Polythiol composition, polymerizable composition for optical material and use thereof

Abstract

A polythiol composition includes a polythiol compound (A) having three or more mercapto groups and a nitrogen-containing compound (B) in which one of a mercapto group of the polythiol compound (A) is replaced with a group represented by the following formula (a) and other one of a mercapto group of the polythiol compound (A) is replaced with a hydroxyl group, in which the peak area of the nitrogen-containing compound (B) is equal to or less than 1.5 with respect to the peak area of 100 of the polythiol compound (A) in a high performance liquid chromatography measurement.

1 . A polythiol composition comprising:
 a polythiol compound (A) having three or more mercapto groups; and   a nitrogen-containing compound (B) in which one of a mercapto group of the polythiol compound (A) is replaced with a group represented by the following formula (a)   
       
         
           
           
               
               
           
         
         wherein, in the formula, * represents an atomic bonding, and other one of a mercapto group of the polythiol compound (A) is replaced with a hydroxyl group, 
         wherein the peak area of the nitrogen-containing compound (B) is equal to or less than 1.5, with respect to the peak area of 100 of the polythiol compound (A) in a high performance liquid chromatography measurement. 
       
     
     
         2 . The polythiol composition according to  claim 1 ,
 wherein the polythiol compound (A) is represented by the following formula (5)   
       
         
           
           
               
               
           
         
       
     
     
         3 . The polythiol composition according to  claim 1 ,
 wherein the polythiol compound (A) is primarily comprised of at least one kind selected from the compounds represented by the following formulae (6) to (8)   
       
         
           
           
               
               
           
         
       
     
     
         4 . A polymerizable composition for an optical material comprising:
 the polythiol composition according to any of  claim 1 ; and   a poly(thio)isocyanate compound.   
     
     
         5 . A method of manufacturing a molded product, comprising: mixing the polythiol composition according to  claim 1  and a poly(thio)isocyanate compound to obtain a polymerizable composition for an optical material; and
 injecting the polymerizable composition into a mold and curing the composition. 
 
     
     
         6 . A molded product which is obtained by curing the polymerizable composition according to  claim 4 . 
     
     
         7 . An optical element comprised of the molded product according to  claim 6 . 
     
     
         8 . A lens comprised of the optical element according to  claim 7 .