US2019131547A1PendingUtilityA1
Azadibenzofurans for electronic applications
Est. expirySep 20, 2032(~6.1 yrs left)· nominal 20-yr term from priority
Inventors:Annemarie WollebThomas SchaeferHeinz WollebUte HeinemeyerNicolle LangerChristian LennartzGerhard WagenblastSoichi WatanabeFlavio Luiz BeneditoHeinz HottingerOliver Dosenbach
C09K 2211/1007C09B 57/00C07D 209/86C07D 519/00C07D 405/04C07F 7/0814C07D 491/147C07D 405/14C09K 2211/1011C09K 2211/1048C09K 2211/1029C09K 2211/1033C09K 2211/1074Y02E10/549C09K 2211/1059C07D 491/048C09B 57/008C09K 11/025C09K 11/06C07F 7/0812C09K 2211/1088C09K 2211/185H01L 51/0072H01L 51/0094H01L 51/0071H01L 51/5056C07D 487/04H10K 85/6572H10K 2101/10H10K 85/40H10K 50/15H10K 85/626H10K 85/6574H10K 50/11H10K 50/17H10K 85/622H10K 85/342H10K 2102/103H10K 50/81H10K 85/657H10K 50/171Y02P70/50
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Claims
Abstract
The present invention relates to compounds of formula (I), which are characterized in that they substituted by benzimidazo[1,2-a]benzimidazo-5-yl and/or benzimidazo[1,2-a]benzimidazo-2,5-ylene groups and in that at least one of the substituents B 1 , B 2 , B 3 , B 4 , B 5 , B 6 , B 7 and B 8 represents N; a process for their production and their use in electronic devices, especially electroluminescent devices. When used as host material for phosphorescent emitters in electroluminescent devices, the compounds of formula I may provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.
Claims
exact text as granted — not AI-modified1 . A compound of the formula
wherein
R 1 is N, or CR 81 ,
B 2 is N, or CR 82 ,
B 3 is N, or CR 83 ,
B 4 is N, or CR 84 ,
B 5 is N, or CR 85 ,
B 6 is N, or CR 86 ,
B 7 is N, or CR 87 ,
B 8 is N, or CR 88 ,
R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 are independently of each other H, a C 1 -C 25 alkyl group, which can optionally be substituted by E and or interrupted by D; a C 6 -C 24 aryl group, which can optionally be substituted by G, a C 2 -C 30 heteroaryl group, which can optionally be substituted by G; or a group of formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ,
o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1,
A 1 , A 2 , A 3 and A 4 are independently of each other a C 6 -C 24 arylen group, which can optionally be substituted by G, or a C 2 -C 30 heteroarylen group, which can optionally be substituted by G;
R 16 is —NR 10 R 11 , or —Si(R 12 )(R 13 ) (R 14 ), a C 6 -C 24 aryl group, which can optionally be substituted by G; or a C 2 -C 30 heteroaryl group, which can optionally be substituted by G;
R 10 and R 11 are independently of each other a C 6 -C 24 aryl group, which can optionally be substituted by G; or a C 2 -C 30 heteroaryl group, which can optionally be substituted by G;
R 12 , R 13 and R 14 are independently of each other a C 1 -C 25 alkyl group, which can optionally be substituted by E and or interrupted by D; C 6 -C 24 aryl group, which can optionally be substituted by G; or a C 2 -C 30 heteroaryl group, which can optionally be substituted by G;
