Ferritic stainless steel sheet

Abstract

To provide a ferritic stainless steel sheet which has high scale spalling even at a high temperature around 1000° C. Provided is a ferritic stainless steel sheet having excellent Mn-containing oxide film-forming ability and scale spalling ability, containing, in terms of mass %: C: 0.001 to 0.020%, N: 0.001 to 0.020%, Si: 0.10 to 0.40%, Mn: 0.20 to 1.00%, Cr: 16.0 to 20.0%, Nb: 0.30 to 0.80%, Mo: 1.80 to 2.40%, W: 0.05 to 1.40%, Cu: 1.00 to 2.50%, and B: 0.0003 to 0.0030%, in which the above-mentioned components are contained satisfying the formula (1) below, and the balance is composed of Fe and inevitable impurities. At least one of N, Al, V, Mg, Sn, Co, Zr, Hf, and Ta may be added in a predetermined content range. 3≦(5×Mo)/(3≦Mn)≦20  (1)

1 . The Mn-containing ferritic stainless steel sheet consisting of, in terms of mass %:
 C: 0.001 to 0.020%,   N: 0.001 to 0.020%,   Si: 0.10 to 0.40%,   Mn: 0.20 to 1.00%,   Cr: 16.0 to 20.0%,   Nb: 0.30 to 0.80%,   Mo: 1.80 to 2.40%,   W: 0.05 to 1.40%,   Cu: 1.00 to 2.50%,   B: 0.0003 to 0.0030%, and   a component selected from at least one group of a first group containing one or more of   Ni: 0.10 to 1.0%,   Al: 0.01 to 1.0%, and   V: 0.01 to 0.50%;   a second group containing   Mg: 0.00010 to 0.0100%;   a third group containing one or more of   Sn: 0.01 to 0.50% and   Co: 0.01 to 1.50%; and   a fourth group containing one or more of   Zr: 0.01 to 1.0%,   Hf: 0.01 to 1.0%, and   Ta: 0.01 to 2.0%, satisfying the formula (1) below   
       and the balance is composed of Fe and inevitable impurities
   5≦(5×Mo)/(3×Mn)≦20  (1),
 
 
       wherein Mo and Mn in the formula (1) each mean the content (mass %) thereof. 
     
     
         2 . The Mn-containing ferritic stainless steel sheet consisting of in terms of mass %:
 C: 0.001 to 0.020%,   N: 0.001 to 0.020%,   Si: 0.10 to 0.40%,   Mn: 0.20 to 1.00%,   Cr: 16.0 to 20.0%,   Nb: 0.30 to 0.80%,   Mo: 1.80 to 2.40%,   W: 0.05 to 1.40%,   Cu: 1.00 to 2.50%,   B: 0.0003 to 0.0030%, and   a component selected from at least one group of a first group containing one or more of   Ni: 0.10 to 1.0%,   Al: 0.01 to 1.0%, and   V: 0.01 to 0.50%;   a second group containing   Mg: 0.00010 to 0.0100%;   a third group containing one or more of   Sn: 0.01 to 0.50% and   Co: 0.01 to 1.50%; and   a fourth group containing one or more of   Zr: 0.01 to 1.0%,   Hf: 0.01 to 1.0%, and   Ta: 0.01 to 2.0%, satisfying the formula (1) below   
       and the balance is composed of Fe and inevitable impurities
   5≦(5×Mo)/(3×Mn)≦20  (1),
 
 
       wherein Mo and Mn in the formula (1) each mean the content (mass %) thereof. 
     
     
         3 . The Mn-containing ferritic stainless steel sheet according to  claim 1 , wherein (Mn, Cr) 3 O 4  is generated on an outermost layer of an oxide film when a heat treatment is performed in a condition of 900 to 1000° C.×100 hours or longer. 
     
     
         4 . The Mn-containing ferritic stainless steel sheet according to  claim 1 , wherein an amount of spalled scale in cases in which the ferritic stainless steel sheet is subjected to a continuous oxidation test in air at 1000° C. for 200 hours is 1.0 mg/cm 2  or smaller.