Sugar-based polyurethanes, methods for their preparation, and methods of use thereof

Abstract

Polyurethane foams which are highly flame resistant are described, as well as the production of such polyurethane foams by the reaction between a natural polyol, such as sucrose or a blend of mono- or disaccharides in place of the standard hydrocarbon-based polyol component, a polyisocyanate and water in the presence of a suitable polyurethane forming catalyst and a non-halogenated flame retardant, and optionally one or more components such as surfactants and/or emulsifiers. The resultant polyurethane foam has a bio-based solid content ranging from about 17% to 30%, may be formulated in a variety of foam densities for a variety of applications, and exhibits a high degree of fire and burn resistance, as exhibited by the flame spread index, flash over resistance determination, and the smoke spread values.

1 .- 22 . (canceled). 
     
     
         23 . A flame-retardant polyurethane foam comprising the reaction product of:
 a first reaction mixture comprising polyisocyanate and optionally a surfactant; and   a second reaction mixture comprising:
 a natural polyol; 
 a surfactant; 
 an aqueous blowing agent; 
 a polyurethane producing catalyst; 
 a flame-retardant; and 
 optionally, a polyether polyol or an alkylene oxide adduct of a non-reducing sugar; 
   wherein the first reaction mixture and the second reaction mixture are used in amounts to provide an Isocyanate Index of 20 to 50; and   wherein the flame-retardant polyurethane foam has a density from about 0.3 lb/ft 3  to about 5.0 lb/ft 3 .   
     
     
         24 . The flame-retardant polyurethane foam according to  claim 23 , wherein the natural polyol is selected from sucrose, dextrose, xylose, fructose, glucose, sorbitol, maltose, erythritol, hexose, sugar invert, sugar beet polyol extracts, molasses, corn syrup, or combinations thereof. 
     
     
         25 . The flame-retardant polyurethane foam according to  claim 23 , wherein:
 the alkylene oxide adduct of a non-reducing sugar is present in the second reaction mixture; and   the alkylene oxide is selected from ethylene oxide, propylene oxide, butylene oxide, isobutylene oxide, N-hexyl oxide, styrene oxide, trimethylene oxide, tetrahydrofuran, or epichlorohydrin.   
     
     
         26 . The flame-retardant polyurethane foam according to  claim 25 , wherein the non-reducing sugar is sucrose. 
     
     
         27 . The flame-retardant polyurethane foam according to  claim 23 , wherein
 the polyether polyol is present in the second reaction mixture; and   the polyether polyol is selected from polypropylene glycol, polyethylene glycol, polytetramethylene glycol, a glycerol polyether triol, a polyether tetrol, a polyether pentol, a polyether octol, a sorbitol polyether polyol, a sucrose polyether polyol, a trimethylol propane polyether polyol, a pentaerythritol polyether polyol, a poly(oxypropylene)triol, a poly(oxyethylene-oxypropylene)triol, a sucrose polyether polyol, a glycerin polyether polyol, or a triethanol amine polyether polyol.   
     
     
         28 . The flame-retardant polyurethane foam according to  claim 23 , wherein the second reaction mixture further comprises a plasticizer, an emulsifier, a biocide, a bacteriostat, a halogenated or non-halogen containing blowing agent other than water, a filler, a dye or colorant, an anti-scorching agent, glycerine, a chain extender/cross-linker, an antioxidant, an antistatic agent, and/or a cell-opening agent. 
     
     
         29 . The flame-retardant polyurethane foam according to  claim 23 , wherein the flame-retardant polyurethane foam meets the Conditions of Acceptance X2.1.6 according to ICC-ES AC 377 flammability tests. 
     
     
         30 . The flame-retardant polyurethane foam according to  claim 29 , wherein the flame-retardant polyurethane foam has a density from about 1.0 lb/ft 3  to about 3.0 lb/ft 3 . 
     
     
         31 . The flame-retardant polyurethane foam according to  claim 23 , wherein the second reaction mixture further comprises a plasticizer selected from a phthalate plasticizer, a phosphate or phosphorus-containing plasticizer, or a benzoate plasticizer. 
     
     
         32 . The flame-retardant polyurethane foam according to  claim 23 , wherein the polyurethane foam exhibits a percent modern carbon (pMC) value of ranging from about 10% to about 50% as determined by ASTM-D6866-11. 
     
     
         33 . The flame-retardant polyurethane foam according to  claim 23 , wherein the weight ratio of the second reaction mixture to the first reaction mixture is from about 0.75:1 to 2:1. 
     
     
         34 . The flame-retardant polyurethane foam according to  claim 23 , wherein the volume ratio of the first reaction mixture to the second reaction mixture is between about 1.0 and 5.0. 
     
     
         35 . The flame-retardant polyurethane foam according to  claim 23 , wherein the second reaction mixture contains from 20 wt. % to about 70 wt. % of natural polyol. 
     
     
         36 . The flame-retardant polyurethane foam according to  claim 23 , wherein the second reaction mixture contains from about 5 wt. % to about 40 wt. % of flame retardant. 
     
     
         37 . The flame-retardant polyurethane foam according to  claim 23 , wherein the flame retardant is a phosphate compound. 
     
     
         38 . The flame-retardant polyurethane foam according to  claim 23 , wherein the flame retardant is selected from tris-(2-chloro-1-methylethyl)phosphate (TMCP), low-odor tris-(2-chloro-1-methylethyl)phosphate (TCPP-LO), tris-(chloroethyl)phosphate (TCEP), tris(chloroisopropyl)phosphate (TCPP), tri-cresyl phosphate (TCP), tris-(1,3-dichloro-2-propyl)phosphate (TDCP), low-viscosity tris-(1,3-dichloro-2-propyl)phosphate (TDCP-LV), or combinations thereof. 
     
     
         39 . The flame-retardant polyurethane foam according to  claim 23 , wherein the polyurethane foam has a bio-based content from about 15% to about 30% as determined by ASTM-D6866-11. 
     
     
         40 . The flame-retardant polyurethane foam according to  claim 23 , wherein the foam exhibits a flame spread value of 15 or less @ 4-inch foam thickness as determined by ASTM E-84. 
     
     
         41 . The flame-retardant polyurethane foam according to  claim 23 , wherein
 the natural polyol is present in the second reaction mixture at about 20-70 wt %;   the surfactant is present in the second reaction mixture at about 1.0-5 wt %;   the aqueous blowing agent is present in the second reaction mixture at about 0.05-10 wt %; and   the polyurethane producing catalyst is present in the second reaction mixture at about 0.01-10 wt %.   
     
     
         42 . A method of making a flame-retardant polyurethane foam, the method comprising combining:
 a first reaction mixture comprising polyisocyanate and optionally a surfactant; and   a second reaction mixture comprising:
 a natural polyol; 
 a surfactant; 
 an aqueous blowing agent; 
 a polyurethane producing catalyst; and 
 a flame-retardant; 
   wherein the first reaction mixture and the second reaction mixture are combined in amounts to provide an Isocyanate Index of 20 to 50 and a density from about 0.3 lb/ft' to about 5.0 lb/ft 3 .