Antireflection film

Abstract

The present invention relates to an antireflection film. The antireflection film includes a low refractive index layer having excellent alkali resistance and exhibiting remarkably improved mechanical properties such as scratch resistance and impact resistance as well as reduction of a glare phenomenon, and a base film exhibiting excellent mechanical strength and water resistance in spite of a thin thickness and having no fear of interference fringes occurring. Therefore, such antireflection film can be used as a protective film of a polarizing plate or used as any other component so as to provide a thin display device, and furthermore, can effectively prevent the glare phenomenon of the display device, and can more improve the durability and lifespan thereof.

1 . An antireflection film comprising: a polyester film having an in-plane retardation value (Rin) of 3000 nm to 30,000 nm in which a ratio (Rin/Rth) of an in-plane retardation value (Rin) to an thickness-direction retardation value (Rth) is 0.2 to 1.2; and
 a low refractive index layer which is disposed on the polyester film and which is a crosslinked polymer comprising a photopolymerizable compound, an inorganic particle, and a polysilsesquioxane in which at least one reactive functional group is substituted.   
     
     
         2 . The antireflection film of  claim 1 , wherein the polyester film is a uniaxially stretched film or a biaxially stretched film of polyethylene terephthalate or polyethylene naphthalate. 
     
     
         3 . The antireflection film of  claim 1 , wherein the photocurable coating composition includes a monomer or an oligomer containing a (meth)acryloyl group or a vinyl group as a photopolymerizable compound. 
     
     
         4 . The antireflection film of  claim 1 , wherein the photocurable coating composition contains a polysilsesquioxane in which at least one reactive functional group is substituted in an amount of 0.5 to 30 parts by weight based on 100 parts by weight of the photopolymerizable compound. 
     
     
         5 . The antireflection film of  claim 1 , wherein the reactive functional group substituted in the polysilsesquioxane includes at least one functional group selected from the group consisting of an alcohols, amines, carboxylic acids, epoxides, imides, (meth)acrylates, nitriles, norbornenes, olefins, polyethylene glycol, thiols, and vinyl groups. 
     
     
         6 . The antireflection film of  claim 1 , wherein the polysilsesquioxane in which at least one reactive functional group is substituted includes the polyhedral oligomeric silsesquioxane (POSS) having a cage structure in which at least one reactive functional group is substituted. 
     
     
         7 . The antireflection film of  claim 1 , wherein the photocurable coating composition further includes a fluorine-based compound containing a photoreactive functional group. 
     
     
         8 . The antireflection film of  claim 7 , wherein the photoreactive functional group contained in the fluorine-based compound is at least one functional group selected from the group consisting of a (meth)acryloyl group, an epoxy group, a vinyl group, and a mercapto group. 
     
     
         9 . The antireflection film of  claim 7 , wherein the fluorine-based compound containing the photoreactive functional group has a weight average molecular weight of 2,000 to 200,000 g/mol. 
     
     
         10 . The antireflection film of  claim 7 , wherein the photocurable coating composition includes 1 to 75 parts by weight of the fluorine-based compound containing the photoreactive functional group based on 100 parts by weight of the photopolymerizable compound. 
     
     
         11 . The antireflection film of  claim 1 , wherein the inorganic fine particle includes a hollow silica particle having a number average particle diameter of 10 nm to 100 nm. 
     
     
         12 . The antireflection film of  claim 11 , wherein the photocurable coating composition includes 10 to 350 parts by weight of the hollow silica nanoparticle based on 100 parts by weight of the photopolymerizable compound. 
     
     
         13 . The antireflection film of  claim 1 , wherein the hard coating layer is interposed between the polyester film and the low refraction index layer. 
     
     
         14 . The antireflection film of  claim 13 , wherein the hard coating layer realizes an antiglare function, a scratch prevention function, an antistatic function, or a combination of two or more of these functions.