Herbicidal composition comprising cinmethylin and specific pigment synthesis inhibitors

Abstract

The present invention relates to a herbicidal composition comprising specific pigment synthesis inhibitors selected from beflubutamide, flurtamone and clomazone. The invention also relates to methods and uses for controlling undesirable vegetation, in particular in crops.

1 - 15 . (canceled) 
     
     
         16 . A herbicidal composition comprising a herbicidally effective amount of (a) (±)-2-exo-(2-Methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane, any of its individual enantiomers or any non-racemic mixture thereof (herbicide A) and (b) at least one pigment synthesis inhibitor selected from the group consisting of beflubutamide (B.1), flurtamone (B.2), and clomazone (B.3) (herbicide B). 
     
     
         17 . The composition of  claim 16  wherein the herbicide A is (±)-2-exo-(2-Methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane. 
     
     
         18 . The composition of  claim 16  wherein the pigment synthesis inhibitor is clomazone (B.3). 
     
     
         19 . The composition of  claim 16  wherein the herbicide A and herbicide B are each present in an amount sufficient to provide a synergistic herbicidal effect. 
     
     
         20 . The composition of  claim 16 , wherein the weight ratio of herbicide A to herbicide B is from 1:0.007 to 1:20. 
     
     
         21 . The composition of  claim 16 , further comprising at least one herbicide C selected from the group consisting of aclonifen (C.1), amicarbazone (C.2), amidosulfuron (C.3), aminopyralid (C.4), amitrole (C.5), asulam (C.6), atrazine (C.7), azimsulfuron (C.8), benfluralin (C.9), bensulfuron (C.10), bensulide (C.11), bentazone (C.12), bicyclopyrone (C.13), bifenox (C.14), bispyribac (C.15), bromoxynil (C.16), carbetamide (C.17), carfentrazone (C.18), chloridazon (C.19), chlorpropham (C.20), chlorsulfuron (C.21), chlorthal (C.22), chlortoluron (C.23), clethodim (C.24), clodinafop (C.25), clopyralid (C.26), cycloxydim (C.27), cyclopyrimorate (C.28), cyhalofop (C.29), 2,4-D (C.30), dazomet (C.31), 2,4-DB (C.32), desmedipham (C.33), dicamba (C.34), dichlorprop (C.35), dichlorprop-P (C.36), diclofop (C.37), diflufenican (C.38), diflufenzopyr (C.39), dimethachlor (C.40), dimethenamid (C.41), dimethenamid-P (C.42), diquat (C.43), dithiopyr (C.44), diuron (C.45), ethametsulfuron (C.46), ethofumesate (C.47), fenoxaprop (C.48), fenoxaprop-P (C.49), fenquinotrione (C.50), flazasulfuron (C.51), florasulam (C.52), fluazifop (C.53), fluazifop-P (C.54), flufenacet (C.55), flumioxazin (C.56), fluometuron (C.57), flupyrsulfuron (C.58), flurochloridone (C.59), fluroxypyr (C.60), foramsulfuron (C.61), glufosinate (C.62), glufosinate-P (C.63), glyphosate (C.64), halauxifen (C.65), halosulfuron (C.66), haloxyfop-P (C.67), indaziflam (C.68), imazamox (C.69), imazapic (C.70), imazaquin (C.71), imazethapyr (C.72), imazosulfuron (C.73), iodosulfuron (C.74), iofensulfuron (C.75), ioxynil (C.76), isoproturon (C.77), isoxaben (C.78), isoxaflutole (C.79), lenacil (C.80), linuron (C.81), MCPA (C.82), MCPB (C.83), mecoprop (C.84), mecoprop-P (C.85), mesosulfuron (C.86), mesotrione (C.87), metam (C.88), metamitron (C.89), metazachlor (C.90), methiozoline (C.91), metobromuron (C.92), metolachlor (C.93), S-metolachlor (C.94), metosulam (C.95), metribuzin (C.96), metsulfuron (C.97), molinate (C.98), monosodium methyl arsenate (MSMA) (C.99), napropamide (C.100), napropamide-M (C.101), nicosulfuron (C.102), orthosulfamuron (C.103), oryzalin (C.104), oxadiargyl (C.105), oxadiazon (C.106), oxasulfuron (C.107), oxyfluorfen (C.108), pendimethalin (C.109), penoxsulam (C.110), pethoxamid (C.111), phenmedipham (C.112), picloram (C.113), picolinafen (C.114), pinoxaden (C.115), pretilachlor (C.116), prodiamine (C.117), profoxydim (C.118), prometryne (C.119), propaquizafop (C.120), propoxycarbazone (C.121), propyzamide (C.122), prosulfocarb (C.123), prosulfuron (C.124), pyraflufen (C.125), pyridate (C.126), pyroxasulfone (C.127), pyroxsulam (C.128), quinclorac (C.129), quinmerac (C.130), quinoclamine (C.131), quizalofop (C.132), quizalofop-P (C.133), rimsulfuron (C.134), saflufenacil (C.135), sethoxydim (C.136), siduron (C.137), simazine (C.138), sulcotrione (C.139), sulfentrazone (C.140), sulfosulfuron (C.141), tembotrione (C.142), tepraloxydim (C.143), terbuthylazine (C.144), thiencarbazone (C.145), thifensulfuron (C.146), tolpyralate (C.147), topramezone (C.148), tralkoxydim (C.149), tri-allate (C.150), triasulfuron (C.151), tribenuron (C.152), triclopyr (C.153), trifloxysulfuron (C.154), trifludimoxazin (C.155), trifluralin (C.156), triflusulfuron (C.157), tritosulfuron (C.158), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid (C.159), benzyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylate (CAS 1390661-72-9, C.160), cyclosulfamuron (C.161), benzobicyclon (C.162), ethoxysulfuron (C.163), halosuflamuron (C.164), propanil (C.165), butachlor (C.166), butralin (C.167), piperophos (C.168), pyrazosulfuron (C.169), thiobencarb (C.170), flucarbazone (C.171), imazapyr (C.172), and agriculturally acceptable salts, esters or amides thereof. 
     
