US2018282896A1PendingUtilityA1
Ferroelectric crystal film, electronic component, manufacturing method of ferroelectric crystal film, and manufacturing apparatus therefor
Est. expiryJun 4, 2032(~5.9 yrs left)· nominal 20-yr term from priority
C30B 23/08H01L 41/319C30B 1/023H01L 41/318C30B 29/68C30B 7/06Y10T117/10C30B 23/02C30B 29/22H10N 30/078H10N 30/079
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Claims
Abstract
A seed crystal film is formed on a substrate in epitaxial growth by a sputtering method, an amorphous film including ferroelectric material is formed over the seed crystal film by a spin-coat coating method, the seed crystal film and the amorphous film are heated in an oxygen atmosphere for oxidation and crystallization of the amorphous film, and thereby a ferroelectric coated-and-sintered crystal film is formed.
Claims
exact text as granted — not AI-modified1 . A manufacturing apparatus for a ferroelectric crystal film, comprising:
a first apparatus forming a ferroelectric seed crystal film having an orientation in a predetermined face over a substrate in epitaxial growth by a sputtering method; a second apparatus performing coating to form an amorphous film including ferroelectric material over said ferroelectric seed crystal film by a spin-coat coating method; and a third apparatus heating said ferroelectric seed crystal film and said amorphous film in an oxygen atmosphere to oxidize and crystallize said amorphous film, and thereby forming a ferroelectric coated-and-sintered crystal film.
2 . The manufacturing apparatus for a ferroelectric crystal film according to claim 1 , wherein
said ferroelectric coated-and-sintered crystal film has an orientation in the same face as said predetermined face.
3 . The manufacturing apparatus for a ferroelectric crystal film according to claim 1 , wherein
each of said ferroelectric seed crystal film and said ferroelectric coated-and-sintered crystal film is a Pb(Zr, Ti)O 3 film or a (Pb, A) (Zr, Ti)O 3 film and A is configured with at least one kind selected from the group consisting of Li, Na, K, Rb, Ca, Sr, Ba, Bi, and La.
4 . The manufacturing apparatus for a ferroelectric crystal film according to claim 3 , wherein
a Zr/Ti ratio in the number of elements for said Pb(Zr, Ti)O 3 film or (Pb, A) (Zr, Ti)O 3 film satisfies the following formula (1).
60/40≤Zr/Ti≤40/60 (1)
5 . The manufacturing apparatus for a ferroelectric crystal film according to claim 3 , wherein
each ratio in the number of elements for said Pb(Zr, Ti)O 3 film satisfies the following formula (2) and each ratio in the number of elements for said (Pb, A) (Zr, Ti)O 3 film satisfies the following formula (3).
Pb/(Zr+Ti)<1.06 (2)
(Pb+A)/(Zr+Ti)≤1.35 (3)
6 . The manufacturing apparatus for a ferroelectric crystal film according to claim 3 , wherein
said ferroelectric seed crystal film has an orientation in ( 001 ), and said ferroelectric coated-and-sintered crystal film has an orientation in ( 001 ).
7 . The manufacturing apparatus for a ferroelectric crystal film according to claim 3 , wherein
said ferroelectric seed crystal film has an orientation in ( 111 ), and said ferroelectric coated-and-sintered crystal film has an orientation in ( 111 ).Cited by (0)
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