiazole, bentranil, benzadox, benzadox-ammonium, benzalkonium chloride, benzamacril, benzamacril-isobutyl, benzamorf, benzfendizone, benzipram, benzobicyclon, benzofenap, benzofluor, benzohydroxamic acid, benzoximate, benzoylprop, benzoylprop-ethyl, benzthiazuron, benzyl benzoate, benzyladenine, berberine, berberine chloride, beta-cyfluthrin, beta-cypermethrin, bethoxazin, bicyclopyrone, bifenazate, bifenox, bifenthrin, bifujunzhi, bilanafos, bilanafos-sodium, binapacryl, bingqingxiao, bioallethrin, bioethanomethrin, biopermethrin, bioresmethrin, biphenyl, bisazir, bismerthiazol, bispyribac, bispyribac-sodium, bistrifluron, bitertanol, bithionol, bixafen, blasticidin-S, borax, Bordeaux mixture, boric acid, boscalid, brassinolide, brassinolide-ethyl, brevicomin, brodifacoum, brofenvalerate, brofluthrinate, bromacil, bromacil-lithium, bromacil-sodium, bromadiolone, bromethalin, bromethrin, bromfenvinfos, bromoacetamide, bromobonil, bromobutide, bromocyclen, bromo-DDT, bromofenoxim, bromophos, bromophos-ethyl, bromopropylate, bromothalonil, bromoxynil, bromoxynil butyrate, bromoxynil heptanoate, bromoxynil octanoate, bromoxynil-potassium, brompyrazon, bromuconazole, bronopol, bucarpolate, bufencarb, buminafos, bupirimate, buprofezin, Burgundy mixture, busulfan, butacarb, butachlor, butafenacil, butamifos, butathiofos, butenachlor, butethrin, buthidazole, buthiobate, buthiuron, butocarboxim, butonate, butopyronoxyl, butoxycarboxim, butralin, butroxydim, buturon, butylamine, butylate, cacodylic acid, cadusafos, cafenstrole, calcium arsenate, calcium chlorate, calcium cyanamide, calcium polysulfide, calvinphos, cambendichlor, camphechlor, camphor, captafol, captan, carbamorph, carbanolate, carbaryl, carbasulam, carbendazim, carbendazim benzenesulfonate, carbendazim sulfite, carbetamide, carbofuran, carbon disulfide, carbon tetrachloride, carbophenothion, carbosulfan, carboxazole, carboxide, carboxin, carfentrazone, carfentrazone-ethyl, carpropamid, cartap, cartap hydrochloride, carvacrol, carvone, CDEA, cellocidin, CEPC, ceralure, Cheshunt mixture, chinomethionat, chitosan, chlobenthiazone, chlomethoxyfen, chloralose, chloramben, chloramben-ammonium, chloramben-diolamine, chloramben-methyl, chloramben-methylammonium, chloramben-sodium, chloramine phosphorus, chloramphenicol, chloraniformethan, chloranil, chloranocryl, chlorantraniliprole, chlorazifop, chlorazifop-propargyl, chlorazine, chlorbenside, chlorbenzuron, chlorbicyclen, chlorbromuron, chlorbufam, chlordane, chlordecone, chlordimeform, chlordimeform hydrochloride, chlorempenthrin, chlorethoxyfos, chloreturon, chlorfenac, chlorfenac-ammonium, chlorfenac-sodium, chlorfenapyr, chlorfenazole, chlorfenethol, chlorfenprop, chlorfenson, chlorfensulphide, chlorfenvinphos, chlorfluazuron, chlorflurazole, chlorfluren, chlorfluren-methyl, chlorflurenol, chlorflurenol-methyl, chloridazon, chlorimuron, chlorimuron-ethyl, chlormephos, chlormequat, chlormequat chloride, chlornidine, chlornitrofen, chlorobenzilate, chlorodinitronaphthalenes, chloroform, chloromebuform, chloromethiuron, chloroneb, chlorophacinone, chlorophacinone-sodium, chloropicrin, chloropon, chloropropylate, chlorothalonil, chlorotoluron, chloroxuron, chloroxynil, chlorphonium, chlorphonium chloride, chlorphoxim, chlorprazophos, chlorprocarb, chlorpropham, chlorpyrifos, chlorpyrifos-methyl, chlorquinox, chlorsulfuron, chlorthal, chlorthal-dimethyl, chlorthal-monomethyl, chlorthiamid, chlorthiophos, chlozolinate, choline chloride, chromafenozide, cinerin I, cinerin II, cinerins, cinidon-ethyl, cinmethylin, cinosulfuron, ciobutide, cisanilide, cismethrin, clethodim, climbazole, cliodinate, clodinafop, clodinafop-propargyl, cloethocarb, clofencet, clofencet-potassium, clofentezine, clofibric