D is —CO—, —COO—, —S—, —SO—, —SO 2 —, —O—, —NR 65 —, —SiR 70 R 71 —, —POR 72 —, —CR 63 ═CR 64 —, or —C≡C—,
E is —OR 69 , —SR 69 , —NR 65 R 66 , —COR 68 , —COOR 67 , —CONR 65 R 66 , —CN, or F,
G is E, or a C 1 -C 18 alkyl group, a C 6 -C 24 aryl group, a C 6 -C 24 aryl group, which is substituted by F, C 1 -C 18 alkyl, or C 1 -C 18 alkyl which is interrupted by O; a C 2 -C 30 heteroaryl group, or a C 2 -C 30 heteroaryl group, which is substituted by F, C 1 -C 18 alkyl, or C 1 -C 18 alkyl which is interrupted by O;
R 63 and R 64 are independently of each other H, C 6 -C 18 aryl; C 6 -C 18 aryl which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy; C 1 -C 18 alkyl; or C 1 -C 18 alkyl which is interrupted by —O—;
R 65 and R 66 are independently of each other a C 6 -C 18 aryl group; a C 6 -C 18 aryl which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy; a C 1 -C 18 alkyl group; or a C 1 -C 18 alkyl group, which is interrupted by —O—; or
R 65 and R 66 together form a five or six membered ring,
R 67 is a C 6 -C 18 aryl group; a C 6 -C 18 aryl group, which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy; a C 1 -C 18 alkyl group; or a C 1 -C 18 alkyl group, which is interrupted by —O—,
R 68 is H; n a C 6 -C 18 aryl group; a C 6 -C 18 aryl group, which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy; a C 1 -C 18 alkyl group; or a C 1 -C 18 alkyl group, which is interrupted by —O—,
R 69 is a C 6 -C 18 aryl; a C 6 -C 18 aryl, which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy; a C 1 -C 18 alkyl group; or a C 1 -C 18 alkyl group, which is interrupted by —O—,
R 70 and R 71 are independently of each other a C 1 -C 18 alkyl group, a C 6 -C 18 aryl group, or a C 6 -C 18 aryl group, which is substituted by C 1 -C 18 alkyl, and
R 72 is a C 1 -C 18 alkyl group, a C 6 -C 18 aryl group, or a C 6 -C 18 aryl group, which is substituted by C 1 -C 18 alkyl, with the proviso that
at least one of the substituents B 1 , B 2 , B 3 , B 4 , B 5 , B 6 , B 7 and B 8 represents N;
not more than two of the groups B 1 , B 2 , B 3 and B 4 represent N; and
not more than two of the groups B 5 , B 6 , B 7 and B 8 represent N; and
with the further proviso that at least one of the substituents R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 represent a group of formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 , wherein R 16 represents a benzimidazo[1,2-a]benzimidazo-5-yl group, which can optionally be substituted by G; and/or at least one of the groups A 1 , A 2 , A 3 and A 4 represents a benzimidazo[1,2-a]benzimidazo-2,5-ylene group, which can optionally be substituted by G.
2 . The compound according to claim 1 , which is a compound of formula
wherein R 8 , R 82 , R 83 , R 8 , R 86 and R 87 are as defined in claim 1 .
