US2018133846A1PendingUtilityA1

Precipitation strengthened nickel based welding material for fusion welding of superalloys

63
Assignee: LIBURDI ENGINEERINGPriority: Dec 24, 2013Filed: Jan 11, 2018Published: May 17, 2018
Est. expiryDec 24, 2033(~7.5 yrs left)· nominal 20-yr term from priority
B23K 35/24B23K 35/0227B23K 35/0261C22F 1/10B23K 35/3033C22C 19/057B23K 35/304C22C 19/056B23K 35/30B23K 35/0255B23P 6/00B23K 35/0222C22C 19/05C22C 30/00
63
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Claims

Abstract

A precipitation strengthened nickel based welding material that comprises 5-15 wt. % Co, 5-25 wt. % Cr, 1-6 wt. % Al, 0.05-0.2 wt. % C, 0.015-0.4 wt. % B, 1-3 wt. % Si, chemical elements selected from among tungsten and molybdenum from about 1 to 20 wt. %, chemical elements selected from among titanium, zirconium, hafnium, tantalum and rhenium from about 1 to 18 wt. % and nickel with impurities to balance, wherein the boron content is inversely proportional to silicon content and decreases from about 0.3 wt. % to about 0.015 wt. % when silicon content increases from about 1 wt. % to about 3 wt. % produces sound high strength and high oxidation resistance crack free welds on precipitation strengthened superalloys and single crystal materials.

Claims

exact text as granted — not AI-modified
1 . A method of producing a precipitation strengthened nickel based welding material for fusion welding of superalloys, the method comprising:
 combining the following in weight percentages:   
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cobalt from about 
                   5 to 15 wt. % 
                 
                     
                   Chromium from about 
                   5 to 25 wt. % 
                 
                     
                   Aluminum from about 
                    1 to 6 wt. % 
                 
                     
                   Carbon from about 
                   0.05 to 0.2 wt. %   
                 
                     
                   Boron from about 
                   0.015 to 0.4 wt. %   
                 
                     
                   Silicon from about 
                    1 to 3 wt. % 
                 
                 
                 
               
                     
                   a combination of one or more of Tungsten and Molybdenum for 
                 
                     
                   a combined total wt. % from about 1 to 20 wt. % 
                 
                     
                   a combination of one or more of Titanium, Zirconium, Hafnium, 
                 
                     
                   Tantalum and Rhenium for a combined total wt. % from 
                 
                     
                   about 1 to 18 wt. %, and 
                 
                     
                   Nickel with impurities to balance; 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
               
            
             
                
                
                
                
                
                
                
               
            
           
         
       
       wherein the boron content is reduced proportionately from about an initial 0.4 wt. % to about a final 0.015 wt. % with a proportionate increase in the silicon content from about an initial 1 wt. % to about a final 3 wt. % such that the total combined boron and silicon content ranges from about 1.4 wt. % to 3.015 wt. %. 
     
     
         2 . A method of producing precipitation strengthened nickel based welding material for fusion welding of superalloys, the method comprising:
 combining the following in weight percentages:   
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cobalt from about 
                   8 to 10 
                   wt. % 
                 
                     
                   Chromium from about 
                   14 to 18 
                   wt. % 
                 
                     
                   Molybdenum from about 
                   3 to 5 
                   wt. % 
                 
                     
                   Tungsten from about 
                   3 to 5 
                   wt. % 
                 
                     
                   Titanium from about 
                   3 to 6 
                   wt. % 
                 
                     
                   Zirconium from about 
                   0.04 to 0.06 
                   wt. % 
                 
                     
                   Aluminum from about 
                   2 to 4 
                   wt. % 
                 
                     
                   Carbon from about 
                   0.05 to 0.2 
                   wt. % 
                 
                     
                   Boron from about 
                   0.1 to 0.35 
                   wt. % 
                 
                     
                   Silicon from about 
                   1 to 3 
                   wt. %, and 
                 
                 
                 
               
                     
                   a combination of one or more of Titanium, Zirconium, Hafnium, 
                 
                     
                   Tantalum and Rhenium for a combined total wt. % from about 
                 
                     
                   1 to 18 wt. %, and 
                 
                     
                   Nickel with impurities to balance; 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
               
            
             
                
                
                
                
                
               
            
           
         
       
       wherein the boron content is reduced proportionately from about an initial 0.35 wt. % to about a final 0.1 wt. % with a proportionate increase in the silicon content from about an initial 1 wt. % to about a final 3 wt. % such that the total combined boron and silicon content ranges from about 1.35 wt. % to 3.1 wt. %. 
     
     
         3 . The method of precipitation strengthening nickel based welding material for fusion welding of superalloys of  claim 1 , wherein the following are combined: 
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cobalt from about 
                   11 to 13 
                   wt. % 
                 
                     
                   Chromium from about 
                   6 to 8 
                   wt. % 
                 
                     
                   Molybdenum from about 
                   1 to 3 
                   wt. % 
                 
                     
                   Tungsten from about 
                   4 to 6 
                   wt. % 
                 
                     
                   Zirconium from about 
                   0.01 to 0.03 
                   wt. % 
                 
                     
                   Aluminum from about 
                   5 to 6 
                   wt. % 
                 
                     
                   Carbon from about 
                   0.1 to 0.15 
                   wt. % 
                 
                     
                   Rhenium from about 
                   1 to 3 
                   wt. % 
                 
                     
                   Tantalum from about 
                   5 to 7 
                   wt. % 
                 
                     
                   Boron from about 
                   0.015 to 0.3 
                   wt. % 
                 
                     
                   Silicon from about 
                   1.2 to 1.8 
                   wt. %, and 
                 
                 
                 
               
                     
                   Nickel with impurities to balance 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
               
            
             
                
                
               
            
           
         
       
     
     
         4 . The method of precipitation strengthening nickel based welding material for fusion welding of superalloys of  claim 3 , wherein the boron content is reduced proportionately from about 0.4 wt. % to about 0.1 wt. % with a proportionate increase in the silicon content from about 1 wt. % to about 3 wt. % such that the total boron and silicon content ranges from about 1.4 wt. % to 3.1 wt. %. 
     