acid, clofop, clofop-isobutyl, clomazone, clomeprop, cloprop, cloproxydim, clopyralid, clopyralid-methyl, clopyralid-olamine, clopyralid-potassium, clopyralid-tris(2-hydroxypropyl)ammonium, cloquintocet, cloquintocet-mexyl, cloransulam, cloransulam-methyl, closantel, clothianidin, clotrimazole, cloxyfonac, cloxyfonac-sodium, CMA, codlelure, colophonate, copper acetate, copper acetoarsenite, copper arsenate, copper carbonate, basic, copper hydroxide, copper naphthenate, copper oleate, copper oxychloride, copper silicate, copper sulfate, copper zinc chromate, coumachlor, coumafuryl, coumaphos, coumatetralyl, coumithoate, coumoxystrobin, CPMC, CPMF, CPPC, credazine, cresol, crimidine, crotamiton, crotoxyphos, crufomate, cryolite, cue-lure, cufraneb, cumyluron, cuprobam, cuprous oxide, curcumenol, cyanamide, cyanatryn, cyanazine, cyanofenphos, cyanophos, cyanthoate, cyantraniliprole, cyazofamid, cybutryne, cyclafuramid, cyclanilide, cyclethrin, cycloate, cycloheximide, cycloprate, cycloprothrin, cyclosulfamuron, cycloxaprid, cycloxydim, cycluron, cyenopyrafen, cyflufenamid, cyflumetofen, cyfluthrin, cyhalofop, cyhalofop-butyl, cyhalothrin, cyhexatin, cymiazole, cymiazole hydrochloride, cymoxanil, cyometrinil, cypendazole, cypermethrin, cyperquat, cyperquat chloride, cyphenothrin, cyprazine, cyprazole, cyproconazole, cyprodinil, cyprofuram, cypromid, cyprosulfamide, cyromazine, cythioate, daimuron, dalapon, dalapon-calcium, dalapon-magnesium, dalapon-sodium, daminozide, dayoutong, dazomet, dazomet-sodium, DBCP, d-camphor, DCIP, DCPTA, DDT, debacarb, decafentin, decarbofuran, dehydroacetic acid, delachlor, deltamethrin, demephion, demephion-O, demephion-S, demeton, demeton-methyl, demeton-O, demeton-O-methyl, demeton-S, demeton-S-methyl, demeton-S-methylsulphon, desmedipham, desmetryn, d-fanshiluquebingjuzhi, diafenthiuron, dialifos, di-allate, diamidafos, diatomaceous earth, diazinon, dibutyl phthalate, dibutyl succinate, dicamba, dicamba-diglycolamine, dicamba-dimethylammonium, dicamba-diolamine, dicamba-isopropylammonium, dicamba-methyl, dicamba-olamine, dicamba-potassium, dicamba-sodium, dicamba-trolamine, dicapthon, dichlobenil, dichlofenthion, dichlofluanid, dichlone, dichloralurea, dichlorbenzuron, dichlorflurenol, dichlorflurenol-methyl, dichlormate, dichlormid, dichlorophen, dichlorprop, dichlorprop-2-ethylhexyl, dichlorprop-butotyl, dichlorprop-dimethylammonium, dichlorprop-ethylammonium, dichlorprop-isoctyl, dichlorprop-methyl, dichlorprop-P, dichlorprop-P-2-ethylhexyl, dichlorprop-P-dimethylammonium, dichlorprop-potassium, dichlorprop-sodium, dichlorvos, dichlozoline, diclobutrazol, diclocymet, diclofop, diclofop-methyl, diclomezine, diclomezine-sodium, dicloran, diclosulam, dicofol, dicoumarol, dicresyl, dicrotophos, dicyclanil, dicyclonon, dieldrin, dienochlor, diethamquat, diethamquat dichloride, diethatyl, diethatyl-ethyl, diethofencarb, dietholate, diethyl pyrocarbonate, diethyltoluamide, difenacoum, difenoconazole, difenopenten, difenopenten-ethyl, difenoxuron, difenzoquat, difenzoquat metilsulfate, difethialone, diflovidazin, diflubenzuron, diflufenican, diflufenzopyr, diflufenzopyr-sodium, diflumetorim, dikegulac, dikegulac-sodium, dilor, dimatif, dimefluthrin, dimefox, dimefuron, dimepiperate, dimetachlone, dimetan, dimethacarb, dimethachlor, dimethametryn, dimethenamid, dimethenamid-P, dimethipin, dimethirimol, dimethoate, dimethomorph, dimethrin, dimethyl carbate, dimethyl phthalate, dimethylvinphos, dimetilan, dimexano, dimidazon, dimoxystrobin, dinex, dinex-diclexine, dingjunezuo, diniconazole, diniconazole-M, dinitramine, dinobuton, dinocap, dinocap-4, dinocap-6, dinocton, dinofenate, dinopenton, dinoprop, dinosam, dinoseb, dinoseb acetate, dinoseb-ammonium, dinoseb-diolamine, dinoseb-sodium, dinoseb-trolamine, dinosulfon, dinotefuran, dinoterb, dinoterb acetate, dinoterbon, diofenolan, dioxabenzofos, dioxacarb, dioxathion, diphacinone, diphacinone-sodium, diphenamid, diphenyl