US2018245194A1PendingUtilityA1

Coated articles and method for making

61
Assignee: GEN ELECTRICPriority: Dec 18, 2015Filed: Apr 27, 2018Published: Aug 30, 2018
Est. expiryDec 18, 2035(~9.4 yrs left)· nominal 20-yr term from priority
B22F 2301/45B22F 2301/15C23C 4/073B22F 2301/052F05D 2300/177B22F 2301/20Y10T428/12931F05D 2230/90F01D 25/007F05D 2300/611C23C 4/134F05D 2300/175Y10T428/12944F05D 2240/24B22F 9/16C22C 30/00C22C 19/07C23C 4/123F01D 5/08C23C 4/129C22F 1/10B22F 9/04B22F 1/142C23C 24/04B22F 7/08B22F 5/009B22F 3/115C22C 19/00F01D 5/02
61
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Claims

Abstract

An article includes a substrate comprising a precipitate-strengthened alloy and a coating disposed over the substrate. The alloy comprises a) a population of gamma-prime precipitates, the population having a multimodal size distribution with at least one mode corresponding to a size of less than about 100 nanometers; or b) a population of gamma-double-prime precipitates having a median size less than about 300 nanometers. The coating comprises at least two elements, and further comprises a plurality of prior particles. At least a portion of the coating is substantially free of rapid solidification artifacts. Methods for fabricating the article and for processing powder useful for fabricating the article are also provided.

Claims

exact text as granted — not AI-modified
1 - 18 . (canceled) 
     
     
         19 . A method comprising:
 heat-treating a quantity of metallic powder, the powder having particulates comprising at least two elements and a plurality of rapid solidification artifacts present within the particulates, wherein the heat-treating is performed at a combination of time and temperature effective to remove substantially all of the rapid solidification artifacts from the powder, thereby forming a processed powder having a desired particle size distribution.   
     
     
         20 . The method of  claim 19 , wherein heat-treating further includes agitating the powder during heat-treatment. 
     
     
         21 . The method of  claim 19 , further comprising mechanically processing sintered material formed during the heat-treating. 
     
     
         22 . The method of  claim 21 , wherein mechanically processing comprises milling the sintered material. 
     
     
         23 . The method of  claim 19 , further comprising disposing a coating material on a substrate, wherein the processed powder is used as a feedstock for the coating material. 
     
     
         24 . The method of  claim 23 , wherein the disposing step comprises spraying the feedstock using a technique that does not melt a substantial portion of the particulates in the feedstock. 
     
     
         25 . The method of  claim 24 , wherein the technique includes cold-spraying, flame spraying, liquid injection flame spraying, air plasma spraying, liquid injection air plasma spraying, high-velocity oxyfuel spraying, liquid injection high velocity oxyfuel spraying, high-velocity air-fuel spraying, or liquid injection high-velocity air-fuel spraying. 
     
     
         26 . The method of  claim 24 , wherein the technique includes liquid injection high velocity air-fuel spraying. 
     
     
         27 . The method of  claim 23 , wherein the substrate comprises a nickel-based superalloy, a nickel-iron-based superalloy, or a cobalt-based superalloy. 
     
     
         28 . The method of claim  9 , wherein the particulates comprise a NiCrAlY composition. 
     
     
         29 . The method of  claim 28 , wherein the composition comprises cobalt; from about 28 percent to about 35 percent nickel; from about 17 percent to about 25 percent chromium; from about 5 percent to about 15 percent aluminum; and from about 0.01 to about 1 percent yttrium. 
     
     
         30 . The method of  claim 28 , wherein the coating comprises beta phase, at least about 25 percent gamma phase by volume, and less than about 1 percent sigma phase by volume. 
     
     
         31 . A method comprising:
 heat-treating a quantity of powder having particulates comprising a MCrAlX composition at a temperature in a range from about 925 degrees Celsius to about 1200 degrees Celsius for at least about 5 minutes to form a processed powder; and   disposing a coating material on a substrate using cold-spraying, flame spraying, air plasma spraying, high-velocity oxyfuel spraying, or high-velocity air-fuel spraying, wherein the processed powder is used as a feedstock for the coating material, and wherein the substrate comprises a nickel-based superalloy;   wherein the disposing step comprises spraying the feedstock using a technique that does not melt a substantial portion of the particulates in the feedstock.   
     
     
         32 . A method comprising:
 disposing a coating onto a substrate by spraying a feedstock, the feedstock comprising a plurality of particulates comprising at least two elements and having at least a portion of the plurality of particulates substantially free of rapid solidification artifacts;   wherein spraying the feedstock comprises using a deposition technique that does not melt a substantial portion of the particulates in the feedstock;   wherein the substrate comprises a precipitate-strengthened alloy, the alloy comprising   a) a population of gamma-prime precipitates, the population having a multimodal size distribution with at least one mode corresponding to a size of less than about 100 nanometers; or b) a population of gamma-double-prime precipitates having a median size less than about 300 nanometers.   
     
     
         33 . The method of  claim 32 , wherein the substrate comprises a nickel-based superalloy, a nickel-iron-based superalloy, or a cobalt-based superalloy. 
     
     
         34 . The method of  claim 32 , wherein the feedstock comprises a MCrAlY composition. 
     
     
         35 . The method of claim of  claim 34 , wherein the feedstock comprises cobalt; from about 28 percent to about 35 percent nickel; from about 17 percent to about 25 percent chromium; from about 5 percent to about 15 percent aluminum; and from about 0.01 to about 1 percent yttrium. 
     
     
         36 . The method of  claim 34 , wherein the feedstock comprises a gamma phase and a beta phase. 
     
     
         37 . The method of  claim 36 , wherein the feedstock includes less than about 1 percent sigma phase by volume. 
     
     
         38 . The method of  claim 36 , wherein the coating is disposed in direct contact with the substrate at an interface, and wherein an interdiffusion zone extending from the interface into the substrate has a thickness of less than about 5 micrometers. 
     
     
         39 . A method comprising:
 disposing a coating onto a substrate by spraying a feedstock, the feedstock comprising a plurality of particulates comprising a MCrAlX composition and having at least a portion of the plurality of particulates substantially free of rapid solidification artifacts;   wherein spraying the feedstock comprises using a deposition technique that does not melt a substantial portion of the particulates in the feedstock;   wherein the substrate comprises a nickel-based superalloy comprising a population of gamma-prime precipitates, the population having a multimodal size distribution with at least one mode corresponding to a size of less than about 100 nanometers.

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