US2019084898A1PendingUtilityA1

Compositions with improved urease-inhibiting effect comprising (thio)phosphoric acid triamide and further compounds

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Assignee: BASF SEPriority: Jul 4, 2013Filed: Nov 21, 2018Published: Mar 21, 2019
Est. expiryJul 4, 2033(~6.9 yrs left)· nominal 20-yr term from priority
Inventors:Karl-Heinrich SchneiderClaudia KlodwigGregor PasdaAlexander WissemeierDaniella LoheAchim ReddigChristian Carlos MiyagawaWolfram ZerullaSteffen TschirschwitzRalf-Thomas RahnAnsgar Gereon AltenhoffStephan Huffer
C05G 3/90C05C 11/00C05G 5/37C05G 5/30C09K 15/30C05C 9/00C09K 15/06C09D 179/02C09K 15/26C09K 15/28C09D 5/00C09K 15/18C05C 9/005C09K 15/10C09K 15/22C05G 3/08C05G 3/0041C05G 3/0029
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Claims

Abstract

An composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I) R 1 R 2 N—P(X)(NH 2 ) 2 , wherein X is oxygen or sulfur; R 1 is a C 1 to C 20 alkyl, C 3 to C 20 cycloalkyl, C 6 to C 20 aryl, or dialkylaminocarbonyl group; R 2 is H, or R 1 and R 2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (C) at least one amine selected from the group consisting of (C1) a polymeric polyamine, and (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C 2 to C 12 alkyl groups R 21 , wherein at least one of the groups R 21 is different to the other groups R 21 , and (C3) an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C 2 to C 12 alkyl groups R 22 , wherein at least one of the groups R 22 bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R 22 is different to the other group(s) R 22 , and (C4) an amine containing at least one saturated or unsaturated C 8 to C 40 alkyl group R 23 , and (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.

Claims

exact text as granted — not AI-modified
1 - 34 . (canceled) 
     
     
         35 . A composition comprising:
 (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)
   R 1 R 2 N—P(X)(NH 2 ) 2 ,
 
   wherein   X is oxygen or sulfur;   R 1  is a C 1  to C 20  alkyl, C 3  to C 20  cycloalkyl, C 6  to C 20  aryl, or dialkylaminocarbonyl group;   R 2  is H, or   R 1  and R 2  together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur,   and   (D) at least one amide according to the general formula (III)
   R 31 CO—NR 32 R 33  
 
   wherein   R 31 CO is an acyl radical having 1 to 22 carbon atoms;   R 32  is H or alkyl, and   R 33  is H or alkyl, or   R 32  and R 33  together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur.   
     
     
         36 . The composition according to  claim 35 , wherein the mixture (A) comprises N-n-butylthiophosphoric acid triamide (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT). 
     
     
         37 . The composition according to  claim 35 , wherein in the general formula (III) of (D) R 32  is H or C 1  to C 4  alkyl, and R 33  is H or C 1  to C 4  alkyl. 
     
     
         38 . The composition according to  claim 35 , wherein in the general formula (III) of (D) R 31 CO is a hydroxysubstituted acyl radical having 1 to 22 carbon atoms. 
     
     
         39 . The composition according to  claim 35 , wherein (D) is a N,N-dialkyl amide based on lactic acid, citric acid, tartaric acid, ricinoleic acid, 12-hydroxy stearic acid, or their mixtures. 
     
     
         40 . The composition according to  claim 35 , wherein (D) is a lactic acid N,N-dimethylamide. 
     
     
         41 . The composition according to  claim 35 , wherein in the general formula (III) of (D) R 31 CO does not contain a hydroxy group. 
     
     
         42 . The composition according to  claim 35 , wherein (D) is selected from the group consisting of N,N-dimethyloctanamide, N,N-dimethylnonanamide, and N,N-dimethyldecanamide. 
     
     
         43 . The composition according to  claim 35 , wherein in the general formula (III) of (D) R 31 CO is an acyl radical having 1 to 3 carbon atoms. 
     
     
         44 . The composition according to  claim 35 , wherein in the general formula (III) of (D) R 32  and R 33  together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur. 
     
     
         45 . The composition according to  claim 35 , wherein in the general formula (III) of (D) R 32  is an acyloxy substituted alkyl group. 
     
     
         46 . The composition according to  claim 35 , wherein in the general formula (III) of (D) R 31 CO is an acyl radical having 1 to 4 carbon atoms, R 32  is an acyloxy substituted alkyl group and R 33  is C 1  to C 4  alkyl. 
     
     
         47 . The composition according to  claim 35 , further comprising
 (B) an aromatic alcohol according to the general formula (II)
   R 11 —C(R 12 )(R 13 )—OH,
 
   wherein   is aryl or alkylaryl;   R 12  is H or alkyl;   R 13  is H or alkyl.   
     
     
         48 . The composition according to  claim 35 , further comprising
 (C) at least one amine selected from the group consisting of
 (C1) a polymeric polyamine, and
 (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C 2  to C 12  alkyl groups R 21 , wherein at least one of the groups R 21  is different to the other groups R 21 , and 
 (C3) an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C 2  to C 12  alkyl groups R 22 , wherein at least one of the groups R 22  bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R 22  is different to the other group(s) R 22 , and 
 
 (C4) an amine containing at least one saturated or unsaturated C 8  to C 40  alkyl group R 23 , and 
 (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group. 
   
     
     
         49 . The composition according to  claim 35 , wherein (C1) is a polyethylene imine. 
     
     
         50 . The composition according to  claim 35 , further comprising
 (E) an alcohol comprising at least two hydroxy groups which are not dissociable in the aqueous medium.   
     
     
         51 . The composition according to  claim 35 , further comprising
 (E) propane-1,2-diol (alpha-propylene glycol).

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