sulfone, diphenylamine, dipropalin, dipropetryn, dipyrithione, diquat, diquat dibromide, disparlure, disul, disulfiram, disulfoton, disul-sodium, ditalimfos, dithianon, dithicrofos, dithioether, dithiopyr, diuron, d-limonene, DMPA, DNOC, DNOC-ammonium, DNOC-potassium, DNOC-sodium, dodemorph, dodemorph acetate, dodemorph benzoate, dodicin, dodicin hydrochloride, dodicin-sodium, dodine, dofenapyn, dominicalure, doramectin, drazoxolon, DSMA, dufulin, EBEP, EBP, ecdysterone, edifenphos, eglinazine, eglinazine-ethyl, emamectin, emamectin benzoate, EMPC, empenthrin, endosulfan, endothal, endothal-diammonium, endothal-dipotassium, endothal-disodium, endothion, endrin, enestroburin, EPN, epocholeone, epofenonane, epoxiconazole, eprinomectin, epronaz, EPTC, erbon, ergocalciferol, erlujixiancaoan, esdepallethrine, esfenvalerate, esprocarb, etacelasil, etaconazole, etaphos, etem, ethaboxam, ethachlor, ethalfluralin, ethametsulfuron, ethametsulfuron-methyl, ethaprochlor, ethephon, ethidimuron, ethiofencarb, ethiolate, ethion, ethiozin, ethiprole, ethirimol, ethoate-methyl, ethofumesate, ethohexadiol, ethoprophos, ethoxyfen, ethoxyfen-ethyl, ethoxyquin, ethoxysulfuron, ethychlozate, ethyl formate, ethyl α-naphthaleneacetate, ethyl-DDD, ethylene, ethylene dibromide, ethylene dichloride, ethylene oxide, ethylicin, ethylmercury 2,3-dihydroxypropyl mercaptide, ethylmercury acetate, ethylmercury bromide, ethylmercury chloride, ethylmercury phosphate, etinofen, etnipromid, etobenzanid, etofenprox, etoxazole, etridiazole, etrimfos, eugenol, EXD, famoxadone, famphur, fenamidone, fenaminosulf, fenamiphos, fenapanil, fenarimol, fenasulam, fenazaflor, fenazaquin, fenbuconazole, fenbutatin oxide, fenchlorazole, fenchlorazole-ethyl, fenchlorphos, fenclorim, fenethacarb, fenfluthrin, fenfuram, fenhexamid, fenitropan, fenitrothion, fenjuntong, fenobucarb, fenoprop, fenoprop-3-butoxypropyl, fenoprop-butometyl, fenoprop-butotyl, fenoprop-butyl, fenoprop-isoctyl, fenoprop-methyl, fenoprop-potassium, fenothiocarb, fenoxacrim, fenoxanil, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-P, fenoxaprop-P-ethyl, fenoxasulfone, fenoxycarb, fenpiclonil, fenpirithrin, fenpropathrin, fenpropidin, fenpropimorph, fenpyrazamine, fenpyroximate, fenridazon, fenridazon-potassium, fenridazon-propyl, fenson, fensulfothion, fenteracol, fenthiaprop, fenthiaprop-ethyl, fenthion, fenthion-ethyl, fentin, fentin acetate, fentin chloride, fentin hydroxide, fentrazamide, fentrifanil, fenuron, fenuron TCA, fenvalerate, ferbam, ferimzone, ferrous sulfate, fipronil, flamprop, flamprop-isopropyl, flamprop-M, flamprop-methyl, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, flocoumafen, flometoquin, flonicamid, florasulam, fluacrypyrim, fluazifop, fluazifop-butyl, fluazifop-methyl, fluazifop-P, fluazifop-P-butyl, fluazinam, fluazolate, fluazuron, flubendiamide, flubenzimine, flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloralin, flucofuron, flucycloxuron, flucythrinate, fludioxonil, fluenetil, fluensulfone, flufenacet, flufenerim, flufenican, flufenoxuron, flufenprox, flufenpyr, flufenpyr-ethyl, flufiprole, flumethrin, flumetover, flumetralin, flumetsulam, flumezin, flumiclorac, flumiclorac-pentyl, flumioxazin, flumipropyn, flumorph, fluometuron, fluopicolide, fluopyram, fluorbenside, fluoridamid, fluoroacetamide, fluorodifen, fluoroglycofen, fluoroglycofen-ethyl, fluoroimide, fluoromidine, fluoronitrofen, fluothiuron, fluotrimazole, fluoxastrobin, flupoxam, flupropacil, flupropadine, flupropanate, flupropanate-sodium, flupyradifurone, flupyrsulfuron, flupyrsulfuron-methyl, flupyrsulfuron-methyl-sodium, fluquinconazole, flurazole, flurenol, flurenol-butyl, flurenol-methyl, fluridone, flurochloridone, fluroxypyr, fluroxypyr-butometyl, fluroxypyr-meptyl, flurprimidol, flursulamid, flurtamone, flusilazole, flusulfamide, fluthiacet, fluthiacet-methyl, flutianil, flutolanil, flutriafol, fluvalinate, fluxapyroxad, fluxofenim, folpet, fomesafen, fomesafen-sodium, fonofos, foramsulfuron, forchlorfenuron, formaldehyde, formetanate, formetanate