Additives for hydrogen/bromine cells

Abstract

The invention relates to the use of 1-alkyl-2-alkyl pyridinium halide (e.g., 1-ethyl-2-methyl pyridinium bromide), 1-alkyl-3-alkyl pyridinium halide (e.g., 1-ethyl-3-methyl pyridinium bromide) or 1-alkyl-3-alkyl imidazolium halide (e.g., 1-butyl 3-methyl imidazolium bromide) as additives in an electrolyte used in hydrogen/bromine cells, for complexing the elemental bromine formed in such cells. The invention also provides an electrolyte comprising aqueous hydrogen bromide and said additives, and processes for operating an electrochemical flow cell selected from the group consisting of hydrogen/bromine or vanadium/bromine cells.

1 ) An electrolyte suitable for use in an electrochemical flow cell, said electrolyte comprising aqueous hydrogen bromide and a liquid complex composed of at least one of 1-alkyl-2-alkyl pyridinium halide, 1-alkyl-3-alkyl pyridinium halide or 1-alkyl-3-alkyl imidazolium halide combined with one or more bromine molecules. 
     
     
         2 ) An electrolyte according to  claim 1 , comprising a liquid complex composed of at least one of 1-ethyl-2-methyl pyridinium bromide, 1-ethyl-3-methyl pyridinium bromide or 1-butyl 3-methyl imidazolium bromide combined with one or more bromine molecules. 
     
     
         3 ) An electrolyte according to  claim 2 , comprising a liquid complex composed of at least one of 1-ethyl-2-methyl pyridinium bromide or 1-ethyl-3-methyl pyridinium bromide, combined with one or more bromine molecules. 
     
     
         4 ) An electrolyte according to  claim 3 , comprising a mixture of 1-ethyl-2-methyl pyridinium bromide and 1-ethyl-3-methyl pyridinium bromide. 
     
     
         5 ) Use of at least one of 1-alkyl-2-alkyl pyridinium halide, 1-alkyl-3-alkyl pyridinium halide or 1-alkyl-3-alkyl imidazolium halide as bromine-complexing agents in an electrochemical flow cell which contains an electrolyte comprising aqueous hydrogen bromide, said cell being hydrogen/bromine cell or vanadium bromine cell. 
     
     
         6 ) Use according to  claim 5 , wherein the 1-alkyl-2-alkyl pyridinium halide is 1-ethyl-2-methyl pyridinium bromide. 
     
     
         7 ) Use according to  claim 5 , wherein the 1-alkyl-3-alkyl pyridinium halide is 1-ethyl-3-methyl pyridinium bromide. 
     
     
         8 ) Use according to  claim 5 , wherein a mixture of 1-ethyl-2-methyl pyridinium bromide and 1-ethyl-3-methyl pyridinium bromide is used. 
     
     
         9 ) A process for operating an electrochemical flow cell selected from the group consisting of hydrogen/bromine or vanadium/bromine cells, comprising adding to HBr-containing electrolyte solution of said cell an additive selected from the group consisting of 1-alkyl-2-alkyl pyridinium halide, 1-alkyl-3-alkyl pyridinium halide, 1-alkyl-3-alkyl imidazolium halide or their mixture. 
     
     
         10 ) A process according to  claim 9 , comprising adding 1-ethyl-2-methyl pyridinium bromide, 1-ethyl-3-methyl pyridinium bromide or a mixture thereof to the HBr-containing electrolyte in hydrogen/bromine cell. 
     
     
         11 ) An energy storage device comprising:
 a plurality of hydrogen/bromine cells arranged in a stack configuration, each cell having therein spaced apart bromine and hydrogen electrodes which are in electrical contact with means for supplying electrical current to the cell and collecting electrical current generated by the cell; a separator positioned in the space between said electrodes dividing the cell into a first and second compartments; and an aqueous hydrogen bromide electrolyte in which 1-alkyl-2-alkyl pyridinium halide, 1-alkyl-3-alkyl pyridinium halide or a mixture thereof is present;   hydrogen storage tank and HBr/Br 2  aqueous electrolyte storage tank connected by means of one or more conduits to the cell compartments;   wherein at least one component of said device comprises high density polyethylene (HDPE).   
     
     
         12 ) An energy storage device according to  claim 11 , wherein the electrolyte storage tank and/or conduit(s) used for electrolyte circulation comprise HDPE. 
     
     
         13 ) An energy storage device according to  claim 11 , wherein the 1-alkyl-2-alkyl pyridinium halide and 1-alkyl-3-alkyl pyridinium halide are 1-ethyl-2-methyl pyridinium bromide and 1-ethyl-3-methyl pyridinium bromide, respectively.