3 . The compound according to claim 2 , wherein
in the compounds of formula (Ia) R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (Ib) R 82 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 82 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (Ic) R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (Id) R 81 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 81 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; the compounds of formula (Ie) R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (If) R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (Ig) R 82 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 82 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (Ih) R 81 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 81 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; the compounds of formula (Ii) R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (Ij) R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (Ik) R 81 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 81 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (Il) R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; in the compounds of formula (Im) R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; the compounds of formula (In) R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 6′ ; or R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; wherein in the compounds of formula (Io) R 82 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and R 86 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or R 82 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and R 86 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1; A 1 , A 2 , A 3 and A 4 are independently of each other a group of the formula
R 16 is a group of the formula
or R 16 has the meaning of R 16′ , if at least one of the groups A 1 , A 2 , A 3 and A 4 represent a group of formula
R 16′ is H, or a group of the formula —Si(R 12 )(R 13 )(R 14 ),
wherein
R 12 , R 13 and R 14 are independently of each other a phenyl group, which can optionally be substituted by one, or more alkyl groups;
R 21 and R 21′ are independently of each other H, a phenyl group, or a C 1 -C 18 alkyl group;
R 22 and R 23 are independently of each other H, or a group of the formula
X is O, S, or NR 24 ,
R 24 is a C 6 -C 24 aryl group, or a C 2 -C 30 heteroaryl group, which can optionally be substituted by G; and
R 89 is H, a group of formula
4 . The compound according to claim 2 , wherein
o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1, A 1 , A 2 , A 3 and A 4 are independently of each other a group of the formula
R 16 is a group of the formula
or R 16 has the meaning of R 16′ , if at least one of the groups A 1 , A 2 , A 3 and A 4 represent a group of formula
R 16′ is H, or a group of the formula
and R 89 is H, a group of formula
wherein X is O, S, or NR 24 , wherein
R 24 is
5 . The compound according to claim 2 , wherein the group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 is a group of formula
6 . The compound according to claim 5 , wherein the group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ is H, or a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf), or (XIIIg); or a group of formula
7 . The compound according to claim 6 , which is
a compound of formula (Ia), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ia), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw)), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ib), wherein R 82 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ib), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 82 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ic), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw)), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ic), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg); and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIII), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Id), wherein R 81 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIj), (XIIk), (XIIl), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIs), (XIIr), (XIII), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIII), (XIIu), (XIIv) (XIIw), (XIIx)), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg); or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Id), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg); and R 81 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIII), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ie), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), (XIIl), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ie), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (If), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (If), wherein R 85 is a group of formula (XIIa), (XIII)), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ii), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ii), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ij), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ij), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); a compound of formula (Il), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Il), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (In), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (In), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId).
8 . The compound according to claim 6 , which is a compound of formula (Ia), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and
R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ia), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); a compound of formula (Ib), wherein R 82 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ib), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 82 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); a compound of formula (Ic), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ic), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), or (XIIIg), and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Id), wherein R 81 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Id), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 81 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); a compound of formula (Ie), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ie), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); a compound of formula (If), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (If), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ij), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (Ij), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (In), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or a compound of formula (In), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId).
9 . The compound according to claim 1 :
Compound
R 83
R 87
A-1
A-2
A-3
A-4
A-5
H
A-6
H
A-7
H
A-8
H
A-9
H
A-10
H
A-11
A-12
A-13
A-14
A-15
A-16
A-17
A-18
A-19
A-20
A-21
A-22
A-23
A-24
A-25
A-26
A-27
A-28
A-29
A-30
A-31
A-32
A-33
A-34
A-35
H
A-36
H
A-37
A-38
A-39
A-40
A-41
H
A-42
H
A-43
A-44
A-45
A-46
A-47
H
A-48
H
A-49
A-50
A-51
A-52
A-53
A-54
A-55
A-56
A-57
H
A-58
A-59
A-60
H
A-61
H
A-62
H
A-63
H
A-64
H
A-65
H
Compound
R 82
R 87
B-1
B-2
B-3
B-4
B-5
B-6
B-7
B-8
Compound
R 85
R 87
C-1
C-2
C-3
C-4
C-5
H
C-6
H
C-7
H
C-8
H
C-9
H
C-10
H
C-11
C-12
C-13
C-14
C-15
C-16
C-17
C-18
C-19
C-20
C-21
C-22
C-23
C-24
C-25
C-26
C-27
C-28
C-29
C-30
C-31
C-32
C-33
C-34
C-35
H
C-36
H
C-37
C-38
C-39
C-40
C-41
H
C-42
H
C-43
C-44
C-45
C-46
C-47
H
C-48
H
C-49
C-50
C-51
C-52
C-53
C-54
C-55
C-56
C-57
H
C-58
C-59
C-60
H
C-61
H
C-62
H
C-63
H
C-64
H
C-65
H
Cmp.