hydrochloride, formothion, formparanate, formparanate hydrochloride, fosamine, fosamine-ammonium, fosetyl, fosetyl-aluminium, fosmethilan, fospirate, fosthiazate, fosthietan, frontalin, fuberidazole, fucaojing, fucaomi, funaihecaoling, fuphenthiourea, furalane, furalaxyl, furamethrin, furametpyr, furathiocarb, furcarbanil, furconazole, furconazole-cis, furethrin, furfural, furilazole, furmecyclox, furophanate, furyloxyfen, gamma-cyhalothrin, gamma-HCH, genit, gibberellic acid, gibberellins, gliftor, glufosinate, glufosinate-ammonium, glufosinate-P, glufosinate-P-ammonium, glufosinate-P-sodium, glyodin, glyoxime, glyphosate, glyphosate-diammonium, glyphosate-dimethylammonium, glyphosate-isopropylammonium, glyphosate-monoammonium, glyphosate-potassium, glyphosate-sesquisodium, glyphosate-trimesium, glyphosine, gossyplure, grandlure, griseofulvin, guazatine, guazatine acetates, halacrinate, halfenprox, halofenozide, halosafen, halosulfuron, halosulfuron-methyl, haloxydine, haloxyfop, haloxyfop-etotyl, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-etotyl, haloxyfop-P-methyl, haloxyfop-sodium, HCH, hemel, hempa, HEOD, heptachlor, heptenophos, heptopargil, heterophos, hexachloroacetone, hexachlorobenzene, hexachlorobutadiene, hexachlorophene, hexaconazole, hexaflumuron, hexaflurate, hexalure, hexamide, hexazinone, hexylthiofos, hexythiazox, HHDN, holosulf, huancaiwo, huangcaoling, huanjunzuo, hydramethylnon, hydrargaphen, hydrated lime, hydrogen cyanide, hydroprene, hymexazol, hyquincarb, IAA, IBA, icaridin, imazalil, imazalil nitrate, imazalil sulfate, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox-ammonium, imazapic, imazapic-ammonium, imazapyr, imazapyr-isopropylammonium, imazaquin, imazaquin-ammonium, imazaquin-methyl, imazaquin-sodium, imazethapyr, imazethapyr-ammonium, imazosulfuron, imibenconazole, imicyafos, imidacloprid, imidaclothiz, iminoctadine, iminoctadine triacetate, iminoctadine trialbesilate, imiprothrin, inabenfide, indanofan, indaziflam, indoxacarb, inezin, iodobonil, iodocarb, iodomethane, iodosulfuron, iodosulfuron-methyl, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium, ioxynil, ioxynil octanoate, ioxynil-lithium, ioxynil-sodium, ipazine, ipconazole, ipfencarbazone, iprobenfos, iprodione, iprovalicarb, iprymidam, ipsdienol, ipsenol, IPSP, isamidofos, isazofos, isobenzan, isocarbamid, isocarbophos, isocil, isodrin, isofenphos, isofenphos-methyl, isolan, isomethiozin, isonoruron, isopolinate, isoprocarb, isopropalin, isoprothiolane, isoproturon, isopyrazam, isopyrimol, isothioate, isotianil, isouron, isovaledione, isoxaben, isoxachlortole, isoxadifen, isoxadifen-ethyl, isoxaflutole, isoxapyrifop, isoxathion, ivermectin, izopamfos, japonilure, japothrins, jasmolin I, jasmolin II, jasmonic acid, jiahuangchongzong, jiajizengxiaolin, jiaxiangjunzhi, jiecaowan, jiecaoxi, jodfenphos, juvenile hormone I, juvenile hormone II, juvenile hormone III, kadethrin, karbutilate, karetazan, karetazan-potassium, kasugamycin, kasugamycin hydrochloride, kejunlin, kelevan, ketospiradox, ketospiradox-potassium, kinetin, kinoprene, kresoxim-methyl, kuicaoxi, lactofen, lambda-cyhalothrin, latilure, lead arsenate, lenacil, lepimectin, leptophos, lindane, lineatin, linuron, lirimfos, litlure, looplure, lufenuron, lvdingjunzhi, lvxiancaolin, lythidathion, MAA, malathion, maleic hydrazide, malonoben, maltodextrin, MAMA, mancopper, mancozeb, mandipropamid, maneb, matrine, mazidox, MCPA, MCPA-2-ethylhexyl, MCPA-butotyl, MCPA-butyl, MCPA-dimethylammonium, MCPA-diolamine, MCPA-ethyl, MCPA-isobutyl, MCPA-isoctyl, MCPA-isopropyl, MCPA-methyl, MCPA-olamine, MCPA-potassium, MCPA-sodium, MCPA-thioethyl, MCPA-trolamine, MCPB, MCPB-ethyl, MCPB-methyl, MCPB-sodium, mebenil, mecarbam, mecarbinzid, mecarphon, mecoprop, mecoprop-2-ethylhexyl, mecoprop-dimethylammonium, mecoprop-diolamine, mecoprop-ethadyl, mecoprop-isoctyl, mecoprop-methyl, mecoprop-P, mecoprop-P-2-ethylhexyl, mecoprop-P-dimethylammonium, mecoprop-P-isobutyl, mecoprop-potassium, mecoprop-P-potassium, mecoprop-sodium, mecoprop-trolamine, medimeform, medinoterb, medinoterb