US2018346843A1PendingUtilityA1

Lubricant compositions for direct injection engines

Assignee: LUBRIZOL CORPPriority: Jun 2, 2017Filed: Jun 1, 2018Published: Dec 6, 2018
Est. expiryJun 2, 2037(~10.8 yrs left)· nominal 20-yr term from priority
C10N 2010/02C10M 159/20C10N 2010/04C10N 2030/45C10N 2030/04C10M 2215/28C10N 2030/52C10N 2030/42C10N 2040/255C10M 2203/1025C10N 2040/25C10M 2223/045C10M 2219/046C10M 169/042C10M 2207/262C10M 2215/24C10M 159/22C10M 2227/066C10M 133/58C10M 2207/028C10M 101/02C10M 159/24C10M 2203/1006C10N 2210/02C10N 2230/04C10N 2240/10C10N 2230/52
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Claims

Abstract

The invention is directed to a method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine by supplying to the sump a lubricant composition which contains an oil of lubricating viscosity and a metal overbased detergent. The metal overbased detergent may be selected from sulfonate detergents, phenate detergents, and salicylate detergents, especially sulfonate detergents with a metal ratio of at least 5.

Claims

exact text as granted — not AI-modified
What is claimed: 
     
         1 . A method for reducing low speed pre-ignition (LSPI) events in a spark-ignited direct injection internal combustion engine over the entire service life of a lubricant composition utilized in said internal combustion engine;
 said method comprising: supplying to the engine a lubricant composition comprising a base oil of lubricating viscosity and a metal overbased detergent.   
     
     
         2 . The method of  claim 1  wherein the method results in the reduction of LSPI events during (i) the entire service life of the lubricant composition, (ii) during the second half of the service life of the lubricant composition, or (iii) during the last 25% of the service life of the lubricant composition. 
     
     
         3 . The method of  claim 2  wherein the service life of the lubricant composition is measured in mileage, in hours of operation, in time present in engine, in age of the lubricant composition, or some combination thereof. 
     
     
         4 . The method of  claim 1 , wherein the engine is operated: (i) under a load with a break mean effective pressure (BMEP) of greater than or equal to 10 bars, (ii) at speeds less than or equal to 3,000 rpm, or (iii) both (i) and (ii). 
     
     
         5 . The method of  claim 1 , wherein the engine is fueled with a liquid hydrocarbon fuel, a liquid nonhydrocarbon fuel, or mixtures thereof. 
     
     
         6 . The method of  claim 1 , wherein the metal overbased detergent comprises a mixture of overbased calcium detergents and overbased magnesium detergents. 
     
     
         7 . The method of  claim 1 , wherein the lubricant composition further comprises at least one other additive selected from an ashless dispersant, an ashless antioxidant, a phosphorus-containing anti-wear additive, a friction modifier, and a polymeric viscosity modifier. 
     
     
         8 . The method of  claim 6 , wherein the metal overbased detergent comprises a sulfonate detergent. 
     
     
         9 . The method of  claim 6 , wherein the metal overbased detergent comprises a salicylate detergent. 
     
     
         10 . The method of  claim 6 , wherein the metal overbased detergent comprises an alkali metal or an alkaline earth metal detergent. 
     
     
         11 . The method of  claim 1 , wherein the metal overbased detergent has a metal ratio of 5 to 30. 
     
     
         12 . The method of  claim 1 , wherein the metal overbased detergent is present in an amount from 0.2 to 8 weight percent of the lubricant composition. 
     
     
         13 . The method of  claim 3 , wherein the lubricating composition further comprises a polyalkenyl succinimide dispersant in an amount from 0.5 to 4 weight % of the composition. 
     
     
         14 . The method of  claim 1 , wherein the lubricating composition comprises at least 50 weight % of a Group II base oil, a Group III base oil, or mixtures thereof. 
     
     
         15 . The method of  claim 1 , wherein the metal overbased detergent comprises a sulfur-coupled phenate detergent. 
     
     
         16 . The method of  claim 1 , wherein the metal overbased detergent is present in an amount to provide 0.1 weight percent to 0.9 weight percent sulfated ash to the lubricating composition. 
     
     
         17 . The method of  claim 1 , wherein there is a reduction in the number of LSPI events of at least 10 percent. 
     
     
         18 . The method of  claim 1 , wherein the low speed pre-ignition events are reduced to less than 20 LSPI events per 100,000 combustion events.

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