     
         22 . The composition of  claim 16 , further comprising at least one safener D selected from the group consisting of benoxacor (D.1), cloquintocet (D.2), cyometrinil (D.3), cyprosulfamide (D.4), dichlormid (D.5), dicyclonon (D.6), dietholate (D.7), fenchlorazole (D.8), fenclorim (D.9), flurazole (D.10), fluxofenim (D.11), furilazole (D.12), isoxadifen (D.13), mefenpyr (D.14), mephenate (D.15), naphthaleneacetic acid (D.16), naphthalic anhydride (D.17), oxabetrinil (D.18), 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3) (D.19), 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine (R-29148, CAS 52836-31-4) (D.20), N-(2-Methoxybenzoyl)-4-[(methylaminocarbonyl)amino]benzenesulfonamide (CAS 129531-12-0) (D.21), and agriculturally acceptable salts, esters or amides thereof. 
     
     
         23 . The composition of  claim 16 , further comprising one or more auxiliaries customary in crop protection. 
     
     
         24 . A method for controlling undesirable vegetation which comprises applying to the vegetation or the locus thereof or applying to the soil or water to prevent the emergence or growth of the undesirable vegetation the composition of  claim 16 . 
     
     
         25 . The method of  claim 24 , wherein the undesirable vegetation is controlled in crop plants selected from wheat, barley, rye, triticale, oat, corn (maize), sunflower, rice, soybeans, peas, Vicia-beans, Phaseolus-beans, peanuts, oilseed rape, canola, cotton, potato, sugarbeet, sugarcane, turfgrasses and vegetables. 
     
     
         26 . The method of  claim 24 , wherein the undesirable vegetation is selected from the genera  Agropyron, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cynodon, Digitaria, Echinochloa, Eleusine, Ischaemum, Leptochloa, Lolium, Panicum, Phalaris, Poa, Rottboellia, Setaria, Anthemis, Amaranthus, Ambrosia, Brassica, Capsella, Centaurea, Chenopodium, Conyza, Descurainia, Galium, Geranium, Kochia, Matricaria, Papaver, Polygonum, Raphanus, Sinapis, Sisymbrium, Stellaria  and  Thlaspi.    
     
     
         27 . The method of  claim 24 , wherein the undesirable vegetation is a herbicide resistant or tolerant weed species. 
     
     
         28 . The method of  claim 24 , wherein the herbicide A is applied in an amount of from 10 to 1000 g/ha. 
     
     
         29 . The method of  claim 24 , wherein the herbicide B is applied in an amount of from 7 to 1000 g/ha. 
     
     
         30 . The method of  claim 24 , wherein the herbicide A is (±)-2-exo-(2-Methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane. 
     
     
         31 . The method of  claim 24 , wherein the pigment synthesis inhibitor is clomazone (B.3) 
     
     
         32 . The method of  claim 24 , wherein the herbicide A and herbicide B are each present in an amount sufficient to provide a synergistic herbicidal effect. 
     
     
         33 . The method of  claim 24 , wherein the weight ratio of herbicide A to herbicide B is from 1:0.007 to 1:20. 
     