acetate, medlure, mefenacet, mefenpyr, mefenpyr-diethyl, mefluidide, mefluidide-diolamine, mefluidide-potassium, megatomoic acid, menazon, mepanipyrim, meperfluthrin, mephenate, mephosfolan, mepiquat, mepiquat chloride, mepiquat pentaborate, mepronil, meptyldinocap, mercuric chloride, mercuric oxide, mercurous chloride, merphos, mesoprazine, mesosulfuron, mesosulfuron-methyl, mesotrione, mesulfen, mesulfenfos, metaflumizone, metalaxyl, metalaxyl-M, metaldehyde, metam, metam-ammonium, metamifop, metamitron, metam-potassium, metam-sodium, metazachlor, metazosulfuron, metazoxolon, metconazole, metepa, metflurazon, methabenzthiazuron, methacrifos, methalpropalin, methamidophos, methasulfocarb, methazole, methfuroxam, methidathion, methiobencarb, methiocarb, methiopyrisulfuron, methiotepa, methiozolin, methiuron, methocrotophos, methometon, methomyl, methoprene, methoprotryne, methoquin-butyl, methothrin, methoxychlor, methoxyfenozide, methoxyphenone, methyl apholate, methyl bromide, methyl eugenol, methyl iodide, methyl isothiocyanate, methylacetophos, methylchloroform, methyldymron, methylene chloride, methylmercury benzoate, methylmercury dicyandiamide, methylmercury pentachlorophenoxide, methylneodecanamide, metiram, metobenzuron, metobromuron, metofluthrin, metolachlor, metolcarb, metominostrobin, metosulam, metoxadiazone, metoxuron, metrafenone, metribuzin, metsulfovax, metsulfuron, metsulfuron-methyl, mevinphos, mexacarbate, mieshuan, milbemectin, milbemycin oxime, milneb, mipafox, mirex, MNAF, moguchun, molinate, molosultap, monalide, monisouron, monochloroacetic acid, monocrotophos, monolinuron, monosulfuron, monosulfuron-ester, monuron, monuron TCA, morfamquat, morfamquat dichloride, moroxydine, moroxydine hydrochloride, morphothion, morzid, moxidectin, MSMA, muscalure, myclobutanil, myclozolin, N-(ethylmercury)-p-toluenesulphonanilide, nabam, naftalofos, naled, naphthalene, naphthaleneacetamide, naphthalic anhydride, naphthoxyacetic acids, naproanilide, napropamide, naptalam, naptalam-sodium, natamycin, neburon, niclosamide, niclosamide-olamine, nicosulfuron, nicotine, nifluridide, nipyraclofen, nitenpyram, nithiazine, nitralin, nitrapyrin, nitrilacarb, nitrofen, nitrofluorfen, nitrostyrene, nitrothal-isopropyl, norbormide, norflurazon, nornicotine, noruron, novaluron, noviflumuron, nuarimol, OCH, octachlorodipropyl ether, octhilinone, ofurace, omethoate, orbencarb, orfralure, ortho-dichlorobenzene, orthosulfamuron, oryctalure, orysastrobin, oryzalin, osthol, ostramone, oxabetrinil, oxadiargyl, oxadiazon, oxadixyl, oxamate, oxamyl, oxapyrazon, oxapyrazon-dimolamine, oxapyrazon-sodium, oxasulfuron, oxaziclomefone, oxine-copper, oxolinic acid, oxpoconazole, oxpoconazole fumarate, oxycarboxin, oxydemeton-methyl, oxydeprofos, oxydisulfoton, oxyfluorfen, oxymatrine, oxytetracycline, oxytetracycline hydrochloride, paclobutrazol, paichongding, para-dichlorobenzene, parafluron, paraquat, paraquat dichloride, paraquat dimetilsulfate, parathion, parathion-methyl, parinol, pebulate, pefurazoate, pelargonic acid, penconazole, pencycuron, pendimethalin, penflufen, penfluron, penoxsulam, pentachlorophenol, pentanochlor, penthiopyrad, pentmethrin, pentoxazone, perfluidone, permethrin, pethoxamid, phenamacril, phenazine oxide, phenisopham, phenkapton, phenmedipham, phenmedipham-ethyl, phenobenzuron, phenothrin, phenproxide, phenthoate, phenylmercuriurea, phenylmercury acetate, phenylmercury chloride, phenylmercury derivative of pyrocatechol, phenylmercury