Zeolite catalysts, methods for producing zeolite catalysts, and methods for producing lower olefins

Abstract

Provided are zeolite catalysts that allow reactions to proceed at temperatures as low as possible when lower olefins are produced from hydrocarbon feedstocks with low boiling points such as light naphtha, make it possible to make propylene yield higher than ethylene yield in the production of lower olefins, and have long lifetime. The zeolite catalysts are used in the production of lower olefins from hydrocarbon feedstocks with low boiling points such as light naphtha. The zeolite catalysts are MFI-type crystalline aluminosilicates containing iron atoms and have molar ratios of iron atoms to total moles of iron atoms and aluminum atoms in the range from 0.4 to 0.7. The use of the zeolite catalysts make it possible to increase propylene yield, to lower reaction temperatures, and to extend catalyst lifetime.

1 - 14 . (canceled) 
     
     
         15 . Zeolite catalysts for producing lower olefins having 2 to 4 carbon atoms, for performing reactions to produce the lower olefins from hydrocarbon feedstocks with low boiling points having a range of boiling points from 35° C. to 200° C. at reaction temperature range from 525° C. to 575° C., and for suppressing formation of aromatic hydrocarbons, the zeolite catalysts comprising MFI-type crystalline aluminosilicates containing iron atoms in a skeleton in a state in which an iron source, a silicon source, and an aluminum source are synthesized by hydrothermal synthesis,
 the zeolite catalysts having molar ratios of iron atoms to total moles of iron atoms and aluminum atoms in the range from 0.4 to 0.7. 
 
     
     
         16 . The zeolite catalysts according to  claim 15 , which are for use in the production of lower olefins from the hydrocarbon feedstocks with low boiling points diluted with inert gas and/or steam,
 the zeolite catalysts having acid densities, defined as molar ratios of silicon atoms to total moles of iron atoms and aluminum atoms, in the range from 12.0 to 45.0.   
     
     
         17 . The zeolite catalysts according to  claim 15 , which are for use in the production of lower olefins from the hydrocarbon feedstocks with low boiling points which are not diluted,
 the zeolite catalysts having acid densities, defined as molar ratios of silicon atoms to total moles of iron atoms and aluminum atoms, in the range from 75.0 to 200.0.   
     
     
         18 . Methods for producing the zeolite catalysts according to  claim 15 , comprising a series of processes including a hydrothermal synthesis step, a molding step, and an ion-exchange step, wherein
 the hydrothermal synthesis step includes synthesizing secondary particles with average sizes in the range from 0.25 μm to 1.0 μm.   
     
     
         19 . Methods for producing the zeolite catalysts according to  claim 15 , comprising a series of processes including a hydrothermal synthesis step, a molding step, and an ion-exchange step, wherein
 the ion exchange-step is performed after the molding step.   
     
     
         20 . Methods for producing lower olefins from hydrocarbon feedstocks with low boiling points using the zeolite catalysts according to  claim 15 , comprising:
 performing reactions to produce the lower olefins from the hydrocarbon feedstocks with low boiling points in the presence of the zeolite catalysts in reaction temperature range from 525° C. to 575° C.