R 81
R 83
R 85
R 87
D-1
D-2
H
H
D-3
H
H
H
D-4
H
D-5
D-6
H
H
D-7
H
H
D-8
H
Compound
R 83
R 87
E-1
E-2
E-3
E-4
E-5
H
E-6
H
E-7
H
E-8
H
E-9
H
E-10
H
E-11
E-12
E-13
E-14
E-15
E-16
E-17
E-18
E-19
E-20
E-21
E-22
E-23
E-24
E-25
E-26
E-27
E-28
E-29
E-30
E-31
E-32
E-33
E-34
E-35
H
E-36
H
E-37
E-38
E-39
E-40
E-41
H
E-42
H
E-43
E-44
E-45
E-46
E-47
H
E-48
H
E-49
E-50
E-51
E-52
E-53
E-54
E-55
E-56
E-57
H
E-58
E-59
E-60
H
E-61
H
E-62
H
E-63
H
E-64
H
E-65
H
Compound
R 83
R 85
F-1
F-2
F-3
F-4
F-5
H
F-6
H
F-7
H
F-8
H
F-9
H
F-10
H
F-11
F-12
F-13
F-14
F-15
F-16
F-17
F-18
F-19
F-20
F-21
F-22
F-23
F-24
F-25
F-26
F-27
F-28
F-29
F-30
F-31
F-32
F-33
F-34
F-35
H
F-36
H
F-37
F-38
F-39
F-40
F-41
H
F-42
H
F-43
F-44
F-45
F-46
F-47
H
F-48
H
F-49
F-50
F-51
F-52
F-53
F-54
F-55
F-56
F-57
H
F-58
F-59
F-60
H
F-61
H
F-62
H
F-63
H
F-64
H
F-65
H
or
10 . An electronic device, comprising a compound according to claim 1 .
11 . The electronic device according to claim 10 , which is an electroluminescent device.
12 . A hole transport layer, or an emitting layer comprising a compound according to claim 1 .
13 . The emitting layer according to claim 12 , comprising the compound as host material in combination with a phosphorescent emitter.
14 . An apparatus selected from the group consisting of stationary visual display units; mobile visual display units; illumination units; keyboards; items of clothing;
furniture; wallpaper, comprising the organic electronic device according to claim 10 .
15 . Use of the compounds of formula I according to claim 1 for electrophotographic photoreceptors, photoelectric converters, organic solar cells, switching elements, organic light emitting field effect transistors, image sensors, dye lasers and electroluminescent devices.
16 . A compound of the formula
wherein
B 1 is N, or CR 81 ,
B 2 is N, or CR 82 ,
B 3 is N, or CR 83 ,
B 4 is N, or CR 84 ,
B 5 is N, or CR 85 ,
B 6 is N, or CR 86 ,
B 7 is N, or CR 87 ,
B 8 is N, or CR 88 , wherein R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 are independently of each other H, a C 1 -C 25 alkyl group, which can optionally be substituted by E and or interrupted by D; a C 6 -C 24 aryl group, which can optionally be substituted by G, a C 2 -C 30 heteroaryl group, which can optionally be substituted by G; a group of formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 , or -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -X 1 ,
o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1,
at least one of the substituents R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 represents a group of formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -X 1 ; wherein
X 1 is Cl, Br, or I, ZnX 12 , X 12 is a halogen atom; —SnR 207 R 208 R 209 , wherein R 207 , R 208 and R 209 are identical or different and are H or C 1 -C 8 alkyl, wherein two radicals optionally form a common ring and these radicals are optionally branched or unbranched; —B(OH) 2 , —B(OY 1 ) 2 ,
—BF 4 Na, or —BF 4 K, wherein Y 1 is independently in each occurrence a C 1 -C 18 alkyl group and Y 2 is independently in each occurrence a C 2 -C 10 alkylene group, and Y 13 and Y 14 are independently of each other hydrogen, or a C 1 -C 18 alkyl group, and o, p, q, r, G, A 1 , A 2 , A 3 , A 4 , R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 are as defined in claim 1 , with the proviso that the following compounds are excluded:
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