nitrate, phenylmercury salicylate, phorate, phosacetim, phosalone, phosdiphen, phosfolan, phosfolan-methyl, phosglycin, phosmet, phosnichlor, phosphamidon, phosphine, phosphocarb, phosphorus, phostin, phoxim, phoxim-methyl, phthalide, picloram, picloram-2-ethylhexyl, picloram-isoctyl, picloram-methyl, picloram-olamine, picloram-potassium, picloram-triethylammonium, picloram-tris(2-hydroxypropyl)ammonium, picolinafen, picoxystrobin, pindone, pindone-sodium, pinoxaden, piperalin, piperonyl butoxide, piperonyl cyclonene, piperophos, piproctanyl, piproctanyl bromide, piprotal, pirimetaphos, pirimicarb, pirimioxyphos, pirimiphos-ethyl, pirimiphos-methyl, plifenate, polycarbamate, polyoxins, polyoxorim, polyoxorim-zinc, polythialan, potassium arsenite, potassium azide, potassium cyanate, potassium gibberellate, potassium naphthenate, potassium polysulfide, potassium thiocyanate, potassium α-naphthaleneacetate, pp′-DDT, prallethrin, precocene I, precocene II, precocene III, pretilachlor, primidophos, primisulfuron, primisulfuron-methyl, probenazole, prochloraz, prochloraz-manganese, proclonol, procyazine, procymidone, prodiamine, profenofos, profluazol, profluralin, profluthrin, profoxydim, proglinazine, proglinazine-ethyl, prohexadione, prohexadione-calcium, prohydrojasmon, promacyl, promecarb, prometon, prometryn, promurit, propachlor, propamidine, propamidine dihydrochloride, propamocarb, propamocarb hydrochloride, propanil, propaphos, propaquizafop, propargite, proparthrin, propazine, propetamphos, propham, propiconazole, propineb, propisochlor, propoxur, propoxycarbazone, propoxycarbazone-sodium, propyl isome, propyrisulfuron, propyzamide, proquinazid, prosuler, prosulfalin, prosulfocarb, prosulfuron, prothidathion, prothiocarb, prothiocarb hydrochloride, prothioconazole, prothiofos, prothoate, protrifenbute, proxan, proxan-sodium, prynachlor, pydanon, pymetrozine, pyracarbolid, pyraclofos, pyraclonil, pyraclostrobin, pyraflufen, pyraflufen-ethyl, pyrafluprole, pyramat, pyrametostrobin, pyraoxystrobin, pyrasulfotole, pyrazolynate, pyrazophos, pyrazosulfuron, pyrazosulfuron-ethyl, pyrazothion, pyrazoxyfen, pyresmethrin, pyrethrin I, pyrethrin II, pyrethrins, pyribambenz-isopropyl, pyribambenz-propyl, pyribencarb, pyribenzoxim, pyributicarb, pyriclor, pyridaben, pyridafol, pyridalyl, pyridaphenthion, pyridate, pyridinitril, pyrifenox, pyrifluquinazon, pyriftalid, pyrimethanil, pyrimidifen, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrimitate, pyrinuron, pyriofenone, pyriprole, pyripropanol, pyriproxyfen, pyrithiobac, pyrithiobac-sodium, pyrolan, pyroquilon, pyroxasulfone, pyroxsulam, pyroxychlor, pyroxyfur, quassia, quinacetol, quinacetol sulfate, quinalphos, quinalphos-methyl, quinazamid, quinclorac, quinconazole, quinmerac, quinoclamine, quinonamid, quinothion, quinoxyfen, quintiofos, quintozene, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, quwenzhi, quyingding, rabenzazole, rafoxanide, rebemide, resmethrin, rhodethanil, rhodojaponin-III, ribavirin, rimsulfuron, rotenone, ryania, saflufenacil, saijunmao, saisentong, salicylanilide, sanguinarine, santonin, schradan, scilliroside, sebuthylazine, secbumeton, sedaxane, selamectin, semiamitraz, semiamitraz chloride, sesamex, sesamolin, sethoxydim, shuangjiaancaolin, siduron, siglure, silafluofen, silatrane, silica gel, silthiofam, simazine, simeconazole, simeton, simetryn, sintofen, SMA, S-metolachlor, sodium arsenite, sodium azide, sodium chlorate, sodium fluoride, sodium fluoroacetate, sodium hexafluorosilicate, sodium naphthenate, sodium orthophenylphenoxide, sodium pentachlorophenoxide, sodium polysulfide, sodium thiocyanate, sodium α-naphthaleneacetate, sophamide, spinetoram, spinosad, spirodiclofen, spiromesifen, spirotetramat, spiroxamine, streptomycin, streptomycin