     
         34 . The method of  claim 24 , wherein the composition further comprises at least one herbicide C selected from the group consisting of aclonifen (C.1), amicarbazone (C.2), amidosulfuron (C.3), aminopyralid (C.4), amitrole (C.5), asulam (C.6), atrazine (C.7), azimsulfuron (C.8), benfluralin (C.9), bensulfuron (C.10), bensulide (C.11), bentazone (C.12), bicyclopyrone (C.13), bifenox (C.14), bispyribac (C.15), bromoxynil (C.16), carbetamide (C.17), carfentrazone (C.18), chloridazon (C.19), chlorpropham (C.20), chlorsulfuron (C.21), chlorthal (C.22), chlortoluron (C.23), clethodim (C.24), clodinafop (C.25), clopyralid (C.26), cycloxydim (C.27), cyclopyrimorate (C.28), cyhalofop (C.29), 2,4-D (C.30), dazomet (C.31), 2,4-DB (C.32), desmedipham (C.33), dicamba (C.34), dichlorprop (C.35), dichlorprop-P (C.36), diclofop (C.37), diflufenican (C.38), diflufenzopyr (C.39), dimethachlor (C.40), dimethenamid (C.41), dimethenamid-P (C.42), diquat (C.43), dithiopyr (C.44), diuron (C.45), ethametsulfuron (C.46), ethofumesate (C.47), fenoxaprop (C.48), fenoxaprop-P (C.49), fenquinotrione (C.50), flazasulfuron (C.51), florasulam (C.52), fluazifop (C.53), fluazifop-P (C.54), flufenacet (C.55), flumioxazin (C.56), fluometuron (C.57), flupyrsulfuron (C.58), flurochloridone (C.59), fluroxypyr (C.60), foramsulfuron (C.61), glufosinate (C.62), glufosinate-P (C.63), glyphosate (C.64), halauxifen (C.65), halosulfuron (C.66), haloxyfop-P (C.67), indaziflam (C.68), imazamox (C.69), imazapic (C.70), imazaquin (C.71), imazethapyr (C.72), imazosulfuron (C.73), iodosulfuron (C.74), iofensulfuron (C.75), ioxynil (C.76), isoproturon (C.77), isoxaben (C.78), isoxaflutole (C.79), lenacil (C.80), linuron (C.81), MCPA (C.82), MCPB (C.83), mecoprop (C.84), mecoprop-P (C.85), mesosulfuron (C.86), mesotrione (C.87), metam (C.88), metamitron (C.89), metazachlor (C.90), methiozoline (C.91), metobromuron (C.92), metolachlor (C.93), S-metolachlor (C.94), metosulam (C.95), metribuzin (C.96), metsulfuron (C.97), molinate (C.98), monosodium methyl arsenate (MSMA) (C.99), napropamide (C.100), napropamide-M (C.101), nicosulfuron (C.102), orthosulfamuron (C.103), oryzalin (C.104), oxadiargyl (C.105), oxadiazon (C.106), oxasulfuron (C.107), oxyfluorfen (C.108), pendimethalin (C.109), penoxsulam (C.110), pethoxamid (C.111), phenmedipham (C.112), picloram (C.113), picolinafen (C.114), pinoxaden (C.115), pretilachlor (C.116), prodiamine (C.117), profoxydim (C.118), prometryne (C.119), propaquizafop (C.120), propoxycarbazone (C.121), propyzamide (C.122), prosulfocarb (C.123), prosulfuron (C.124), pyraflufen (C.125), pyridate (C.126), pyroxasulfone (C.127), pyroxsulam (C.128), quinclorac (C.129), quinmerac (C.130), quinoclamine (C.131), quizalofop (C.132), quizalofop-P (C.133), rimsulfuron (C.134), saflufenacil (C.135), sethoxydim (C.136), siduron (C.137), simazine (C.138), sulcotrione (C.139), sulfentrazone (C.140), sulfosulfuron (C.141), tembotrione (C.142), tepraloxydim (C.143), terbuthylazine (C.144), thiencarbazone (C.145), thifensulfuron (C.146), tolpyralate (C.147), topramezone (C.148), tralkoxydim (C.149), tri-allate (C.150), triasulfuron (C.151), tribenuron (C.152), triclopyr (C.153), trifloxysulfuron (C.154), trifludimoxazin (C.155), trifluralin (C.156), triflusulfuron (C.157), tritosulfuron (C.158), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid (C.159), benzyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylate (CAS 1390661-72-9, C.160), cyclosulfamuron (C.161), benzobicyclon (C.162), ethoxysulfuron (C.163), halosuflamuron (C.164), propanil (C.165), butachlor (C.166), butralin (C.167), piperophos (C.168), pyrazosulfuron (C.169), thiobencarb (C.170), flucarbazone (C.171), imazapyr (C.172), and agriculturally acceptable salts, esters or amides thereof. 
     
     
         35 . The method of  claim 24 , wherein the composition further comprises at least one safener D selected from the group consisting of benoxacor (D.1), cloquintocet (D.2), cyometrinil (D.3), cyprosulfamide (D.4), dichlormid (D.5), dicyclonon (D.6), dietholate (D.7), fenchlorazole (D.8), fenclorim (D.9), flurazole (D.10), fluxofenim (D.11), furilazole (D.12), isoxadifen (D.13), mefenpyr (D.14), mephenate (D.15), naphthaleneacetic acid (D.16), naphthalic anhydride (D.17), oxabetrinil (D.18), 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3) (D.19), 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine (R-29148, CAS 52836-31-4) (D.20), N-(2-Methoxybenzoyl)-4-[(methylaminocarbonyl)amino]benzenesulfonamide (CAS 129531-12-0) (D.21), and agriculturally acceptable salts, esters or amides thereof.