     
         5 . The method according to  claim 1 , wherein the precipitation strengthened nickel based welding material for fusion welding of superalloys produced is a welding powder. 
     
     
         6 . The method according to  claim 1 , wherein the precipitation strengthened nickel based welding material for fusion welding of superalloys produced is a welding wire. 
     
     
         7 . The method according to  claim 1 , wherein the precipitation strengthened nickel based welding material for fusion welding of superalloys produced is for use in a repair section of a turbine engine component. 
     
     
         8 . A precipitation strengthened nickel based welding material for fusion welding of superalloys comprised of the following elements in weight percentages: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cobalt from about 
                   5 to 15 wt. % 
                 
                     
                   Chromium from about 
                   5 to 25 wt. % 
                 
                     
                   Aluminum from about 
                    1 to 6 wt. % 
                 
                     
                   Carbon from about 
                   0.05 to 0.2 wt. %   
                 
                     
                   Boron from about 
                   0.015 to 0.4 wt. %   
                 
                     
                   Silicon from about 
                    1 to 3 wt. % 
                 
                 
                 
               
                     
                   Selected from among Tungsten and Molybdenum from 
                 
                     
                   about 1 to 20 wt. % 
                 
                     
                   Selected from among Titanium, Zirconium, Hafnium, Tantalum 
                 
                     
                   and Rhenium from about 1 to 18 combined total wt. %, and 
                 
                     
                   Nickel with impurities to balance; 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
               
            
             
                
                
                
                
                
                
               
            
           
         
       
       wherein the boron content is reduced proportionately from about an initial 0.4 wt. % to about a final 0.015 wt. % with a proportionate increase in the silicon content from about an initial 1 wt. % to about a final 3 wt. % such that the total combined boron and silicon content ranges from about 1.4 wt. % to 3.015 wt. %. 
     
     
         9 . A precipitation strengthened nickel based welding material for fusion welding of superalloys comprised of the following elements in weight percentages: 
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cobalt from about 
                   8 to 10 
                   wt. % 
                 
                     
                   Chromium from about 
                   14 to 18 
                   wt. % 
                 
                     
                   Molybdenum from about 
                   3 to 5 
                   wt. % 
                 
                     
                   Tungsten from about 
                   3 to 5 
                   wt. % 
                 
                     
                   Titanium from about 
                   3 to 6 
                   wt. % 
                 
                     
                   Zirconium from about 
                   0.04 to 0.06 
                   wt. % 
                 
                     
                   Aluminum from about 
                   2 to 4 
                   wt. % 
                 
                     
                   Carbon from about 
                   0.05 to 0.2 
                   wt. % 
                 
                     
                   Boron from about 
                   0.1 to 0.35 
                   wt. % 
                 
                     
                   Silicon from about 
                   1 to 3 
                   wt. %, and 
                 
                 
                 
               
                     
                   Selected from among Titanium, Zirconium, Hafnium, Tantalum 
                 
                     
                   and Rhenium from about 1 to 18 combined total wt. %, and 
                 
                     
                   Nickel with impurities to balance; 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
               
            
             
                
                
                
                
               
            
           
         
       
       wherein the boron-silicon content is determined wherein the boron content is reduced proportionately from about an initial 0.35 wt. % to about a final 0.1 wt. % with a proportionate increase in the silicon content from about an initial 1 wt. % to about a final 3 wt. % such that the total combined boron and silicon content ranges from about 1.35 wt. % to 3.1 wt. %. 
     
     
         10 . The precipitation strengthened nickel based welding material for fusion welding of superalloys of  claim 8 , limited to the following in weight percentages: 
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cobalt from about 
                   11 to 13 
                   wt. % 
                 
                     
                   Chromium from about 
                   6 to 8 
                   wt. % 
                 
                     
                   Molybdenum from about 
                   1 to 3 
                   wt. % 
                 
                     
                   Tungsten from about 
                   4 to 6 
                   wt. % 
                 
                     
                   Zirconium from about 
                   0.01 to 0.03 
                   wt. % 
                 
                     
                   Aluminum from about 
                   5 to 6 
                   wt. % 
                 
                     
                   Carbon from about 
                   0.1 to 0.15 
                   wt. % 
                 
                     
                   Rhenium from about 
                   1 to 3 
                   wt. % 
                 
                     
                   Tantalum from about 
                   5 to 7 
                   wt. % 
                 
                     
                   Boron from about 
                   0.015 to 0.3 
                   wt. % 
                 
                     
                   Silicon from about 
                   1.2 to 1.8 
                   wt. %, and 
                 
                 
                 
               
                     
                   Nickel with impurities to balance 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
               
            
             
                
                
               
            
           
         
       
     
     
         11 . The precipitation strengthened nickel based welding material claimed in  claim 10  wherein the boron content reduced proportionately from about 0.4 wt. % to about 0.1 wt. % with a proportionate increase in the silicon content from about 1 wt. % to about 3 wt. % such that the total boron and silicon content ranges from about 1.4 wt. % to 3.1 wt. %.

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