sesquisulfate, strychnine, sulcatol, sulcofuron, sulcofuron-sodium, sulcotrione, sulfallate, sulfentrazone, sulfiram, sulfluramid, sulfometuron, sulfometuron-methyl, sulfosulfuron, sulfotep, sulfoxaflor, sulfoxide, sulfoxime, sulfur, sulfuric acid, sulfuryl fluoride, sulglycapin, sulprofos, sultropen, swep, tau-fluvalinate, tavron, tazimcarb, TCA, TCA-ammonium, TCA-calcium, TCA-ethadyl, TCA-magnesium, TCA-sodium, TDE, tebuconazole, tebufenozide, tebufenpyrad, tebufloquin, tebupirimfos, tebutam, tebuthiuron, tecloftalam, tecnazene, tecoram, teflubenzuron, tefluthrin, tefuryltrione, tembotrione, temephos, tepa, TEPP, tepraloxydim, terallethrin, terbacil, terbucarb, terbuchlor, terbufos, terbumeton, terbuthylazine, terbutryn, tetcyclacis, tetrachloroethane, tetrachlorvinphos, tetraconazole, tetradifon, tetrafluron, tetramethrin, tetramethylfluthrin, tetramine, tetranactin, tetrasul, thallium sulfate, thenylchlor, theta-cypermethrin, thiabendazole, thiacloprid, thiadifluor, thiamethoxam, thiapronil, thiazafluron, thiazopyr, thicrofos, thicyofen, thidiazimin, thidiazuron, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thifluzamide, thiobencarb, thiocarboxime, thiochlorfenphim, thiocyclam, thiocyclam hydrochloride, thiocyclam oxalate, thiodiazole-copper, thiodicarb, thiofanox, thiofluoximate, thiohempa, thiomersal, thiometon, thionazin, thiophanate, thiophanate-methyl, thioquinox, thiosemicarbazide, thiosultap, thiosultap-diammonium, thiosultap-disodium, thiosultap-monosodium, thiotepa, thiram, thuringiensin, tiadinil, tiaojiean, tiocarbazil, tioclorim, tioxymid, tirpate, tolclofos-methyl, tolfenpyrad, tolylfluanid, tolylmercury acetate, topramezone, tralkoxydim, tralocythrin, tralomethrin, tralopyril, transfluthrin, transpermethrin, tretamine, triacontanol, triadimefon, triadimenol, triafamone, tri-allate, triamiphos, triapenthenol, triarathene, triarimol, triasulfuron, triazamate, triazbutil, triaziflam, triazophos, triazoxide, tribenuron, tribenuron-methyl, tribufos, tributyltin oxide, tricamba, trichlamide, trichlorfon, trichlormetaphos-3, trichloronat, triclopyr, triclopyr-butotyl, triclopyr-ethyl, triclopyr-triethylammonium, tricyclazole, tridemorph, tridiphane, trietazine, trifenmorph, trifenofos, trifloxystrobin, trifloxysulfuron, trifloxysulfuron-sodium, triflumizole, triflumuron, trifluralin, triflusulfuron, triflusulfuron-methyl, trifop, trifop-methyl, trifopsime, triforine, trihydroxytriazine, trimedlure, trimethacarb, trimeturon, trinexapac, trinexapac-ethyl, triprene, tripropindan, triptolide, tritac, triticonazole, tritosulfuron, trunc-call, uniconazole, uniconazole-P, urbacide, uredepa, valerate, validamycin, valifenalate, valone, vamidothion, vangard, vaniliprole, vernolate, vinclozolin, warfarin, warfarin-potassium, warfarin-sodium, xiaochongliulin, xinjunan, xiwojunan, XMC, xylachlor, xylenols, xylylcarb, yishijing, zarilamid, zeatin, zengxiaoan, zeta-cypermethrin, zinc naphthenate, zinc phosphide, zinc thiazole, zineb, ziram, zolaprofos, zoxamide, zuomihuanglong, α-chlorohydrin, α-ecdysone, α-multistriatin, and α-naphthaleneacetic acid.
43 . A composition according to claim 1 further comprising an agriculturally acceptable carrier.
44 . A composition according to claim 1 wherein said molecule is in the form of a pesticidally acceptable acid addition salt.
45 . A composition according to claim 1 wherein said molecule is in the form of a salt derivative.
46 . A composition according to claim 1 wherein said molecule is in the form a hydrate.
47 . A composition according to claim 1 wherein said molecule is in the form an ester derivative.
48 . A composition according to claim 1 wherein said molecule is in the form a crystal polymorph.
49 . A composition according to claim 1 wherein said molecule has a 2 H in place of 1 H.
50 . A composition according to claim 1 wherein said molecule has a 14 C in place of a 12 C.
51 . A composition according to claim 1 further comprising a biopesticide.
52 . A composition according to claim 1 further comprising one or more of the following compounds:
(a) 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-oxa-1-azaspiro[4,5]dec-3-en-2-one;
(b) 3-(4′-chloro-2,4-dimethyl[1,1′-biphenyl]-3-yl)-4-hydroxy-8-oxa-1-azaspiro[4,5]dec-3-en-2-one;
(c) 4-[[(6-chloro-3-pyridinyl)methyl]methylamino]-2(5H)-furanone;
(d) 4-[[(6-chloro-3-pyridinyl)methyl]cyclopropylamino]-2(5H)-furanone;
(e) 3-chloro-N2-[(1S)-1-methyl-2-(methylsulfonyl)ethyl]-N1-[2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]-1,2-benzenedicarboxamide;
(f) 2-cyano-N-ethyl-4-fluoro-3-methoxy-benenesulfonamide;
(g) 2-cyano-N-ethyl-3-methoxy-benzenesulfonamide;
(h) 2-cyano-3-difluoromethoxy-N-ethyl-4-fluoro-benzenesulfonamide;
(i) 2-cyano-3-fluoromethoxy-N-ethyl-benzenesulfonamide;
(j) 2-cyano-6-fluoro-3-methoxy-N,N-dimethyl-benzenesulfonamide;
(k) 2-cyano-N-ethyl-6-fluoro-3-methoxy-N-methyl-benzenesulfonamide;
(l) 2-cyano-3-difluoromethoxy-N,N-dimethylbenzenesulfon-amide;
(m) 3-(difluoromethyl)-N-[2-(3,3-dimethylbutyl)phenyl]-1-methyl-1H-pyrazole-4-carboxamide;
(n)N-ethyl-2,2-dimethylpropionamide-2-(2,6-dichloro-α,α,α-trifluoro-p-tolyl) hydrazone;
(o)N-ethyl-2,2-dichloro-1-methylcyclopropane-carboxamide-2-(2,6-dichloro-α,α,α-trifluoro-p-tolyl) hydrazone nicotine;
(p) O-{(E−)-[2-(4-chloro-phenyl)-2-cyano-1-(2-trifluoromethylphenyl)-vinyl]}S-methyl thiocarbonate;
(q) (E)-N1-[(2-chloro-1,3-thiazol-5-ylmethyl)]-N2-cyano-N1-methylacetamidine;
(r) 1-(6-chloropyridin-3-ylmethyl)-7-methyl-8-nitro-1,2,3,5,6,7-hexahydro-imidazo[1,2-a]pyridin-5-ol;
(s) 4-[4-chlorophenyl-(2-butylidine-hydrazono)methyl)]phenyl mesylate; and
(t) N-Ethyl-2,2-dichloro-1-methylcyclopropanecarboxamide-2-(2,6-dichloro-alpha, alpha, alpha-trifluoro-p-tolyl)hydrazone.
53 . A composition according to claim 1 further comprising a compound having one or more of the following modes of action: acetylcholinesterase inhibitor; sodium channel modulator; chitin biosynthesis inhibitor; GABA and glutamate-gated chloride channel antagonist; GABA and glutamate-gated chloride channel agonist; acetylcholine receptor agonist; acetylcholine receptor antagonist; MET I inhibitor; Mg-stimulated ATPase inhibitor; nicotinic acetylcholine receptor; Midgut membrane disrupter; oxidative phosphorylation disrupter, and ryanodine receptor (RyRs).
54 . A composition according to claim 1 further comprising a seed.
55 . A composition according to claim 1 further comprising a seed that has been genetically modified to express one or more specialized traits.
56 . A composition according to claim 1 wherein said composition is encapsulated inside, or placed on the surface of, a capsule.
57 . A composition according to claim 1 wherein said composition is encapsulated inside, or placed on the surface of, a capsule, wherein said capsule has a diameter of about 100-900 nanometers or about 10-900 microns.
58 . A process comprising applying a composition according to claim 1 , to an area to control a pest, in an amount sufficient to control such pest.
59 . A process according to claim 58 wherein said pest is selected from beetles, earwigs, cockroaches, flies, aphids, scales, whiteflies, leafhoppers, ants, wasps, termites, moths, butterflies, lice, grasshoppers, locusts, crickets, fleas, thrips , bristletails, mites, ticks, nematodes, and symphylans.
60 . A process according to claim 58 wherein said pest is from the Phyla Nematoda or Arthropoda.
61 . A process according to claim 58 wherein said pest is from the Subphyla Chelicerata, Myriapoda, or Hexapoda.
62 . A process according to claim 58 wherein said pest is from the Class of Arachnida, Symphyla, or Insecta.
63 . A process according to claim 58 wherein said pest is from the Order Anoplura, Order Coleoptera, Order Dermaptera, Order Blattaria, Order Diptera, Order Hemiptera, Order Hymenoptera, Order Isoptera, Order Lepidoptera, Order Mallophaga, Order Orthoptera, Order Siphonaptera, Order Thysanoptera, Order Thysanura, Order Acarina, or Order Symphyla.
64 . A process according to claim 58 wherein said pest is BAW, CEW, or GPA.
65 . A process according to claim 58 wherein said amount is from about 0.01 grams per hectare to about 5000 grams per hectare.
66 . A process according to claim 58 wherein said amount is from about 0.1 grams per hectare to about 500 grams per hectare.
67 . A process according to claim 58 wherein said amount is from about 1 gram per hectare to about 50 grams per hectare.
68 . A process according to claim 58 wherein said area is an area where apples, corn, cotton, soybeans, canola, wheat, rice, sorghum, barley, oats, potatoes, oranges, alfalfa, lettuce, strawberries, tomatoes, peppers, crucifers, pears, tobacco, almonds, sugar beets, or beans, are growing, or the seeds thereof are going to be planted.
69 . A process according to claim 58 further comprising applying said composition to a genetically modified plant that has been genetically modified to express one or more specialized traits.
70 . A process according to claim 1 where said composition further comprise ammonium sulfate.
71 . A process comprising: orally administering; or topically applying; a composition according to claim 1 , to a non-human animal, to control endoparasites, ectoparasites, or both.
72 . A process comprising applying a composition according to claim 1 to a plant to enhance the plant's health, yield, vigor, quality, or tolerance, at a time when pest activity is low.Cited by (0)
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